Abstract
We have investigated sorption of hydrochloric acid with saponite of the Varvarovskii deposit, Khmelnitsky region (Ukraine) against various salt backgrounds in the solution, varied by an addition of sodium chloride. Information has been obtained on desorption of cations of Na+, K+, Ca2+, Mg2+, Fen+, Al3+ from saponite at different acidity of the equilibrium solution. It has been found out that at the pH of the equilibrium solution more than 3.4 its substantial pollution by cations being desorbed from the material does not occur. We have determined the composition of the cation-exchange complex and its overall capacity. The effect of anomalously low desorption of singly charged cations have been detected.
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Ostapenko, V.T., Tarasevich, Yu.I., and Kulishenko, A.E., and Sinel’nik, N.A., Application of Natural Mineral Sorbents for Intensification of the Coagulation Process, Khimiya i Tekhnologiya Vody, 1990, vol. 12, no. 9, pp. 819–821.
Tarasevich, Yu.I., Polyakova, V.E., Ivanova, Z.G. and Trifonova, M.Yu., The Composition and Thermal Resistance of Hydrates of Exchange Cations of Saponite, ibid., 2011, vol. 33, no. 4, pp. 381–391.
Pshinko, G.N., Kobets, S.A., Bogolepov, A.A., and Goncharuk, V.V., Purification of Waters Containing Uranium with Saponite Clay, ibid., 2010, vol. 37, no. 1, pp. 20–29.
Ganzyuk, A.Ya. and Yasinovich, Yu.O., Research of Adsorption Properties of Saponite Modified by Cations of Multivalent Metals, Visn. Khmenits. Nats. Un-tu, 2010, no. 1, pp. 230–235.
Trifonova, M.Yu., Dolenko, S.A., Tarasevich, Yu.I., and Bondarenko, S.V., Adsorption of Organic Anions from Aqueous Solutions with Layer Silicates by Substituted Cation Polyelectrolyte, Khimiya i Tekhnologiya Vody, 2011, vol. 33. no. 5, pp. 477–487.
Polyakov, V.E., Tarasevich, Yu.I., Kosorukova, and A.A., Hrytsyk, V.E., Composition and Properties of Ukraine’s Saponites, Ukr. Khim. Zhurn., 2011, vol. 77, no. 2, pp. 95–99.
Hrytsyk, V.E., Osadochnye porody i rudy (Sedimentary Rocks and Ores), Kiev: Nauk. Dumka, 1984.
Dmitrenko, Yu.A. and Mamchenko, A.V., Assessment of Sorption Properties of Saponite with Respect to Fluoride Ions, Khimiya i Tekhnologiya Vody, 2012, vol. 34, no. 6, pp. 477–487.
Shtrubel, G. and Zimmer, Z. Kh., Mineralogicheskii slovar’, (Mineralogical Dictionary), Moscow: Nedra, 1987.
Bolshaya sovetskaya entsiklopedia (Great Soviet Encyclopedea), Moscow: Sov. Entsyklopedia, 1975.
Polyakov, V.E. and Tarasevich, Yu.I., Ion Exchange Equilibriums Involving Singly Charged Cations on Saponite, Khimiya i Tekhnologiya Vody, 2012, vol. 34, no. 1, pp. 18–27.
Goncharuk, V.V., SOS: Drinking Water, ibid., 2010, vol. 32, no. 5, pp. 463–512.
pH-metr-millivoltmetr pH-150MA. Rukovodstvo po ekspluatatsii MTIC 2.840.858PE (A pH-150 pH-meter-millivoltmeter (Operation Instruction MTIS 2.840.858RE).
Lur’e, Yu.Yu., Unifitsirovannye metody analiza vod (Unified Methods of Analyzing Waters), Moscow: Khimiya, 1973.
Khavezov, I. and Tsaliev, D., Atomnyi-absobtsionnyi analiz (Atomic-Absoption Analysis), Leningrad: Khimiya, 1983.
Mamchenko, A.V. and Valuiskaya, E.A., Analiz kislotno-osnovnogo ravnovesiya na karboksilnykh ionitakh v ramkakh binominal’nogo raspredeleniya (The Analysis of Acid-Basic Equilibrium on Carboxylic Ion-Exchangers within the Framework of the Model of Binomial Distribution), Khimiya i Tekhnologiya Vody, 1997, vol. 19, no. 6, pp. 653–572.
Mamchenko, A.V. and Valuiskaya, E.A., Analysis of the Curves of Poteniometric Titration of Carboxyl Ion-Exchangers in Terms of the Theory of Exchange Equilibriums, ibid., 1998, vol. 20, no. 5, pp. 451–460.
Tarasevich, Yu.I., Stroenie i khimiya poverkhnosti sloistykh silikatov (The Structure and Chemistry of the Surface of Layer Silicates), Kiev: Nauk. Dumka, 1988.
Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (The Manual on Analytical Chemistry), Moscow: Khimiya, 1989.
Kul’skii, L.A., Goronovskii, I.T., Koganovskii, A.M., and Shevchenko, M.A., Spravochnik po svoistvam, metodam analiza i ochistki vody (The Manual on Properties, Methods of Analysis and Water Treatment), Kiev: Nauk. Dumka, 1980.
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Original Russian Text © Yu.A. Dmitrenko, A.V. Mamchenko, 2013, published in Sverkhtverdye Materialy, 2013, Vol. 35, No. 1, pp. 29–42.
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Dmitrenko, Y.A., Mamchenko, A.V. Sorption of hydrochloric acid with saponite. J. Water Chem. Technol. 35, 15–22 (2013). https://doi.org/10.3103/S1063455X13010037
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DOI: https://doi.org/10.3103/S1063455X13010037