Abstract
A nonmonotonic bimodal dependence of elastic, Rayleigh scattering on the potassium phenosan concentration in an aqueous solution has been revealed. A similar dependence has been found, for the first time, for scattering amplitude fluctuations. The observed correlation is indicative of structural transitions in hydration shells of potassium phenosan, which are responsible for the increase and scatter of their size comparable with the wavelength (527 nm) of a laser spectrometer.
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Pal’mina, N.P., Mal’tseva, E.L., and Burlakova, E.B., Khim. Fiz., 1995, vol. 14, no. 11, pp. 47–60.
Ryzhkina, I.S., Kiseleva, Yu.V., Murtazina, L.I., and Konovalov, A.I., Dokl. Akad. Nauk, 2012, vol. 446, no. 3, pp. 303–307.
Konovalov, A.I. and Ryzhkina, I.S., Izv. Akad. Nauk, Ser. Khim., 2014, no. 1, pp. 1–14.
Vuks, M.F., Rasseyanie sveta v gazakh, zhidkostyakh i rastvorakh (Light Scattering in Gases, Liquids, and Solutions), Leningrad: Izd. LGU, 1977.
Landau, L.D. and Lifshits, E.M., Teoreticheskaya fizika, vol. 5: Statisticheskaya fizika (Theoretical Physics, vol. 5: Statistical Physics), Moscow: Fizmatlit, 2002.
Bunkin, A.F., Davydov, M.A., and Pershin, S.M., Phys. Wave Phenom., 2014, vol. 22, no. 2, pp. 91–94.
Pershin, S.M., Bunkin, A.F., Grishin, M.Ya., Davydov, M.A., Lednev, V.N., Pal’mina, N.P., and Fedorov, A.N., Dokl. Phys., 2015, vol. 60, no. 3, pp. 114–117.
Pershin, S.M., Dokl. Phys. Chem., 2014, vol. 455, part 1, pp. 37–40.
Pershin, S.M., Biofizika, 2014, vol. 59, no. 6, pp. 1209–1219.
Bunkin, A.F., Pershin, S.M., and Nurmatov, A.A., Laser Phys. Lett., 2006, vol. 3, no. 6, pp. 275–277.
Bunkin, A.F. and Pershin, S.M., Kvant. Elektron., 2010, vol. 40, no. 12, pp. 1098–1102.
Belov, V.V., Belyaeva, I.A., Shmatov, G.P., Zubareva, G.M., and Palmina, N.P., Dokl. Phys. Chem., 2011, vol. 439, no. 1, pp. 123–126.
Zubareva, G.M., Kargopolov, A.V., and Yaguzhinskii, L.S., Biofizika, 2003, vol. 48, no. 2, pp. 197–200.
Klimontovich, Yu.L., Statisticheskaya fizika (Statistical Physics), Moscow: Nauka, 1982.
Vuks, M.F. and Shurupova, L.V., Opt. Commun., 1972, vol. 5, no. 4, pp. 277–278.
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Original Russian Text © S.M. Pershin, A.F. Bunkin, M.Ya. Grishin, V.N. Lednev, N.P. Palmina, 2016, published in Doklady Akademii Nauk, 2016, Vol. 466, No. 2, pp. 184–187.
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Pershin, S.M., Bunkin, A.F., Grishin, M.Y. et al. Nonmonotonic concentration dependences of elastic light scattering and its fluctuations in aqueous solutions. Dokl Phys Chem 466, 19–22 (2016). https://doi.org/10.1134/S0012501616010061
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DOI: https://doi.org/10.1134/S0012501616010061