Abstract
Experimental data of bismuth activity coefficients at 1773 K were obtained by isopiestic method and compared to calculated values. Thermodynamic properties of the Sn-Ni-Bi liquid phase were estimated by means of the general solution model and by the methods of Kohler. Description of the ternary liquid phase (Gibbs excess energy dependence on the temperature and the composition) was achieved by using available thermodynamic data of the constitutive binary systems (Ni-Bi, Sn-Bi, Sn-Ni). A comparison between calculated quantities and experimental data wasconducted. The present assessment with thermodynamically optimized values of the system Sn-Ni-Bi (obtained by the CALPHAD approach) was in good agreement. The suggested appearance of a liquid phase miscibility gap at high temperatures is in agreement with the experimental bismuth activity data and with the assessed thermochemical functions.
Similar content being viewed by others
References
S.K. Kang, A.K. Sarkhel, J. Electron. Mater. 23, 701 (1994)
W.J. Plumbridge, Materials at High Temp. 17, 381 (2000)
K. Suganuma, Current Opinion in Solid State and Mat. Sci. 5, 55 (2001)
H. Huang, L. Zhou, M. Zhang, X. Liu, Mater. Letters, 61, 655 (2007)
N.M. Sharif, C.K. Yew, T. Ariga, A.B. Ismail, Z. Hussain, JALCOM 507, 290 (2010)
C. Chen, C. Ho, A. Lin, G. Luo, C. Kao, J. Electron. Mater. 29, 1200 (2000)
W.H. Tao, C. Chen, C.E. Ho, W.T. Chen, C.R. Kao, Chem. Mater. 13, 1051 (2001)
J. Lee, S. Chen, H. Chang, C. Chen, J. Electron. Mater. 32, 117 (2003)
G.P. Vassilev, K.I. Lilova, J.C. Gachon, Therm. Acta 447(1) 106 (2006)
G.P. Vassilev, K.I. Lilova, J.C. Gachon, In Proceedings of VIIIth Int. Workshop of Assoc. Phase Diagram and Thermod. Committee, Košice, Slovakia, 19 Nov. 2005, (Ins. Met. and Mat. Sc., Polish Academy of Sciences, Krakow, Poland 2005), 27 ISBN 83-921845-5-6
S.-K. Seo, M.G. Cho, H.M. Lee, J. El. Mat. 36, 1536 (2007)
G.P. Vassilev, K.I. Lilova, J.-C. Gachon, J. Mining and Metallurgy 43B(2), 141 (2007)
G.P. Vassilev, K.I. Lilova, J.-C. Gachon, Cryst. Res. Technol. 43(9), 980 (2008)
G.P. Vassilev, K.I. Lilova, J.-C. Gachon, JALCOM 469, 264 (2009)
A. Dinsdale, A. Watson, A. Kroupa, J. Vrestal, A. Zemanova, J. Vizdal, Atlas of Phase Diagrams for the Lead-Free Soldering, COST 531 (Lead-free Soders), (COST office, Czech Republic, 2008) Vol. 1, ISBN 978-80-86292-28-1
G. Vassilev, V. Gandova, P. Docheva, Cryst. Res. Technol. 44(1), 25 (2008)
M. Hilert, CALPHAD 4, 1 (1980)
P. Chartrand, A.D. Pelton, J. Phase Equilib. 21(2), 141 (2000)
A.D. Pelton, CALPHAD Journal, 25(2), 319 (2001)
F. Kohler, Monatsh. Chem. 91, 738 (1960)
G.W. Toop, Trans. ALME 233, 850 (1965)
K.C. Chou, CALPHAD 19, 315 (1995)
K.C. Chou, W.C. Li, F. Li, M. He, CALPHAD 20, 395 (1996)
S.K. Lee, S.J. Kim, Calphad 25, 97 (2001)
D. Živković, I. Katayama, H. Yamashita, D. Manasijević, Ž. Živković, RMZ — Materials and Geoenvironment 53, 155 (2006)
S. Marjanović, D. Manasijević, D. Živković, D. Gusković, D. Minić, RMZ — Materials and Geoenvironment 56, 30 (2009)
D. Živković, D. Manasijević, I. Mihajlović, Ž. Živković, J. Serb. Chem. Soc. 71, 203 (2006)
C. Schmetterer, H. Flandorfer and H. Ipser, J. Non-Cryst. Solids 354, 2953 (2008)
A. Zemanova, A. Kroupa, Thermodynamic database of the action COST MP 0602, In proceeding of: COST Action MP 0602, Annual COST MP 0602 Meeting, April 7–9, 2010 Bratislava, Slovakia
O. Redlich, A. Kister, Indust. Eng. Chem. 40, 345 (1948)
H. Ipser, Ber. der Bunsen-Gesellchaft-Physical chemistry Chemical Physics 102, 1217 (1998)
G. Vassilev, J. Alloys Comp. 186, 99 (1992)
J. Romanowska, T. Pomianek, G. Wnuk, Arch. of Metallurgy 46, 255 (2001)
G. Wnuk, J. Romanowska, T. Pomianek, J. Chem. Therm. 35, 711 (2003)
G. Wnuk, J. Romanowska, Arch. of Metallurgy and Materials 49, 917 (2004)
G.P. Vassiliev, J. Romanowska, G. Wnuk, Int. J. Mat. Res. 98(6), 1 (2007)
J. Romanowska, G. Wnuk, P. Romanowski, Archives of Metallurgy and Materials, 53(4) 1107 (2008)
O. Kubaschewski, C.B. Alcock, Metallurgical Thermochemistry (Perg. Press, Oxford, 1972) 237
O. Teppo, J. Niemela, P. Taskinen, Thermochimica Acta 173, 137 (1990)
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Milcheva, N., Romanowska, J. & Vassilev, G. Sn-Ni-Bi liquid phase thermodynamic properties. cent.eur.j.chem. 9, 149–156 (2011). https://doi.org/10.2478/s11532-010-0128-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2478/s11532-010-0128-6