Abstract
The pyrolysis of two types of raw materials of plant origin (sawdust and sunflower husks), components of the organic matter of biomass (hemicellulose, cellulose, and lignin), and model mixtures prepared from components in accordance with their fractions in the raw materials was studied. Pyrolysis of the materials was carried out using TGA and a laboratory setup with a fixed bed reactor. The distribution and composition of the products were determined at pyrolysis temperatures of 350, 425, 500, and 575°C. Experimental data obtained with the biomass samples and model mixtures were compared with calculated values obtained based on the pyrolysis of individual components and their fractions in the biomass. The possibility of predicting the distribution of pyrolysis products depending on the component composition was investigated. The influence of intercomponent interaction in biomass on the yield and composition of pyrolysis products was revealed.
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REFERENCES
Bhattacharjee, N. and Biswas, A.B.J., Environ. Chem. Eng., 2019, vol. 7, no. 1, p. 102903. https://doi.org/10.1016/j.jece.2019.102903
Diblasi, C., Prog. Energy Combust. Sci., 2008, vol. 34, no. 1, p. 47. https://doi.org/10.1016/j.pecs.2006.12.001
Wu, Y., Gui, Q., Zhang, H., Li, H., Li, B., Liu, M., Chen, Y., Zhang, S., Yang, H., and Chen, H., J. Anal. Appl. Pyrolysis, 2023, vol. 173, p. 106039. https://doi.org/10.1016/j.jaap.2023.106039
Demirbaş, A., Energy Convers. Manage., 2000, vol. 41, no. 6, p. 633. https://doi.org/10.1016/s0196-8904(99)00130-2
Lam, M.K., Khoo, C.G., and Lee, K.T., Biofuels from Algae, Elsevier, 2019, chap. 19, p. 475. https://doi.org/10.1016/b978-0-444-64192-2.00019-6.
Zhou, H., Long, Y., Meng, A., Li, Q., and Zhang, Y., Thermochim. Acta, 2013, vol. 566, p. 36. https://doi.org/10.1016/j.tca.2013.04.040
Yu, J., Paterson, N., Blamey, J., and Millan, M., Fuel, 2017, vol. 191, p. 140. https://doi.org/10.1016/j.fuel.2016.11.057
Burhenne, L., Messmer, J., Aicher, T., and Laborie, M.-P., J. Anal. Appl. Pyrolysis, 2013, vol. 101, p. 177. https://doi.org/10.1016/j.jaap.2013.01.012
Chua, Y.W., Wu, H., and Yu, Y., Proc. Combust. Inst., 2021, vol. 38, no. 3, p. 3977. https://doi.org/10.1016/j.proci.2020.08.014
Anwar, Z., Gulfraz, M., and Irshad, M., J. Radiat. Res. Appl. Sci., 2014, vol. 7, no. 2, p. 163. https://doi.org/10.1016/j.jrras.2014.02.003
Raveendran, K., Ganesh, A., and Khilar, K.C., Fuel, 1996, vol. 75, p. 987. https://doi.org/10.1016/0016-2361(96)00030-0
Senneca, O., Cerciello, F., Russo, C., Wütscher, A., Muhler, M., and Apicella, B., Fuel, 2020, vol. 271, p. 117656. https://doi.org/10.1016/j.fuel.2020.117656
Yang, H., Yan, R., Chen, H., Lee, D.H., and Zheng, C., Fuel, 2007, vol. 86, nos. 12–13, p. 1781. https://doi.org/10.1016/j.fuel.2006.12.013
Orfão, J.J.M., Antunes, F.J.A., and Figueiredo, J.L., Fuel, 1999, vol. 78, no. 3, p. 349. https://doi.org/10.1016/s0016-2361(98)00156-2
Wu, Y., Zhao, Z., Li, H., and He, F., J. Fuel Chem. Technol., 2009, vol. 37, p. 427. https://doi.org/10.1016/s1872-5813(10)60002-3
Reyes, L., Abdelouahed, L., Mohabeer, C., Buvat, J.C., and Taouk, B., Energy Convers. Manage., 2021, vol. 244, p. 114459. https://doi.org/10.1016/j.enconman.2021.114459
Couhert, C., Commandre, J.-M., and Salvador, S., Fuel, 2009, vol. 88, no. 3, p. 408. https://doi.org/10.1016/j.fuel.2008.09.019
Sun, C., Tan, H., and Zhang, Y., Renewable Energy, 2023, vol. 205, p. 851. https://doi.org/10.1016/j.renene.2023.02.015
Gani, A. and Naruse, I., Renewable Energy, 2007, vol. 32, no. 4, p. 649. https://doi.org/10.1016/j.renene.2006.02.017
Zhu, X., Liu, M., Sun, Q., Ma, J., Xia, A., Huang, Y., Zhu, X., and Liao, Q., Fuel, 2022, vol. 327, p. 125141. https://doi.org/10.1016/j.fuel.2022.125141
Batenin, V.M., Bessmertnykh, A.V., Zaichenko, V.M., Kosov, V.F., and Sinel’shchikov, V.A., Therm. Eng., 2010, vol. 57, no. 11, p. 946. https://doi.org/10.1134/S0040601510110066
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Zaichenko, V.M., Lavrenov, V.A. & Faleeva, Y.M. Study of the Slow Pyrolysis of Lignin, Hemicellulose, and Cellulose and the Effect of Their Interaction in Plant Biomass. Solid Fuel Chem. 57, 428–436 (2023). https://doi.org/10.3103/S0361521923060083
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DOI: https://doi.org/10.3103/S0361521923060083