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Mössbauer study of compounds of Cu3 − x Fe x SnS4 and Cu2Fe1 −x Zn x SnS4 systems

  • Proceedings of the XIth International Conference “Mössbauer Spectroscopy and Its Applications”
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

A Mössbauer study of the structural and charge states of 57Fe and 119Sn atoms in the compounds of Cu3 −x Fe x SnS4 and Cu2Fe1 − x Zn x SnS4 systems was performed. It was shown that the iron atoms in the compounds of both systems were in the divalent and trivalent states occupying the tetrahedral positions of the structure. The character of the changes of the degree of covalency of the Fe2+-S, Fe3+-S and Sn4+-S bonds during the isomorphic substitution in the systems was established.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119992, Russia

    V. S. Rusakov, N. I. Chistyakova, I. A. Burkovsky & A. M. Gapochka

  2. Institute of the Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, Moscow, 109017, Russia

    T. L. Evstigneeva

Authors
  1. V. S. Rusakov
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  2. N. I. Chistyakova
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  3. I. A. Burkovsky
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  4. A. M. Gapochka
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  5. T. L. Evstigneeva
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Corresponding author

Correspondence to V. S. Rusakov.

Additional information

Original Russian Text © V.S. Rusakov, N.I. Chistyakova, I.A. Burkovsky, A.M. Gapochka, T.L. Evstigneeva, 2010, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2010, Vol. 74, No. 3, pp. 420–424.

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Rusakov, V.S., Chistyakova, N.I., Burkovsky, I.A. et al. Mössbauer study of compounds of Cu3 − x Fe x SnS4 and Cu2Fe1 −x Zn x SnS4 systems. Bull. Russ. Acad. Sci. Phys. 74, 389–393 (2010). https://doi.org/10.3103/S1062873810030226

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  • DOI: https://doi.org/10.3103/S1062873810030226

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