Abstract
An analysis is performed for experimental data on the rates of reactions describing ethane pyrolysis. A 1–25% level of accuracy is obtained, which greatly exceeds the world value. A critical analysis is also performed for existing theoretical models of the rates of chemical reactions.
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REFERENCES
Mukhina, T.N., Barabanov, N.L., Babash, S.E., et al., Piroliz uglevodorodnogo syr’ya (Pyrolysis of Hydrocarbon Feed), Moscow: Khimiya, 1987.
Leatherd, D.A. and Purnell, J.H., Ann. Rev. Phys. Chem., 1970, vol. 21, p. 197.
Davidson, D.F. and Hanson, R.K., Int. J. Chem. Kinet., 2004, vol. 36, p. 510.
Westley, F., Tables of Recommended Rate Constants for Chemical Reactions Occurring in Combustion, National Standard Reference Data Series, NSRDS-NB 67, 1980.
NIST Chemical Kinetics Database, Standard Reference Database 17-2Q98, Gaithersburg: NIST, 1998.
Burkholder, J.B., Sander, S.P., Abbatt, J.P.D., et al., Chemical kinetics and photochemical data for use in atmospheric studies, Eval. no. 18, Pasadena: JPL, 2015.
GRI-Mech. www.me.berkeley.edu/gri_mech.
Baulch, D.L., Bowman, C.T., Cobos, C.J., et al., J. Phys. Chem. Ref. Data, 2005, vol. 34, no. 3, p. 757.
Ibragimova, L.B, Smekhov, G.D., and Shatalov, O.P., Fiz.-Khim. Kinet. Gaz. Din., 2009, vol. 8, p. 1.
Mass, U. and Warnatz, J., Combust. Flame, 1988, vol. 74, p. 53.
Miller, J.A., Prog. Energy Combust. Sci., 1989, vol. 15, no. 4, p. 287.
Belov, A.A. and Kalitkin, N.N., Zh. Vychislit. Mat. Mat. Fiz., 2020, vol. 60, no. 7, p. 105.
Harris, F.E., Ann. Rev. Phys. Chem., 1972, vol. 23, no. 1, p. 415.
Murrell, J.N., Carter, S., Farantos, S.C., et al., Molecular Potential Energy Functions, New York: Wiley, 1984.
Robinson, P.G. and Holbrook, K.A., Monomolecular Reactions, New York: Wiley, 1972.
Nurislamova, L.F., Stoyanovskaya, O.P., Stadnichenko, O.A., et al., Chem. Prod. Process Model., 2014, vol. 9, no. 2, p. 143.
Snytnikov, V.N., Snytnikov, P.V., Amosov, Yu.I., et al., Kinet. Catal., 2010, vol. 51, p. 10.
Belov, A.A., Kalitkin, N.N., and Kozlitin, I.A., Fusion Eng. Des., 2019, vol. 141, p. 51.
TEFIS Database. http://tefis.keldysh.ru.
Funding
This work was supported by the Russian Science Foundation, project no. 16-11-10001-P.
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Translated by O. Zhukova
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Topor, O.I., Belov, A.A. & Fedorov, I.A. Refining the Rates of Reactions Describing Ethane Pyrolysis. Bull. Russ. Acad. Sci. Phys. 85, 196–200 (2021). https://doi.org/10.3103/S106287382102026X
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DOI: https://doi.org/10.3103/S106287382102026X