Abstract
The main methods for the production of potentially valuable elements from fossil fuels (petroleum and coal) are considered. A large body of factual data on this problem is analyzed based on the experimental and theoretical studies and the works of foreign and Russian scientists. The methods of the extraction of potentially valuable elements, in particular, Ge from coals and V from oils and petroleum products, are described. It is shown that, in addition to fossil fuels with the technological concentrations of potentially valuable elements, some by-products of the processing of caustobioliths are of interest for the recovery of these elements. These are mainly fly ashes, slags, and their mixtures trapped after the combustion or gasification of coals and oil conversion products and also after the utilization of overburden rocks and high-ash cleaning rejects by thermal methods. The minimum concentrations of a number of potentially valuable elements in fossil fuels are roughly estimated, at which oils and coals should be considered as complex raw materials for the use of their organic matter and the manufacture of the commercial compounds of valuable trace elements.
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References
Gribkov, V.V., Extended Abstract of Doctoral (Geol. Mineral.) Dissertation, VNIGRI, Leningrad, 1989.
Shpirt, M.Ya. and Rashevskii, V.V., Formy soedinenii i povedenie mikroelementov v protsessakh pererabotki goryuchikh iskopaemykh (Chemical Speciation and Behavior of Trace Elements in the Processing of Fossil Fuels), Moscow: Kuchkovo Pole, 2010.
Shpirt, M.Ya. and Punanova, S.A., Mikroelementy kaustobiolitov. Problemy genezisa i promyshlennogo ispol’zovaniya (Trace Elements of Caustobioliths: Genesis and Industrial Application Problems), Saarbrucken: Lambert Academic Publishing, 2012.
Gribkov, V.V. and Ryumin, A.A., Metody tekhnologicheskoi otsenki i osvoeniya resursov vanadiya v neftyakh i bitumakh (Methods for the Technological Assessment and Development of Vanadium Resources in Oils and Bitumens), Moscow: AO Geoinformmark, 1994, no. 2.
Seredin, V.V., Ugol’naya baza Rossii (Coal Basis of Russia), Moscow: OOO Geoinformmark, 2004, vol. 6.
Shpirt, M.Ya., Fiziko-khimicheskie i tekhnologicheskie printsipy proizvodstva soedinenii germaniya (Physicochemical and Technological Principles of the Production of Germanium Compounds), Apatity: Izd. Kol’sk. Nauchn. Tsentra Ross. Akad. Nauk, 2009.
Shpirt, M.Ya., Kler, V.R., and Pertsikov, I.Z., Neorganicheskie komponenty tverdykh topliv (Inorganic Components of Solid Fuels), Moscow: Khimiya, 1990.
Shpirt, M.Ya., Fiziko-khimicheskie osnovy pererabotki germanievogo syr’ya (Physicochemical Fundamentals of the Processing of Germanium Raw Materials), Moscow: Metallurgiya, 1977.
Tanutrov, I.N., Sviridova, M.N., and Podkopaev, O.I., RF Patent 2090809, 1997.
Dedov, A.G., Mel’nikov, V.B., Nekrasova, V.V., et al., Neftekhimiya, 1995, vol. 35, no. 5, p. 387.
Magariya, R.Z., Teoreticheskie osnovy khimicheskikh protsessov pererabotki nefti (Theoretical Fundamentals of the Chemical Processes of Oil Conversion), Leningrad: Khimiya, 1985.
Nurzhanova, S.B., Kozlov, V.A., Batrakova, L.Kh., et al., Neft’ Gaz Almaty, 2000, no. 3, p. 84.
Sitnikova, G.Yu., Rastova, N.V., Davydova, S.L., et al., Neftekhimiya, 1990, vol. 30, no. 4, p. 49.
Ryumin, A.A., Beloglazov, K.K., and Gribkov, V.V., Problemy podgotovki i osvoeniya resursov vanadiya v neftyakh i bitumakh (Problems of the Preparation and Development of Vanadium Resources in Oils and Bitumens), Leningrad: Tr. VNIGRI, 1991, p. 148.
Rakutin, Yu.V., Mingazetdinov, F.A., and Galimov, R.A., Ross. Khim. Zh., 1995, vol. 39, no. 5, p. 103.
Penning, R.T., US Patent 4752376, 1988.
Bakirova, S.F., Kuandykov, B.M., Turkov, O.S., et al., Geteroorganicheskie soedineniya v neftyakh Zapadnogo Kazakhstana (Heteroorganic Compounds in the Petroleum of Western Kazakhstan), Almaty: Gylym, 1993.
Nadirov, N.K., Kotova, A.V., Kam’yanov, V.F., et al., Metally v neftyakh (Metals in Petroleum), Alma-Ata: Nauka, 1984.
Radchenko, B.D., Zh. Vses. Khim. O-va im D. I. Mendeleeva, 1984, vol. 29, no. 4, p. 392.
