Abstract
The hydrogenation of anthracene in the presence of the nanosized catalysts based on iron β-FeOOH and Fe(OA)3 (OA refers to oleic acid) and the spherical catalysts NiO/SiO2 and Fe2O3/SiO2 obtained from ash and slag from thermal power plants was studied. It was found that the above catalytic systems can arranged in the following order according to the yields of hydrogenation and destruction products upon the hydrogenation of polycyclic hydrocarbons: β-FeOOH, Fe(OA)3, and Fe3O4 nanoparticles > NiO/SiO2 and Fe2O3/SiO2 spherical catalysts > commercial cobalt-molybdenum catalyst. It was established that the test catalysts are promising for the hydrogenation of polycyclic hydrocarbons, and they can be used for the direct liquefaction of coal.
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Ma Feng Yun, Baikenov, M.I., Gudun, K.A., et al., Vestn. Karagandinsk. Univ., 2012, no. 2, p. 50.
Vol’fkovich, S.I., Obshchaya khimicheskaya tekhnologiya (General Chemical Technology), Moscow: GNTIKhL, 1953, vol. 1.
Hintai, S., Fengfi, S., and Tateeva, A.B., Vestn. Kar. Gos Univ., 2011, no. 4 (64), p. 60.
Gudun, K.A., Baikenov, M.I., Tusipkhan, A., et al., Materialy VIII miedzynarodowej naukowi-praktycznej konferencji: Fizyka, chemia a chemiczne technologie (Proc. VIII Int. Sci.-Pract. Conf.: Physics, Chemistry, and Chemical Engineering), Przemysl: Nauka i Studia, 2012, vol. 44, p. 87.
Karnaukhov, A.P., Adsorbtsiya. Tekstura dispersnykh i poristykh materialov (Adsorption: Texture of Dispersed and Porous Materials), Moscow: Nauka, 1990.
Krichko, A.A., Ozerenko, A.A., Frosin, S.B., et al., Katal. Prom-st., 2007, no. 2, p. 30.
Krichko, A.A., Ozerenko, A.A., Maloletnev, A.S., et al., Katal. Prom-st., 2007, no. 3, p. 23.
Zekel’, L.A., Khim. Tverd. Topl. (Moscow), 2001, no. 5, p. 49.
Maloletnev, A.S., Ozerenko, A.A., and Shpirt, M.Ya., Khim. Tverd. Topl. (Moscow), 2007, no. 1, p. 35.
Karnaukhov, A.P., Adsorbtsiya. Tekstura dispersnykh i poristykh materialov (Adsorption: Texture of Dispersed and Porous Materials), Moscow: Nauka, 1999.
Sharypov, V.I., Kuznetsov, P.N., and Korniets, E.D., Khim. Tverd. Topl. (Moscow), 1990, no. 3, p. 48.
Imanbaev, S.Sh., Baikenova, G.G., Meiramov, M.G., et al., Mater. konf. RKhO im. D. I. Mendeleeva: “Innovatsionnye khimicheskie tekhnologii i biotekhnologii novykh materialov i produktov” (Proc. Conf. Mendeleev Russ. Chem. Soc. “Innovative Chemical Technologies and Biotechnologies for New Materials and Products), Moscow: RKhTU im. D.I. Mendeleeva, 2010, p. 259.
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Original Russian Text © M.I. Baikenov, G.G. Baikenova, A.S. Isabaev, A.B. Tateeva, Zh.S. Akhmetkarimova, A. Tusipkhan, A.Zh. Mataeva, K.K. Esenbaeva, 2015, published in Khimiya Tverdogo Topliva, 2015, No. 3, pp. 22–27.
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Baikenov, M.I., Baikenova, G.G., Isabaev, A.S. et al. Effect of new catalytic systems on the process of anthracene hydrogenation. Solid Fuel Chem. 49, 150–155 (2015). https://doi.org/10.3103/S0361521915030039
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DOI: https://doi.org/10.3103/S0361521915030039