Abstract
A brief review of publications by foreign researchers on the study of the structure, phase composition and properties of five-component high-entropy alloys (HEAs) in different structural states in a wide temperature range over the past two decades has been made. HEAs attract the attention of scientists with their unique and unusual properties. Difficulties in conducting a comparative analysis and summarizing data due to different methods for obtaining HEAs, modes of mechanical tests for uniaxial compression and tension, sample sizes and shapes, types of heat treatments, and phase composition (BCC and FCC lattices) are noted. It is noted that HEAs with the BCC lattice have predominantly high strength and low ductility, while HEAs with the FCC lattice have low strength and increased ductility. It is shown that a significant increase in the properties of HEA FeMnCoCrNi with the FCC lattice can be achieved by doping with boron and optimizing the parameters of thermomechanical treatment when doping with carbon in an amount of 1% (at %). The deformation curves analyzed in the temperature range of –196…800°C indicate an increase in the yield strength with a decrease in the grain size from 150 to 5 μm. As the temperature decreases, the yield strength and relative elongation increase. The effect of the deformation rate on the mechanical properties consists in an increase in the tensile strength and yield strength, which is most noticeable at high rates of 10–2–103 s–1. The features of the deformation behavior of HEAs in single- and polycrystalline states are noted. The complex of high operational properties of HEAs provides the possibility of their application in various industries. The prospects for using energy treatments to modify surface layers and further improve the HEAs properties are noted.
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REFERENCES
Yeh, J.W., Chen, S.K., Lin, S.J., Gan, J.Y., Chin, T.S., Shun, T.T., Tsau, C.H., and Chang, S.Y., Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes, Adv. Eng. Mater., 2004, vol. 6, no. 5, pp. 299–303. https://doi.org/10.1002/adem.200300567
Zhang, Y., Yang, X., and Liaw, P.K., Alloy design and properties optimization of high-entropy alloys, JOM, 2012, vol. 64, no. 7, pp. 830–838. https://doi.org/10.1007/s11837-012-0366-5
Yeh, J.W., Recent progress in high-entropy alloys, Ann. Chim. Sci. Mater., 2006, vol. 31, no. 6, pp. 633–648. https://doi.org/10.3166/acsm.31.633-648
Yeh, J.W., Alloy design strategies and future trends in high-entropy alloys, JOM, 2013, vol. 65, no. 12, pp. 1759–1771. https://doi.org/10.1007/s11837-013-0761-6
Zhang, L.S., Ma, G.-L., Fu, L.-C., and Tian, J.-Y., Recent progress in high-entropy alloys, Adv. Mater. Res., 2013, vols. 631–632, pp. 227–232. https://doi.org/10.4028/www.scientific.net/AMR.631-632.227
Zhang, Y., Zuo, T.T., Tang, Z., Gao, M.C., Dahmen, K.A., Liaw, P.K., and Lu, Z.P., Microstructures and properties of high-entropy alloys, Progr. Mater. Sci., 2014, vol. 61, pp. 1–93. https://doi.org/10.1016/j.pmatsci.2013.10.001
Gali, A. and George, E.P., Tensile properties of high- and medium-entropy alloys, Intermetallics, 2013, vol. 39, pp. 74–78. https://doi.org/10.1016/j.intermet.2013.03.018
Cantor, B., Chang, I.T.H., Knight, P., and Vincent, A.J.B., Microstructural development in equiatomic multicomponent alloys, Mater. Sci. Eng., A, 2004, vol. 375–377, pp. 213–218. https://doi.org/10.1016/j.msea.2003.10.257
