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Increasing the Lifetime of Water Transportation Vehicles by Using Multifunctional Composites with a Polymer Matrix, Ultradisperse Diamond, and Discrete Fibrous Filler

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Abstract

Epoxy resin polymer composites with improved mechanical and thermophysical properties have been developed. To improve the material characteristics, an ultradisperse diamond and a multifunctional discrete fibrous (polyester–viscose–elastane) filler are added to the epoxy oligomer. The following properties of the composites are studied: hardness, residual stress, and thermal coefficients of linear expansion. It is established that the optimal concentration is in the range of q = 0.02–0.03 wt % relative to 100 wt % of the epoxy matrix for the multifunctional discrete fibrous filler and 0.05 wt % per 100 wt % of the epoxy matrix for the ultradisperse diamond. The models of formation of the structure of composites during the cross-linking process are proposed. They imply the presence of a polymer in the composites, an additional filler in the form of fibers, and a third structure in the form of external surface layers that are formed around the fibers in the polymerization process. The models illustrate the formation of the structure of composites at the micro-, meso-, and macroscopic levels.

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Notes

  1. Hereinafter, the composition of materials is given in wt %.

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ACKNOWLEDGMENTS

We express our sincere gratitude to O.O. Shul’zhenko, the corresponding member of the National Academy of Sciences of Ukraine, for the assistance in acquiring ultradisperse diamond obtained by detonation synthesis at the V. Bakul Institute for Superhard Materials, National Academy of Sciences of Ukraine, for the use as a filler during the formation of epoxy materials. This made it possible to conduct a series of experiments for the development of a modified epoxy binder, as well as to continue accumulation of research data on the formation of new matrices for the further production of superhard materials.

Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Kherson State Maritime Academy, Kherson, Ukraine

    A. V. Buketov, Yu. M. Shulga & O. M. Bezbakh

  2. V. Bakul Institute for Superhard Materials, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    I. P. Fesenko

  3. Ternopil Ivan Puluj National Technical University, Ternopil, Ukraine

    O. A. Pastukh

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  1. A. V. Buketov
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  2. Yu. M. Shulga
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  3. I. P. Fesenko
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  4. O. M. Bezbakh
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Correspondence to A. V. Buketov, I. P. Fesenko or O. A. Pastukh.

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Buketov, A.V., Shulga, Y.M., Fesenko, I.P. et al. Increasing the Lifetime of Water Transportation Vehicles by Using Multifunctional Composites with a Polymer Matrix, Ultradisperse Diamond, and Discrete Fibrous Filler. J. Superhard Mater. 46, 40–54 (2024). https://doi.org/10.3103/S1063457624010027

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