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The Ti-Fe-P system: phase equilibria and crystal structure of phases

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Central European Journal of Chemistry

Abstract

Phase equilibria was investigated in the Ti-Fe-P system at T = 1070 K in the region 0–67 at.% of P, employing X-ray powder diffraction. The two ternary compounds, namely Ti0.5–0.8Fe1.5−1.2P (Co2Si-type; space group Pnma; a = 0.5964(2)–0.6011(3), b = 0.3575(3)–0.3600(1), c = 0.6828(2)–0.6882(2) nm) and Ti0.85−1.25Fe1.15−0.75P (ZrNiAl-type; space group P-62m; a = 0.6071(4)–0.6117(1), c = 0.3510(9)–0.3506(1) nm) exist in the Ti-Fe-P system at this temperature. The crystal structure of the Ti0.85–1.25Fe1.15−0.75P compound was additionally determined by X-ray single crystal diffraction on the phase with stoichiometric composition. The substitutions of Ti by Fe were observed for Ti5P3.16, Ti3P and TiP phases, and Fe for Ti in the case of Fe3P, Fe2P binary compounds.

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References

  1. A.O. Oliynyk, Y.F. Lomnytska, M.V. Dzevenko, S.S. Stoyko, A. Mar, Inorg. Chem. 52, 983 (2013)

    Article  CAS  Google Scholar 

  2. H. Kaneko, T. Nishizawa, K. Tamaki, J. Jpn. Inst. Met. 29, 159 (1965)

    CAS  Google Scholar 

  3. S. Rundqvist, P.C. Nawapong, Acta Chem. Scand. 20(8), 2250 (1966)

    Article  CAS  Google Scholar 

  4. H. Ohtani, N. Hanaya, M. Hasebe, S.-i. Teraoka, M. Abe, Calphad. 30, 147 (2006)

    Article  CAS  Google Scholar 

  5. L.G. Akselrud, P.Yu. Zavalii, Yu.N. Grin, V.K. Pecharski, B. Baumgartner, E. Wölfel, Mat. Sci. Forum 133–136, 335 (1993)

    Article  Google Scholar 

  6. N. Masciocchi, The Rigaku Journal 14(2), 9 (1997)

    CAS  Google Scholar 

  7. J. Rodriguez-Carvajal, Commission on powder diffraction (IUCr). Newsl. 26, 12 (2001)

    Google Scholar 

  8. G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement (University of Göttingen, Germany, 1997) 12–19

    Google Scholar 

  9. T.B. Massalski (Ed.), Binary Alloy Phase Diagrams, 2nd edition (ASM International, Materials Park, OH, 1990) 827

    Google Scholar 

  10. P. Villars (Ed.), Pearson’s Handbook Desk Edition. Crystallographic Data for Intermetallic Phases (Metals Park, OH 44070, 1997) 2888

    Google Scholar 

  11. P.J. Brown, J. Deportes, B. Ouladdiaf, J. Phys.: Condens. Matter. 4(49), 10015 (1992)

    Article  CAS  Google Scholar 

  12. M. Gemmi, X.-D. Zou, S. Hovmoeller, A. Migliori, M. Vennstrom, Y. Andersson, Acta Cryst. A. 59, 117 (2003)

    Article  Google Scholar 

  13. T. Lundstroem, P.O. Snell, Acta Chem. Scand. 21, 1343 (1967)

    Article  Google Scholar 

  14. J. Emsley, The Elements, 3th edition (Oxford University Press, Oxford, 1998) 300

    Google Scholar 

  15. V.S. Babizhetskyy, Ya.F. Lomnytska, Inorg. Mater. 38(9), 905 (2002)

    Article  Google Scholar 

  16. Ya.F. Lomnytska, Inorg. Mater. 37(1), 9 (2001)

    Article  Google Scholar 

  17. Ya.F. Lomnytska, L.P. Agatiska, Yu.B. Kuzma, Ukr. Chim. Journal. 47(2), 142 (1981) (in Russian)

    Google Scholar 

  18. S.V. Muchnik, Ya.F. Lomnytska, V.B. Chernogorenko, K.A. Lynchak, Poroshkovaya Metallurgia 2, 71 (1989) (in Russian)

    Google Scholar 

  19. Yu.B. Kuzma, Ya.F. Lomnytska, V.V. Sapovskiy, Neorg. Mater. 17(4), 647 (1981) (in Russian)

    CAS  Google Scholar 

  20. M. Klimczak, E. Talik, J. Jarosz, T. Mydlarz, Mater. Sci. Poland. 26(4), 35 (2008)

    Google Scholar 

  21. J. F. Riecken, G. Heymann, H. Huppertz, R. Pöttgen, Z. Anorg. Allg. Chem. 633(5–6), 869 (2007)

    Article  CAS  Google Scholar 

  22. A. Nylund, A. Roger, J.P. Senateur, R. Fruchart, Monatsh. Chem. 102(5), 1631 (1971)

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Laboratory MOLTECH — Anjou, UMR-CNRS 6200, University of Angers, 49045, Angers, France

    Oksana Toma

  2. Department of Analytical Chemistry, Ivan Franko National University of Lviv, UA-79005, Lviv, Ukraine

    Mariya Dzevenko & Yaroslava F. Lomnytska

  3. Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada

    Anton Oliynyk

Authors
  1. Oksana Toma
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  2. Mariya Dzevenko
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  3. Anton Oliynyk
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  4. Yaroslava F. Lomnytska
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Correspondence to Mariya Dzevenko.

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Toma, O., Dzevenko, M., Oliynyk, A. et al. The Ti-Fe-P system: phase equilibria and crystal structure of phases. cent.eur.j.chem. 11, 1518–1526 (2013). https://doi.org/10.2478/s11532-013-0282-8

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  • DOI: https://doi.org/10.2478/s11532-013-0282-8

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