Nadirov, N.K., Kozlov, V.S., Batrakova, L.Kh., et al., Kompleksnaya pererabotka prirodnykh bitumov i bitumsoderzhashchikh porod. Sb. nauchnykh trudov (Complex Processing of Natural Bitumen and Bitumen-Containing Rocks: Collected Articles), Moscow: VNIINeft’, 1989, p. 127.
Nadirov, N.K., Vysokovyazkie nefti i neftebituminoznye porody Kazakhstana kak kompleksnoe syr’e dlya razlichnykh otraslei narodnogo khozyaistva (High-Viscosity Oils and Oil-Bitumen Rocks of Kazakhstan as Complex Raw Materials for Various Branches of Industry: Collected Articles), Moscow: VNIIneft’, 1991, vol. 109, p. 43.
Nukenov, D.N., Punanova, S.A., and Agafonova, Z.G., Metally v neftyakh, ikh kontsentratsiya i metody izvlecheniya (Metals in Petroleum; Their Concentration and Extraction Methods), Moscow: GEOS, 2001.
Nukenov, D.N., Punanova, S.A., and Vasilenko, P.A., Mater. konf. “Problemy i perspektivy razvitiya neftegazovoi otrasli Kazakhstana v XXI veke” (Proc. Conf. “Problems and Prospects of the Development of the Oil and Gas Industry of Kazakhstan in the 21st Century”), Aktau, 2001, p. 35.
Nukenov, D., Bisembaev, A., and Rakhmetullaev, A., Kazakhstan Patent 20876, 1998.
Nusupbekova, D.A., Nurmambetov, K.E., Nurmambetova, D.E., and Nukenov, D., Kazakhstan Patent 23169, 2010.
Huh, B.K. and Yan, T., US Patent 4980049, 1991.
Dmitrievskii, A.N., Skibitskaya, N.A., Zekel’, L.A., et al., Khim. Tverd. Topl. (Moscow), 2006, no. 2, p. 47.
Abyzgil’din, Yu.M., Mikhailyuk, Yu.L., and Yarullin, K.S., Ratovskaya. A.A. Porfiriny i metalloporfirinovye kompleksy neftei (Porphyrins and Metal Porphyrin Complexes of Petroleum), Moscow: Nauka, 1977.
Nasirov, R.N. and Vel’k, O.D., Ekspress-informatsiya VNIIOENG (Rapid Information of VNIIOENG), Moscow, 1992, no 3, p. 12.
Galimov, R.A., Krivonozhkina, L.B., Abushaeva, V.V., et al., Neftekhimiya, 1993, vol. 33, no. 6, p. 552.
Syunyaev, Z.I., Syunyaev, R.Z., and Safieva, R.Z., Neftyanye dispersnye sistemy (Petroleum Disperse Systems), Moscow: Khimiya, 1990.
Soskind, D.M. and Gribkov, V.V., Khim. Tekhnol. Topl. Masel, 1988, no. 4, p. 7.
Kadieva, M.Kh., Khadzhiev, S.N., Kadiev, Kh.M., and Yakovenko, T.V., Neftekhimiya, 2011, vol. 51, no. 6, p. 435.
Visaliev, M.Ya., Shpirt, M.Ya., Kadiev, Kh.M., Dvorkin, V.I., Magomadov, E.E., and Khadzhiev, S.N., Khim. Tverd. Topl. (Moscow), 2012, no. 2, p. 32.
Soskind, D.M., Radchenko, E.D., Spektor, G.S., and Zenchenkova, M.G., Khim. Tekhnol. Topl. Masel, 1984, no. 2, p. 4.
Abyzgil’din, Yu.M., Syunyaev, Z.I., Masagutov, R.M., et al., Vliyanie mineral’nykh primesei neftei na tekhnologicheskie protsessy i ekspluatatsionnye svoistva nefteproduktov (Effect of the Mineral Impurities of Oils on Processes and the Performance Characteristics of Oil Products), Moscow: TsNIITEneftekhim, 1974.
Guzei, L.S., Zhmurko, G.P., and Soboleva, N.Yu., Ross. Khim. Zh., 1995, vol. 39, no. 5, p. 64.
Avdonin, V.V., Boitsov, V.E., Grigor’ev, V.M., et al., Mestorozhdeniya metallicheskikh poleznykh iskopaemykh (Metal Ore Deposits), Moscow: ZAO Geoinformmark, 1998.
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Original Russian Text © M.Ya. Shpirt, D.N. Nukenov, S.A. Punanova, M.Ya. Visaliev, 2013, published in Khimiya Tverdogo Topliva, 2013, No. 2, pp. 3–14.
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Shpirt, M.Y., Nukenov, D.N., Punanova, S.A. et al. Principles of the production of valuable metal compounds from fossil fuels. Solid Fuel Chem. 47, 71–82 (2013). https://doi.org/10.3103/S0361521913020110
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DOI: https://doi.org/10.3103/S0361521913020110