Jiang, L., Lu, Y., Dong, Y., Wang, T., Cao, Z., and Li, T., Annealing effects on the microstructure and properties of bulk high-entropy CoCrFeNiTi0.5 alloy casting ingot, Intermetallics, 2014, vol. 44, pp. 37–43. https://doi.org/10.1016/j.intermet.2013.08.016
Shun, T.-T., Chang, L.-Y., and Shiu, M.-H., Microstructure and mechanical properties of multiprincipal component CoCrFeNiMox alloys, Mater. Charact., 2012, vol. 70, pp. 63–67. https://doi.org/10.1016/j.matchar.2012.05.005
Senkov, O.N. and Miracle, D.B., A topological model for metallic glass formation, J. Non-Cryst. Solids, 2003, vol. 317, nos. 1–2, pp. 34–39. https://doi.org/10.1016/S0022-3093(02)01980-4
Takeuchi, A., Chen, N., Wada, T., Yokoyama, Y., Kato, H., Inoue, A., and Yeh, J.W., Pd20Pt20Cu20Ni20P20 high-entropy alloy as a bulk metallic glass in the centimeter, Intermetallics, 2011, vol. 19, no. 10, pp. 1546–1554. https://doi.org/10.1016/j.intermet.2011.05.030
Singh, S., Wanderka, N., Murty, B.S., Glatzel, U., and Banhart, J., Decomposition in multi-component AlCoCrCuFeNi high-entropy alloy, Acta Mater., 2011, vol. 59, no. 1, pp. 182–190. https://doi.org/10.1016/j.actamat.2010.09.023
George, E.P., Curtin, W.A., and Tasan, C.C., High entropy alloys: A focused review of mechanical properties and deformation mechanisms, Acta Mater., 2020, vol. 188, pp. 435–474. https://doi.org/10.1016/j.actamat.2019.12.015
Miracle, D.B. and Senkov, O.N., A critical review of high entropy alloys and related concepts, Acta Mater., 2017, vol. 122, pp. 448–511. https://doi.org/10.1016/j.actamat.2016.08.081
Raghavan, R., Kirchlechner, C., Jaya, B.N., Feuerbacher, M., and Dehm, G., Mechanical size effects in a single crystalline equiatomic FeCrCoMnNi high entropy alloy, Scr. Mater., 2017, vol. 129, pp. 52–55. https://doi.org/10.1016/j.scriptamat.2016.10.026
Zhou, Y.J., Zhang, Y., Wang, Y.L., and Chen, G.L., Solid solution alloys of AlCoCrFeNiTix with excellent room-temperature mechanical properties, Appl. Phys. Lett., 2007, vol. 90, p. 181904. https://doi.org/10.1063/1.2734517
Qiao, J.W., Ma, S.G., Huang, E.W., Chuang, C.P., Liaw, P.K., and Zhang, Y., Microstructural characteristics and mechanical behaviors of AlCoCrFeNi high-entropy alloys at ambient and cryogenic temperature, Mater. Sci. Forum, 2011, vol. 688, pp. 419–425. https://doi.org/10.4028/www.scientific.net/MSF.688.419
Gludovatz, B., Hohenwarter, A., Catoor, D., Chang, E.H., George, E.P., and Ritchie, R.O., A fracture-resistant high-entropy alloy for cryogenic applications, Science, 2014, vol. 345, no. 6201, pp. 1153–1158. https://doi.org/10.1126/science.1254581
Seol, J.B., Bae, J.W., Li, Z., Han, J.Ch., Kim, J.G., Raabe, D., and Kim, H.S., Boron doped ultrastrong and ductile high-entropy alloys, Acta Mater., 2018, vol. 151, pp. 366–376. https://doi.org/10.1016/j.actamat.2018.04.004
Slone, C.E., Chakraborty, S., Miao, J., George, E.P., Mills, M.J., and Niezgoda, S.R., Influence of deformation induced nanoscale twinning and FCC-HCP transformation on hardening and texture development in medium-entropy CrCoNi alloy, Acta Mater., 2018, vol. 158, pp. 38–52. https://doi.org/10.1016/j.actamat.2018.07.028
Wu, Z., Bei, H., Pharr, G.M., and George, E.P., Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures, Acta Mater., 2014, vol. 81, pp. 428–441. https://doi.org/10.1016/j.actamat.2014.08.026
Otto, F., Dlouhy, A., Somsen, C., Bei, H., Eggeler, G., and George, E.P., The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy, Acta Mater., 2013, vol. 61, no. 15, pp. 5743–5755. https://doi.org/10.1016/j.actamat.2013.06.018
Wingley, D.A., Mechanical properties of materials at low temperatures, Cryogenics, 1968, vol. 8, no. 1, pp. 3–12. https://doi.org/10.1016/S0011-2275(68)80042-6
