Skip to main content
SpringerLink
Log in

Assessment of Kinetic Indicators of Coke Formation in the Course of Steam Cracking with the Use of Inhibitors

  • Published:
Solid Fuel Chemistry Aims and scope Submit manuscript

Abstract

The decrease of coke formation in the steam cracking of hydrocarbon raw materials was studied with the use of the following inhibitors: dimethyl disulfide (DMDS), dimethyl sulfide (DMS), and dimethyl sulfoxide (DMSO). The influence of various factors on coke formation has been established: the amount of inhibitor (0–300 ppm), process temperature (750–600°C) and the water vapor/raw material ratio (0–1 kg/kg). The kinetic parameters of the process of reducing coke formation have been calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

REFERENCES

  1. Albright, L.F., McConnell, C.F., and Welther, K., in Thermal Hydrocarbon Chemistry, Advances in Chemistry Series, Washington, DC: American Chemical Society, 1979, no. 183, p. 175.

  2. Zhagfarov, F.G., Karpov, A.B., and Kozlov, A.M., Osnovnye protsessy glubokoi khimicheskoi pererabotki prirodnogo gaza (The Main Processes of Deep Chemical Processing of Natural Gas), Moscow: Bukstrim, 2013.

  3. Karpov, A.B., Zhagfarov, F.G., and Kozlov, A.M., Neftepererabotka i Neftekhimiya. Nauchno-Tekhnicheskie Dostizheniya i Peredovoi Opyt, 2015, no. 11, p. 2.

  4. Karpov, A.B., Zhagfarov, F.G., and Kozlov, A.M., Territ. Neftegaz, 2015, no. 11, p. 100.

  5. Pavlova, I.V., Polovnyak, V.K., Khabibrakhmanov, A.F., Starkov, A.K., and Chuklova, M.E., Vestn. Kazan. Tekhnol. Univ., 2009, no. 1, p. 73.

  6. Zhagfarov, F.G., Doctoral Sci. (Eng.) Dissertation, Moscow: Gubkin Russian State University of Oil and Gas (National Research University), 2005.

  7. Zhagfarov, F.G., Karpov, A.B., Vasilenko, V.Yu., and Sorokin, B.A., NefteGazoKhimiya, 2014, no. 4, p. 24.

  8. Porter, G. and Gard, A., The Mechanism of Carbon Formation, Paris: Mem. AGB, no. 16, p. 1954.

  9. Geniesse, J.C. and Raymond, R., Ind. Eng. Chem., 1930, no. 25, p. 1274.

  10. Khabibrakhmanov, A.F., Cand. Sci. (Eng.) Dissertation, Kazan: Kazan State Technological Univ., 2010.

  11. Lapidus, A.L., Golubeva, I.A., and Zhagfarov, F.G., Gazokhimiya. Uchebnoe posobie (Gas Chemistry. Student’s Book), Moscow: TsentrLit-NefteGaz, 2008.

Download references

Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

Author information

Authors and Affiliations

  1. Gubkin State University of Oil and Gas, 119991, Moscow, Russia

    A. B. Karpov & F. G. Zhagfarov

  2. Topchiev Institute of Petrochemical Synthesis (TIPS), Russian Academy of Sciences, 119991, Moscow, Russia

    A. M. Gyul’maliev

Authors
  1. A. B. Karpov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. G. Zhagfarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Gyul’maliev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to A. B. Karpov, F. G. Zhagfarov or A. M. Gyul’maliev.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by V. Makhlyarchuk

Publisher’s Note.

Allerton Press remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Karpov, A.B., Zhagfarov, F.G. & Gyul’maliev, A.M. Assessment of Kinetic Indicators of Coke Formation in the Course of Steam Cracking with the Use of Inhibitors. Solid Fuel Chem. 57 (Suppl 1), S6–S11 (2023). https://doi.org/10.3103/S0361521923070030

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S0361521923070030

Keywords:

Search

Navigation