Abstract
A systematic study of the compositions of individual microspheres with sizes of <2.5 μm in a fine fraction of fly ash after the pulverized combustion of Ekibastuz coal was carried out using scanning electron microscopy in combination with energy dispersive X-ray spectroscopy (SEM–EDS). It was established that individual ash microspheres with diameters of <1 and 1–2.5 μm from aerosol particle classes PM1 and PM1–2.5, respectively, form several groups depending on SiO2, Al2O3, and FeO contents, and various mineral precursors participated in the formation of these groups. Microspheres of group (1), in the compositions of which SiO2 + Al2O3 > 90 wt % and FeO < 3 wt %, were formed with the participation of NH4-illite and montmorillonite. Isomorphic mixtures of mixed-layer minerals of the illite–montmorillonite series with a low degree of cationic substitution with iron took part in the formation of microspheres of group (2) containing SiO2 + Al2O3 > 90 wt % and FeO = 3–6 wt %. Mineral precursors of microspheres of group (3), SiO2 + Al2O3 < 90 wt % and FeO to 11 wt %, were mixed-layer illite–montmorillonites with a high degree of cationic substitution with iron and Fe3+ included into interlayer sites.
Similar content being viewed by others
REFERENCES
https://energy.skolkovo.ru/downloads/documents/SEneC/Research/SKOLKOVO_EneC_Coal_generation_2019.01.01_Rus.pdf.
Drozhzhin, B.S., Shpirt, M.Ya., Danilin, L.D., Kuvaev, M.D., Pikulin, I.V., Potemkin, G.A., and Redyushev, S.A., Solid Fuel Chem., 2008, vol. 42, no. 2, p. 107. https://doi.org/10.3103/S0361521908020110
Vassilev, S.V. and Vassileva, C.G., Energy Fuels, 2005, vol. 19, no. 3, p. 1084. https://doi.org/10.1021/ef049694d
Blissett, R.S. and Rowson, N.A., Fuel, 2012, vol. 97, p. 1. https://doi.org/10.1016/j.fuel.2012.03.024
Kizil’shtein, L.Ya., Dubov, I.V., Shpitsgluz, A.L., and Parada, S.G., Komponenty zol i shlakov TES (Components of the Ash and Slag of Thermal Power Plants), Moscow: Energoatomizdat, 1995.
Ahmaruzzaman, M., Prog. Energy Combust. Sci., 2010, vol. 36, no. 3, p. 327. https://doi.org/10.1016/j.pecs.2009.11.003
Yao, Z.T., Ji, X.S., Sarker, P.K., Tang, J.H., Ge, L.Q., Xia, M.S., and Xi, Y.Q., Earth-Sci. Rev., 2015, vol. 141, p. 105. https://doi.org/10.1016/j.earscirev.2014.11.016
Sarkar, A., Rano, Ruma., Mishra, K.K., and Sinha, I.N., Fuel Process. Technol., 2005, vol. 86, no. 11, p. 1221. https://doi.org/10.1016/j.fuproc.2004.12.002
Moreno, N., Querol, X., Andres, J.M., Stanton, K., Towler, M., Nugteren, H., Janssen-Jurkovicova, M., and Jones, R., Fuel, 2005, vol. 84, no. 11, p. 1351. https://doi.org/10.1016/j.fuel.2004.06.038
Bhanarkar, A.D., Gavane, A.G., Tajne, D.S., Tamhane, S.M., and Nema, P., Fuel, 2008, vol. 87, nos. 10–11, p. 2095. https://doi.org/10.1016/j.fuel.2007.11.001
Ghosal, S., Ebert, J.L., and Self, S.A., Fuel Process. Technol., 1995, vol. 44, nos. 1–3, p. 81. https://doi.org/10.1016/0378-3820(94)00115-A
Martinez-Tarazona, M.R. and Spears, D.A., Fuel Process. Technol., 1996, vol. 47, no. 1, p. 79. https://doi.org/10.1016/0378-3820(96)01001-6
Akimochkina, G.V., Kushnerova, O.A., Rogovenko, E.S., and Fomenko, E.V., J. Sib. Fed. Univ., Chem., 2018, vol. 11, no. 2, p. 197. https://doi.org/10.17516/1998-2836-0068
Kushnerova, O.A., Akimochkina, G.V., Fomenko, E.V., Rabchevskii, E.V., and Anshits, A.G., Solid Fuel Chem., 2018, vol. 52, no. 3, p. 188. https://doi.org/10.3103/S0361521918030059
Fomenko, E.V., Akimochkina, G.V., and Anshits, A.G., Therm. Eng., 2019, vol. 66, no. 8, p. 560. https://doi.org/10.1134/S0040601519080020
Fomenko, E.V., Anshits, N.N., Kushnerova, O.A., Akimochkina, G.V., Kukhtetskiy, S.V., and Anshits, A.G., Energy Fuels, 2019, vol. 33, no. 4, p. 3584. https://doi.org/10.1021/acs.energyfuels.9b00097
Lighty, J.S., Veranth, J.M., and Sarofim, A.F., J. Air Waste Manage. Assoc., 2000, vol. 50, p. 1565. https://doi.org/10.1080/10473289.2000.10464197
Riffault, V., Arndt, J., Marris, H., Mbengue, S., Setyan, A., Alleman, L.Y., Deboudt, K., Flament, P., Augustin, Delbarre, P., and Wenger, J., Crit. Rev. Env. Sci. Tech., 2015, vol. 45, no. 21, p. 2305. https://doi.org/10.1080/10643389.2015.1025636
Shpirt, M.Ya., Kler, V.R., and Pertsikov, I.Z., Neorganicheskie komponenty tverdykh topliv (Inorganic Components of Solid Fuels), Moscow: Khimiya, 1990.
