Abstract
Obtaining dissociated zircon (a mixture of associated dioxides of zirconium and silicon (ZrO2, SiO2) by sintering ZrSiO4 with MgO and the subsequent leaching of the forming pitch by concentrated hydrochloric acid is studied. The mechanism of sintering of the ZrSiO4 + MgO mixture is established based on laboratory investigations. The optimal parameters of the process (the molar ratio of components and the temperature and duration of heating at the final temperature) for the maximal transformation of zircon into zirconium dioxide are determined.
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Simonov, Yu.A., Kritskii, A.A., Rychkov, V.N., and Tomashov, V.A., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 2009, no. 5, pp. 24–27.
Baryshnikov, N.V., Geger, V.E., Denisova, I.D., et al., Metallurgiya tsirkoniya i gafniya (Metallurgy of Zirconium and Hafnium), Nekhamkin, A.G., Ed., Moscow: Metallurgiya, 1979.
D. Nel, Republic of South Africa Patent 95101439/25, 1999.
Akhmetov, T.G., Khimicheskaya tekhnologiya neorganicheskikh veshchestv (Chemical Technology of Inorganic Substances), Moscow: Khimiya, 1998.
Rakov, E.G., Ftoridy ammoniya (Ammonium Fluorides), Moscow: Neorganicheskaya Khimiya, 1988.
Hossain, D. and Brett, N.H., Trans. Brit. Ceram. Soc, 1969, vol. 68, no. 4, pp. 145–150.
Reddy, S.R. and Mandai, G., Trans. Indian Ceram. Soc, 1975, vol. 34, no. 1, pp. 1–7.
Berezhnoi, A.S.,, in Mnogokomponentnye sistemy okislov (Multicomponent Oxide Systems), Kiev: Naukova Dumka, 1970.
Libenson, G.A., Lopatin, V.Yu., and Komarnitskii, G.V., Protsessy poroshkovoi metallurgii (Processes of Powder Metallurgy), Moscow: MISiS, 2002.
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Original Russian Text © Yu.A. Simonov, A.A. Kritskii, V.N. Rychkov, V.A. Tomashov, 2010, published in Izvestiya VUZ. Tsvetnaya Metallurgiya, 2010, No. 2, pp. 52–56.
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Simonov, Y.A., Kritskii, A.A., Rychkov, V.N. et al. Determination of optimal conditions for obtaining a mixture of associated dioxides of zirconium and silicon by sintering of ZrSiO4 with MgO. Russ. J. Non-ferrous Metals 51, 140–143 (2010). https://doi.org/10.3103/S1067821210020124
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DOI: https://doi.org/10.3103/S1067821210020124