Oxidation of molten impurities in converters by means of combustion flames: Thermodynamic principles. 2. Interaction of flame with metal and slag in converter bath

Abstract

Thermodynamic analysis is applied to the physicochemical processes in the converter bath when intensifying bath heating by means of gas–oxygen burners. In the converter’s working space, when the combustion flames interact with the liquid bath, the oxygen and natural gas supplied through the burners and the oxygen supplied through the tuyere interact in a bubbling slag–metal emulsion. As a result, iron and the impurities are oxidized. The use of such burners changes the gas composition: not only O₂, CO, and CO₂ are present, but also H₂ and H₂O, which changes the oxidative capacity of the gas phase. The presence of solid carbon (for example, pulverized coal) in the burner flame may be used to control and intensify the combustion process. Combustion is most effective in the oxidation of carbon to CO when the oxygen excess is less than 1.0. The oxidation conditions of carbon in the melt change with variation in its activity as a function of its concentration and the temperature. The equilibrium in the M–O–C system may be described by the oxygen partial pressure ${P_{{O_2}}}$, which may be regarded as a universal characteristic. In addition, the equilibrium may be assessed on the basis of the associated ratios ${P_{CO}}/{P_{C{O_2}}}$ and ${P_{{H_2}}}/{P_{{H_2}O}}$ It is found that iron may be oxidized by oxygen and, to some extent, by carbon dioxide. At 1600–2000 K, there is practically no oxidation of iron by steam. The carbon dissolved in the steel is oxidized relatively effectively by oxygen and carbon dioxide until its concentration is less than 0.1% C. Steam oxidizes carbon very poorly and is not much more effective with manganese and silicon. With increase in temperature, the rate at which carbon dissolved in steel is oxidized by oxygen increases, while the oxidation rate of manganese and silicon falls. Above 1800 K, superoxidized slag with a high FeO content actively oxidizes silicon (to <2% Si), manganese (to <1% Mn), and carbon (to <1.5% C).