Abstract
The thermodynamic analysis of the composition of the combustion products of 15 types of coals was carried out with consideration for the formation of potassium and sodium aluminosilicates and solid and liquid slag removal. Based on the results of the analysis, the approximating temperature dependences of the concentrations of condensed components (potassium and sodium sulfates) were obtained for the cases of two-phase and single-phase equilibriums; conclusions on the comparative influence of solid and liquid slag removal on the probability of the formation of submicron particles on the combustion of coals were made. The found dependences will make it possible to perform a numerical simulation of the bulk condensation of potassium and sodium sulfate vapors upon the cooling of coal combustion products in a process flow.
Similar content being viewed by others
References
Dockery, D.W., Pope, C.A., Xu, X.P., Spengler, J.D., Ware, J.H., Fay, M.E., Ferris, B.G., and Speizer, F.E., New England J. Med., 1993, vol. 329, p. 1753.
Vejahati, F., Xu, Z., and Gupta, R., Fuel, 2010, vol. 89, no. 4, p. 904.
Soco, E. and Kalembkiewicz, J., Fuel, 2009, vol. 88, no. 8, p. 1513.
Li, J., Zhuang, X., and Querol, X., Fuel, 2011, vol. 90, no. 1, p. 240.
Zhang, L. and Ninomiya, Y., 21nd Pittsburg Coal Conf., 2004.
Zhang, L. and Ninomiya, Y., Fuel, 2006, vol. 85, no. 2, p. 194.
Lockwood, F.C. and Yousif, S., Fuel Proc. Technol., 2000, vols. 65–66, p. 439.
Tomeczek, J. and Palugniok, H., Fuel, 2002, vol. 81, p. 1251.
Kortsenshtein, N.M. and Samuilov, E.V., Izv. Ross. Akad. Nauk, Energ., 2005, no. 3, p. 169.
Kortsenshteyn, N.M., Lebedeva, L.N., Petrov, L.V., and Samuilov, E.V., Kolloidn. Zh., 2015, no. 2, p. 174.
Lebedeva, L.N., Kortsenshtein, N.M., and Samuilov, E.V., Teploenergetika, 2014, no. 12, p. 70.
Vdovchenko, V.S., Martynova, M.I., Novitskii, M.V., and Yushina, G.D., Energeticheskoe toplivo SSSR: Spravochnik (USSR Energy Fuel: A Handbook), Moscow: Energoizdat, 1991.
Gerasimov, G.Ya., Zhegul’skaya, N.A., Rozhdestvenskii, I.B., Samuilov, E.V., and Sheveleva, N.A., Mat. Model., 1998, vol. 10, no. 8, p. 3.
Glushko, V.P., Gurvich, L.V., Bergman, G.A., et al., Termodinamicheskie svoistva individual’nykh veshchestv (Thermodynamic Properties of Individual Substances), Moscow: Nauka, 1978–1982, vols. 1–4.
JANAF Thermochemical Tables, Washington: NSRDS, 1971, nos. 135–137.
JANAF Thermochemical Tables. Supplement, J. Phys. Chem. Ref. Data, 1974, vol. 3, no. 2, p. 311; 1975, vol. 4, no. 1, p. 1; 1978, vol. 7, no. 3, p. 793; 1982, vol. 11, no. 3, p. 695.
Shpirt, M.Ya., Kler, V.R., and Pertsikov, I.Z., Neorganicheskie komponenty tverdykh topliv (Inorganic Components of Solid Fuels), Moscow: Khimiya, 1990.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.M. Kortsenshteyn, L.V. Petrov, 2017, published in Khimiya Tverdogo Topliva, 2017, No. 3, pp. 43–50.
About this article
Cite this article
Kortsenshteyn, N.M., Petrov, L.V. Thermodynamic analysis of the formation of submicron particles on the combustion of coals. Solid Fuel Chem. 51, 170–176 (2017). https://doi.org/10.3103/S0361521917030053
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S0361521917030053