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Physicochemical characteristics of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III)

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Central European Journal of Chemistry

Abstract

The crystal structure of 2-methylpyridinium tetrachloroferrate(III) was determined. The iron cation is tetracoordinated by chloride anions, and it adopts a slightly distorted tetrahedral coordination with three angles smaller, two almost equal and one larger than the tetrahedral. The compound is isostructural with its 3-, and 4-methylpyridinium analogues. The thermal properties of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III) have been studied using TG and DSC techniques. The compounds exhibit a high stability in the melt.

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Authors and Affiliations

  1. Department of General and Inorganic Chemistry, Faculty of Chemistry, University of Gdańsk, 80 952, Gdańsk, Poland

    Dariusz Wyrzykowski, Dagmara Jacewicz & Lech Chmurzyński

  2. Department of Physical Chemistry, Faculty of Chemistry, University of Gdańsk, 80 952, Gdańsk, Poland

    Michał Wera & Artur Sikorski

Authors
  1. Dariusz Wyrzykowski
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  2. Michał Wera
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  3. Artur Sikorski
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  4. Dagmara Jacewicz
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  5. Lech Chmurzyński
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Correspondence to Dariusz Wyrzykowski.

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Wyrzykowski, D., Wera, M., Sikorski, A. et al. Physicochemical characteristics of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III). cent.eur.j.chem. 9, 1096–1101 (2011). https://doi.org/10.2478/s11532-011-0106-7

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  • DOI: https://doi.org/10.2478/s11532-011-0106-7

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