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High Stokes shift long-wavelength energy gap regulated fluorescence in the series of nitro/dimethylamino-substituted ortho-analogs of POPOP

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Central European Journal of Chemistry

An Erratum to this article was published on 07 October 2011

An Erratum to this article was published on 07 October 2011

An Erratum to this article was published on 07 October 2011

Abstract

A series of novel nitro-substituted ortho-analogs of POPOP was synthesized. Like the most of the other known compounds of this class, the synthesized molecules demonstrate high Stokes shift fluorescence emission owing to the planarization of their molecules at electronic excitation. Significant fluorescence quenching in polar solvents was described as the “energy gap law” action rather than the specific effect of the dialkylamino group excited state twisting.

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Authors and Affiliations

  1. Kharkov V.N. Karazin National University, Kharkov, 61077, Ukraine

    Rodion Yu. Iliashenko, Olexiy S. Zozulia & Andrey O. Doroshenko

  2. Ukrainian-American Laboratory of Computational Chemistry, Kharkiv, 61001, Ukraine

    Andrey O. Doroshenko

  3. Jackson, Mississippi, 38217-0510, USA

    Andrey O. Doroshenko

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  1. Rodion Yu. Iliashenko
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  2. Olexiy S. Zozulia
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  3. Andrey O. Doroshenko
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Correspondence to Andrey O. Doroshenko.

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An erratum to this article can be found at http://dx.doi.org/10.2478/s11532-011-0111-x

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Iliashenko, R.Y., Zozulia, O.S. & Doroshenko, A.O. High Stokes shift long-wavelength energy gap regulated fluorescence in the series of nitro/dimethylamino-substituted ortho-analogs of POPOP. cent.eur.j.chem. 9, 962–971 (2011). https://doi.org/10.2478/s11532-011-0092-9

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