Skip to main content
Log in

Extraction of Rare Earth Elements from Brown Coals of the Sergeevskoe Deposit (Amur Region) According to Experimental Data

  • Published:
Solid Fuel Chemistry Aims and scope Submit manuscript

Abstract

A series of experiments on the leaching of rare earth elements (REEs) from Miocene brown coals of the Sergeevskoe deposit with water and alkaline and acid solutions was carried out. Using a set of methods (ICP MS, XRD analysis, heavy concentrate analysis, SEM EDS, and IR spectrometry), it was revealed that acid leaching was the most effective: 72–99% of REEs was extracted with a 1 M solution of hydrochloric acid in 24–48 h. This fact indicates that most of the REEs in the brown coals of the Sergeevskoe deposit were associated with the organic matrix in the form of complexes with the carboxyl groups of humic and fulvic acids. The high percentage of REE extraction indicates the possibility of using coals from the Sergeevskoe deposit as an easily enriched source of REEs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Ivanov, V.V., Ekologicheskaya geokhimiya elementov. Spravochnik (Ecological Geochemistry of Elements. Handbook), book 6: Redkie f-elementy (Rare f-Elements), Moscow: Ekologiya, 1997.

  2. Perelomov, L.V., Agrokhimiya, 2007, no. 11, p. 85.

  3. Forster, H.J., Am. Mineral., 1998, vol. 83, p. 1302.

    Article  CAS  Google Scholar 

  4. Buhn, B., Rankin, A.H., Schneider, J., and Dulski, P., Chem. Geol., 2002, vol. 186, p. 75.

    Article  CAS  Google Scholar 

  5. Tyler, G., Plant Soil, 2004, vol. 267, p. 191.

    Article  CAS  Google Scholar 

  6. Brown, T.J., Idoine, N.E., Wrighton, C.E., Raycraft, E.R., Hobbs, S.F., Shaw, R.A., Everett, P., Kresse, C., Deady, E.A., and Bide, T., World Mineral Production 2014–2018, British Geological Survey, 2020.

  7. Sun, G., Li, Z., Liu, T., Chen, J., Wu, T., and Feng, X., Environ. Geochem. Health, 2017, vol. 39, no. 6, p. 1469.

    Article  CAS  PubMed  Google Scholar 

  8. Ketris, M.P. and Yudovich, Ya.E., Int. J. Coal Geol., 2009, vol. 78, p. 135.

    Article  CAS  Google Scholar 

  9. Dai, S., Xie, P., Jia, S., Ward, C.R., Hower, J.C., Yan, X., and French, D., Ore Geol. Rev., 2017, vol. 80, p. 1.

    Article  Google Scholar 

  10. Hower, J.C., Ruppert, L.F., and Eble, C.F., Coal Geol., 1999, vol. 39, p. 141.

    Article  CAS  Google Scholar 

  11. Seredin, V.V., Int. J. Coal Geol., 1996, vol. 30, p. 101.

    Article  CAS  Google Scholar 

  12. Shpirt, M.Ya., Seredin, V.V., and Goryunova, N.P., Khim. Tverd. Topl. (Moscow, Russ. Fed.), 1999, no. 3, p. 91.

  13. Sorokin, A.P. and Konyushok, A.A., Dokl. Earth Sci., 2018, vol. 483, no. 2, p. 1571. https://doi.org/10.1134/S1028334X18120218

    Article  CAS  Google Scholar 

  14. Sorokin, A.P., Konyushok, A.A., Kuz’minykh, V.M., Artemenko, T.V., and Popov, A.A., Geotectonics, 2019, vol. 53, no. 2, p.193. https://doi.org/10.1134/S0016852119020092

    Article  CAS  Google Scholar 

  15. Radomskaya, V.I., Shumilova, L.P., Noskova, L.P., Sorokin, A.P., Pavlova, L.M., Dugin, S.V., Soktoev, B.R., Poselyuzhnaya, A.V., and Ivanov, V.V., Solid Fuel Chem., 2022, vol. 56, no. 1, p. 20. https://doi.org/10.3103/S0361521923010068

    Article  Google Scholar 

  16. Radomskaya, V.I., Shumilova, L.P., Noskova, L.P., Sorokin, A.P., Pavlova, L.M., and Ivanov, V.V., Dokl. Earth Sci., 2022, vol. 507, no. 2, p. 1032. https://doi.org/10.1134/S1028334X22601031

    Article  Google Scholar 

  17. Vasil’ev, I.A., Kapanin, V.P., Kovtonyuk, G.P., Mel’nikov, V.D., Luzhnov, V.L., Danilov, A.P., and Sorokin, A.P., Mineral’no-syr’evaya baza Amurskoi oblasti na rubezhe vekov (Mineral Resource Base of the Amur Region at the Turn of the Century), Blagoveshchensk: Zeya, 2000.

  18. Sorokin, A.P., Konyushok, A.A., Kuz’minykh, V.M., and Dugin, S.V., Minerals, 2021, vol. 11, p. 682.

    Article  CAS  Google Scholar 

  19. Golovin, A.A., Moskalenko, N.N., Achkasov, A.I., Volochkovich, K.L., Gulyaeva, N.G., Gusev, G.S., Kilipko, V.A., Krinochkin, L.V., Morozova, I.A., Trefilova, N.Ya., Ginzburg, L.N., Beder, A.B., Klyuev, O.S., and Kolotov, B.A., Trebovaniya k proizvodstvu I rezul’tatam mnogotselevogo geokhimicheskogo kartirovaniya masshtaba 1:200 000 (Requirements for the Production and Results of Multi-Purpose Geochemical Mapping on a Scale of 1:200 000), Moscow: Institute of Mineralogy, Geochemistry and Crystal Chemistry of Rare Elements, 2002.

  20. Milovskii, A.V., Mineralogiya i petrografiya (Mineralogy and Petrography), Moscow: Nedra, 1985.

  21. Arens, V.Zh., Fiziko-khimicheskaya geotekhnologiya (Physical and Chemical Geotechnology), Moscow: Moscow State Mining Univ., 2001.

  22. Bryers. R.W., Prog. Energy Combust. Sci., 1996, vol. 22, p. 29.

  23. Rudnick, R.L. and Gao, S., Treatise Geochem., 2003, no. 3, p. 1.

  24. Tamarkina, Yu.V., Kucherenko, V.A., and Shendrik, T.G., Solid Fuel Chem., 2014, vol. 48, no. 4, p. 251. https://doi.org/10.3103/S0361521914040119

    Article  CAS  Google Scholar 

  25. Yang, R., Das, S., and Tsai, B., Fuel, 1985, vol. 64, no. 6, p. 735.

    Article  CAS  Google Scholar 

  26. Zhang, W., Noble, A., Yang, X., and Honaker, R.A., Minerals, 2020, no. 10, p. 451.

Download references

Funding

This work was supported by the Russian Science Foundation (project no. 22-27-00116, https://rscf.ru/project/22-27-00116/).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to V. I. Radomskaya, L. P. Shumilova, A. P. Sorokin, B. R. Soktoev, V. V. Ivanov or L. M. Pavlova.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by V. Makhlyarchuk

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Radomskaya, V.I., Shumilova, L.P., Sorokin, A.P. et al. Extraction of Rare Earth Elements from Brown Coals of the Sergeevskoe Deposit (Amur Region) According to Experimental Data. Solid Fuel Chem. 57, 411–422 (2023). https://doi.org/10.3103/S036152192306006X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S036152192306006X

Keywords:

Navigation