Yeh, J.W., Physical metallurgy of high-entropy alloys, JOM, 2015, vol. 67, no. 10, pp. 2254–226. https://doi.org/10.1007/s11837-015-1583-5
Okamoto, N.L., Fujimoto, S., Kambara, Y., Kawamura, M., Zhenghao, M.T.C., Matsunoshita, H., Tanaka, K., Inui, H., and George, E.P., Size effect, critical resolved shear stress, stacking fault energy, and solid solution strengthening in the CrMnFeCoNi high-entropy alloy, Sci. Rep., 2016, vol. 6, p. 35863. https://doi.org/10.1038/srep35863
Patriarca, L., Ojha, A., Sehitoglu, H., and Chumlyakov, Y.I., Slip nucleation in single crystal FeNiCoCrMn high entropy alloy, Scr. Mater., 2016, vol. 112, pp. 54–57. https://doi.org/10.1016/j.scriptamat.2015.09.009
Kireeva, I.V., Chumlyakov, Yu.I., Pobedennaya, Z.V., Kuksgausen, I.V., and Karaman, I., Orientation dependence of twinning in single crystalline CoCrFeMnNi high-entropy alloy, Mater. Sci. Eng., A, 2017, vol. 705, pp. 176–181. https://doi.org/10.1016/j.msea.2017.08.065
Wu, Z., Gao, Y.F., and Bei, H., Single crystal plastic behavior of a single-phase, face-center-cubic-structured, equiatomic FeNiCrCo alloy, Scr. Mater., 2015, vol. 109, pp. 108–112. https://doi.org/10.1016/j.scriptamat.2015.07.031
Park, J.M., Moon, J., Bae, J.W., Jang, M.J., Park, J., Lee, S., and Kim, H.S., Strain rate effects of dynamic compressive deformation on mechanical properties and microstructure of CoCrFeMnNi high-entropy alloy, Mater. Sci. Eng., A, 2018, vol. 719, pp. 155–163. https://doi.org/10.1016/j.msea.2018.02.031
Zhang, Z., Sheng, H., Wang, Z., Gludovatz, B., Zhang, Z., George, E.P., Yu, Q., Mao, S.X., and Ritchie, R.O., Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy, Nat. Commun., 2017, vol. 8, no. 1, p. 14390. https://doi.org/10.1038/ncomms14390
Laplanche, G., Kostka, A., Horst, O.M., Eggeler, G., and George, E.P., Microstructure evolution and critical stress for twinning in the CrMnFeCoNi high-entropy alloy, Acta Mater., 2016, vol. 118, pp. 152–163. https://doi.org/10.1016/j.actamat.2016.07.038
Varvenne, C., Luque, A., and Curtin, W.A., Theory of strengthening in fcc high entropy alloys, Acta Mater., 2016, vol. 118, pp. 164–176. https://doi.org/10.1016/j.actamat.2016.07.040
Shaysultanov, D.G., Salishchev, G.A., Ivanisenko, Yu.V., Zherebtsov, S.V., Tikhonovsky, M.A., and Stepanov, N.D., Novel Fe36Mn21Cr18Ni15Al10 high entropy alloy with bcc/B2 dual-phase structure, J. Alloys Compd., 2017, vol. 705, pp. 756–763. https://doi.org/10.1016/j.jallcom.2017.02.211
Meyers, M.A., Vohringer, O., and Lubarda, V.A., The onset of twinning in metals: A constitutive description, Acta Mater., 2001, vol. 49, no. 19, pp. 4025–4039. https://doi.org/10.1016/S1359-6454(01)00300-7
Zhu, Y.T., Liao, X.Z., and Wu, X.L., Deformation twinning in nanocrystalline materials, Progr. Mater. Sci., 2012, vol. 57, no. 1, pp. 1–62. https://doi.org/10.1016/j.pmatsci.2011.05.001
Senkov, O.N. and Semiatin, S.L., Microstructure and properties of a refractory high-entropy alloy after cold working, J. Alloys Compd., 2015, vol. 649, pp. 1110–1123. https://doi.org/10.1016/j.jallcom.2015.07.209
Chien-Chang, J., Ko-Kai, T., Wei-Lin, H., Ming-Hung, T., Che-Wei, T., Chun-Ming, L., Swe-Kai, C., Su-Jien, L., and Jien-Wei, Y., Solution strengthening of ductile refractory HfMoxNbTaTiZr high-entropy alloys, Mater. Lett., 2016, vol. 175, pp. 284–287. https://doi.org/10.1016/j.matlet.2016.03.133
Zamora, R.J., Uberuaga, B.P., Perez, D., and Voter, A.F., The modern temperature-accelerated dynamics approach, Ann. Rev. Chem. Biomol. Eng., 2016, vol. 7, pp. 87–110. https://doi.org/10.1146/annurev-chembioeng-080615-033608
