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Study of Anticorrosive Action of Alkylphosphonic Acid Solutions in Monoethanolamine Based on the Formation of Chelate Complexes With Iron Ions

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Steel in Translation Aims and scope

Abstract

A study was carried out of the anti-corrosion effect of two acids on St3 steel: nitrilotrimethylenephosphonic (NTP) and oxyethylidenediphosphonic (OEDPA), in combination with monoethanolamine. The dependence of the inhibitory effect of NTP and OEDPA complexes with monoethanolamine on their concentration in solution was studied. The possibility of their use as corrosion inhibitors of low-carbon steel has been shown.

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REFERENCES

  1. Erofeev, M.N., Spiryagin, V.V., Pankin, D.A., Chmykhalo, A.I., Lesyuk, E.A., and Chelnokov, A.V., Protection against corrosion and restoration of heat exchanger surfaces during repair and operation, J. Mach. Manuf. Reliab., 2020, vol. 49, no. 10, pp. 878–883. https://doi.org/10.3103/s1052618820100052

    Article  Google Scholar 

  2. Kravchenko, I.N., Kuznetsov, Yu.A., Sirotov, A.V., Glinskii, M.A., and Petrovskaya, E.A., Anticorrosive protection of heat-exchange equipment of agro-industrial complex processing plants by repair and restoration coatings, Vestn. Mosk. Gos. Agroinzh. Univ. V.P. Goryachkina, 2019, no. 3, pp. 51–58.

  3. Grazion, S., Spiryagin, V., Erofeev, M., Kravchenko, I., Kuznetsov, Yu., Mukomela, M., Velichko, S., Ašonja, A., and Kalashnikova, L., Diagnostics of defect detection in the initial stages of structural failure using the acoustic emission method of control, Appl. Eng. Lett.: J. Eng. Appl. Sci., 2022, vol. 7, no. 2, pp. 45–53. https://doi.org/10.18485/aeletters.2022.7.2.1

    Article  Google Scholar 

  4. Semashko, N.A., Shport, V.I., Mar’in, B.N., Pekarsh, A.I., Murav’ev, V.I., and Evstigneev, A.I., Akusticheskaya emissiya v eksperimental’nom materialovedenii (Acoustic Emission in Experimental Materials Science), Moscow: Mashinostroenie, 2002.

  5. Kharebov, V.G., Zhukov, A.V., and Kuz’min, A.N., Practical evaluation of the acoustic emission method on process gas pipelines, Mire Nerazrushayushchego Kontrolya, 2008, no. 3, pp. 24–26.

  6. Zhukov, A.V., Kuz’min, A.N., and Styukhin, N.F., Inspection of pipelines using the acoustic emission method, Mire Nerazrushayushchego Kontrolya, 2009, no. 1, pp. 29–31.

  7. Golovin, V.A., Kuznets, V.T., Kublitskii, K.V., and Il’in, A.B., Method of protection against corrosion and scale deposits and restoration of tubes of heat-exchange equipment and a device for carrying out this method, RF Patent 2186633, 2002.

  8. Horn, M.J., Pipe coating system and method, RF Patent 2343999, 2009.

  9. Curran, E.L., Solving heat exchanger tube problems with thin film thermally conductive coating applications and novel tube and pipe cleaning as a precursor to coating application and NDT, Proc. Int. Conf. on Heat Exchanger Fouling and Cleaning VIII, Schladming, Austria: 2009, pp. 414–419.

  10. Pankin, D.A., Spiryagin, V.V., Chelnokov, A.V., and Chmykhalo, A.I., Method of protection against corrosion and scale deposits and restoration of tubes of heat-exchange equipment and a device for carrying out this method, 2019.

  11. Zhuang, Q., Geddis, P., Clements, B., and Ko, V., Corrosion-resistant coating development with potential application in equipment of low-temperature waste heat recovery, Can. J. Chem. Eng., 2018, vol. 96, no. 1, pp. 101–106. https://doi.org/10.1002/cjce.23019

    Article  CAS  Google Scholar 

  12. Altsybeeva, A.I. and Levin, S., Ingibitory korrozii metallov. Spravochnik (Metal Corrosion Inhibitors), Leningrad: Khimiya, 1968.

  13. Levashova, V.I., Yangirova, I.V., and Kazakova, E.V., Overview of corrosion inhibitors based on organoboron compounds, Sovrem. Probl. Nauki Obraz., 2014, no. 6, p. 21.

  14. Danyakin, N.V. and Sigida, A.A., Methods and mechanisms of application of corrosion inhibitors for metals and alloys, Elektronnyi Nauchn. Zh. Kurskogo Gos. Univ., 2017, no. 2, pp. 132–140.

  15. Stepin, S.N., Kuznetsova, O.P., Vakhin, A.V., and Khabibrakhmanov, B.I., Application of phosphorus-containing complexones and complexonates as metal corrosion inhibitors, Vestn. Kazanskogo Tekhnologicheskogo Univ., 2012, vol. 15, no. 13, pp. 88–98.

    Google Scholar 

  16. Kuznetsov, Yu.I., Role of complexation in corrosion inhibition, Zashch. Met., 2007, vol. 26, no. 6, pp. 954–964.

    Google Scholar 

  17. Kuznetsov, Yu.I. and Trunov, E.A., On the mechanism of inhibitory action of zincphosphonates in neutral media, Zh. Prikl. Khim., 1984, vol. 57, no. 3, pp. 498–504.

    CAS  Google Scholar 

  18. Kubicki, J., Kuczkovska, S., Falevicz, P., and Pyrvahov, B., Investigations on adsorptive and inhibitive properties of aminomethylenephosphonic anide and their synergism with other compounds, 6th Europ. Symp. on Corrosion Inhibitors, Ferrara, Italy: 1985, no. 2, pp. 1131–1143.

  19. Noda, D., Saito, N., Yamada, I., and Tagaya, M., Investigation of adsorptive orientation state change of anionic porphyrin with the hydrolysis reaction of α-tricalcium phosphate, CrystEngComm, 2022, vol. 24, no. 22, pp. 4008–4012. https://doi.org/10.1039/d2ce00505k

    Article  CAS  Google Scholar 

  20. Petrov, S.A., Method of preparation of monoethanolamine salts of phosphonic acids, RF Patent 2529194, 2014.

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This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Correspondence to I. N. Kravchenko.

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Translated by I. Moshkin

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Zimovets, V.S., Kravchenko, I.N., Danyakin, N.V. et al. Study of Anticorrosive Action of Alkylphosphonic Acid Solutions in Monoethanolamine Based on the Formation of Chelate Complexes With Iron Ions. Steel Transl. 53, 1200–1204 (2023). https://doi.org/10.3103/S0967091224700116

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