Geologiya mestorozhdenii uglya i goryuchikh slantsev SSSR: Ugol’nye basseiny i mestorozhdeniya Kazakhstana (Geology of Coal and Oil Shale Deposits of the USSR: Coal Basins and Deposits of Kazakhstan), Moscow: Nedra, 1973, vol. 5.
Korobetskii, I.A. and Shpirt, M.Ya., Genezis i svoistva mineral’nykh komponentov uglei (Genesis and Properties of Mineral Coal Components), Novosibirsk: Nauka, 1988.
Vdovenko, M.I., Mineral’naya chast' energeticheskikh uglei (Mineral Matter of Power Generating Coals), Alma-Ata: Nauka, 1973.
Mineraly. Sloistye silikaty: Spravochnik (Minerals. Layered Silicates: A Handbook), Chukhrov, F.V., Ed., Moscow: Nauka, 1992, vol. 4.
Fomenko, E.V., Anshits, N.N., Solovyov, L.A., Mikhailova, O.A., and Anshits, A.G., Energy Fuels, 2013, vol. 27, no. 9, p. 5440. https://doi.org/10.1021/ef400754c
Anshits, N.N., Fedorchak, M.A., Zhizhaev, A.M., Sharonova, O.M., and Anshits, A.G., Inorg. Mater., 2018, vol. 54, no. 2, p. 187. https://doi.org/10.1134/S0020168518020012
Anshits, N.N., Fedorchak, M.A., Zhizhaev, A.M., and Anshits, A.G., Inorg. Mater., 2018, vol. 54, no. 3, p. 253. https://doi.org/10.1134/S0020168518030032
Anshits, N.N., Fedorchak, M.A., Sharonova, O.M., Kirik, N.P., Shishkina, N.N., Zhizhaev, A.M., and Anshits, A.G., Inorg. Mater., 2018, vol. 54, no. 5, p. 466. https://doi.org/10.1134/S0020168518050011
Anshits, N.N., Fedorchak, M.A., Zhizhaev, A.M., and Anshits, A.G., Energy Fuels, 2019, vol. 33, no. 7, p. 6788. https://doi.org/10.1021/acs.energyfuels.9b01077
Zheng, Q., Liu, Q., and Shi, S., Int. J. Coal Geol., 2016, vol. 153, p. 1.https://doi.org/10.1016/j.coal.2015.11.008
Zhao, Y., Zhang, J., and Zheng, C., Int. J. Coal Geol., 2012, vol. 94, p. 82. https://doi.org/10.1016/j.coal.2011.04.007
Petrova, V.V., Nizkotemperaturnye vtorichnye mineraly i ikh rol’ v litogenezise (silikaty, alyumosilikaty, gidroksidy) (Low-Temperature Secondary Minerals and Their Role in Lithogenesis (Silicates, Aluminosilicates, and Hydroxides)), Moscow: GEOS, 2005.
Funding
This study was supported by the Russian Foundation for Basic Research, the Government of Krasnoyarsk krai, and the Krasnoyarsk Science Foundation (project no. 18-43-240002) and performed at the Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences within the framework of a state contract (AAAA-A17-117021310222-4).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by V. Makhlyarchuk
About this article
Cite this article
Fomenko, E.V., Akimochkina, G.V., Kushnerova, O.A. et al. Composition of Individual Microspheres in a Finely Dispersed Fraction from Fly Ash after the Pulverized Combustion of Ekibastuz Coal. Solid Fuel Chem. 54, 91–98 (2020). https://doi.org/10.3103/S0361521920020032
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S0361521920020032