Perez, D., Uberuaga, B.P., and Voter, A.F., The parallel replica dynamics method—Coming of age, Comput. Mater. Sci., 2015, vol. 100, pp. 90–103. https://doi.org/10.1016/j.commatsci.2014.12.011
Egami, T., Guo, W., Rack, P.D., and Nagase, T., Irradiation resistance of multicomponent alloys, Metall. Mater. Trans. A, 2014, vol. 45, pp. 180–183. https://doi.org/10.1007/s11661-013-1994-2
Kunce, I., Polanski, M., and Bystrzycki, J., Structure and hydrogen storage properties of a high entropy ZrTiVCrFeNi alloy synthesized using Laser Engineered Net Shaping (LENS), Int. J. Hydrogen Energy, 2013, vol. 38, no. 27, pp. 12180–12189. https://doi.org/10.1016/j.ijhydene.2013.05.071
Kao, Y.F., Chen, S.K., Sheu, J.H., Lin, J.T., Lin, W.E., Yeh, J.W., Lin, S.J., Lion, T.H., and Wang, C.W., Hydrogen storage properties of multi-principal-component CoFeMnTixVyZrz alloys, Int. J. Hydrogen Energy, 2010, vol. 35, no. 17, pp. 9046–9059. https://doi.org/10.1016/j.ijhydene.2010.06.012
Firstov, S.A., Gorban’, V.F., Danilenko, N.I., Karpets, M.V., Andreev, A.A., and Makarenko, E.S., Thermal stability of superhard nitride coatings from high-entropy multicomponent Ti–V–Zr–Nb–Hf alloy, Powder Metall. Met. Ceram., 2014, vol. 52, pp. 560–566. https://doi.org/10.1007/s11106-014-9560-z
Pogrebnjak, A.D., Bagdasaryan, A.A., Yakushchenko, I.V., and Beresnev, V.M., The structure and properties of high-entropy alloys and nitride coatings based on them, Russ. Chem. Rev., 2014, vol. 83, pp. 1027–1061. https://doi.org/10.1070/RCR4407
Zaguliaev, D., Gromov, V., Rubannikova, Y., Konovalov, S., Ivanov, Y., Romanov, D., and Semin, A., Structure and phase states modification of AL-11SI-2CU alloy processed by ion-plasma jet and pulsed electron beam, Surf. Coat. Technol., 2020, vol. 383, p. 125246. https://doi.org/10.1016/j.surfcoat.2019.125246
Zhang, C., Lv, P., Xia, H., Yang, Z., Konovalov, S., Chen, X., and Guan, Q., The microstructure and properties of nanostructured Cr–Al alloying layer fabricated by high-current pulsed electron beam, Vacuum, 2019, vol. 167, pp. 263–270. https://doi.org/10.1016/j.vacuum.2019.06.022
Konovalov, S.V., Komissarova, I.A., Ivanov, Yu.F., Gromov, V.E., and Kosinov, D.E., Structural and phase changes under electropulse treatment of fatigue-loaded titanium alloy VT1-0, J. Mater. Res. Technol., 2019, vol. 8, no. 1, pp. 1300–1307. https://doi.org/10.1016/j.jmrt.2018.09.008
Konovalov, S., Ivanov, Y., Gromov, V., and Panchenko, I., Fatigue-induced evolution of AISI 310S steel microstructure after electron beam treatment, Materials, 2020, vol. 13, no. 20, p. 4567. https://doi.org/10.3390/ma13204567
Romanov, D., Moskovskii, S., Konovalov, S., Sosnin, K., Gromov, V., and Ivanov, Y., Improvement of copper alloy properties in electro-explosive spraying of ZnO–Ag coatings resistant to electrical erosion, J. Mater. Res. Technol., 2019, vol. 8, no. 6, pp. 5515–5523. https://doi.org/10.1016/j.jmrt.2019.09.019
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This work was carried out with the support by a grant from Russian Science Foundation (project 20-19-00452).
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Osintsev, K.A., Gromov, V.E., Konovalov, S.V. et al. High Entropy Alloys: Structure, Mechanical Properties, Deformation Mechanisms and Applications. Steel Transl. 52, 167–173 (2022). https://doi.org/10.3103/S0967091222020176
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DOI: https://doi.org/10.3103/S0967091222020176