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Interfacial transfer of Cd2+ assisted by 4′ — morpholino-acetophenone-4-phenyl-3-thiosemicarbazone across the water/1,2-dichloroethane interface

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Central European Journal of Chemistry

Abstract

The assisted transfer of heavy metal ions by interfacial complexation with 4′-morpholinoacetophenone-4-phenyl-3-thiosemicarbazone (MAPPT) at the interface between two immiscible electrolyte solutions (ITIES) was studied by cyclic voltammetry. The voltammograms obtained across the water/1,2-dichloroethane interface using the MAPPT ligand in the organic phase shows that the assisted metal ion transfers have different nature for different ions. The quasi-reversible voltammetric peak of the Cd2+ ion was obtained and is discussed in detail. The dependence of the half-wave transfer potential on MAPPT concentration showed that the equilibrium is effectively displaced towards a 1:3 (metal:ligand) stoichiometry with an association constant of log β o =15.46 (±0.11) for the Cd2+ ion, corresponding to the TIC/TID mechanism.

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References

  1. P.O. Dwyer, V.J. Cunnane, J. Electroanal.Chem. 581, 16 (2005)

    Article  Google Scholar 

  2. M. Senda, T. Kakiuchi, T. Osakai, Electrochim. Acta 36, 253 (1991)

    Article  CAS  Google Scholar 

  3. M.F. Mousavi, S. Sahari, N. Alizadeh, M. Shamsipur, Anal. Chim. Acta 414, 189 (2000)

    Article  CAS  Google Scholar 

  4. Z. Samec, E. Samcova, H.H. Girault, Talanta 63, 21 (2004)

    Article  CAS  Google Scholar 

  5. M. Itagaki, T. Ono, K. Watanabe, Electrochim. Acta 44, 4365 (1999)

    Article  CAS  Google Scholar 

  6. I. Bustero, Y. Cheng, J.C. Mugica, T.F. Otero, A.F. Silva, D.J. Schiffrin, Electrochim. Acta 44, 29 (1998)

    Article  CAS  Google Scholar 

  7. C.M. Starks, C.L. Liotta, M. Halpern, Phase Transfer Catalysis (Chapman & Hall, New York, 1994)

    Google Scholar 

  8. D.J. Fermin, H.D. Duong, Z. Ding, P.F. Brevent, H.H. Girault, Electrochem. Commun. 1, 29 (1999)

    Article  CAS  Google Scholar 

  9. V. Beni, M. Ghita, D.W.M. Arrigan, Biosens. Bioelectron. 20, 2097 (2005)

    Article  CAS  Google Scholar 

  10. F. Reymond, V.C. Courtois, G. Steyaert, G. Bouchard, P.A. Carrupt, B. Testa, H.H. Girault, J. Electroanal. Chem. 462, 235 (1999)

    Article  CAS  Google Scholar 

  11. X. Liu, G. Bouchard, H.H. Girault, B. Testa, P. Carrupt, Anal. Chem. 75, 7036 (2003)

    Article  CAS  Google Scholar 

  12. Z. Samec, Pure Appl. Chem. 76, 2147 (2004)

    Article  CAS  Google Scholar 

  13. J. Koryta, Electrochim. Acta 24, 293 (1979)

    Article  CAS  Google Scholar 

  14. L. Sinru, Z. Zaofan, H. Freiser, J. Electroanal. Chem. 210, 137 (1986)

    Article  Google Scholar 

  15. T. Kakutani, Y. Nishiwaki, T. Osakai, M. Senda, Bull. Chem. Soc. Jpn. 59, 781 (1986)

    Article  CAS  Google Scholar 

  16. Z. Samec, P. Papoff, Anal. Chem. 62, 1010 (1990)

    Article  CAS  Google Scholar 

  17. Y. Shao, M.D. Osborne, H.H. Girault, J. Electroanal. Chem. 318, 101 (1991)

    Article  CAS  Google Scholar 

  18. F. Reymond, P.A. Carrupt, H.H. Girault, J. Electroanal. Chem. 449, 49 (1998)

    Article  CAS  Google Scholar 

  19. H.J. Lee, PhD Thesis, EPFL (Lausanne, SWI, 1999)

    Google Scholar 

  20. A.M. Baruzzi, H. Wendt, J. Electroanal. Chem. 279, 19 (1990)

    Article  CAS  Google Scholar 

  21. Y. Cheng, D.J. Schiffrin, P. Guerriero, P.A. Vigato, Inorg. Chem. 33, 765 (1994)

    Article  CAS  Google Scholar 

  22. H. Katano, M. Senda, Anal.Sci. 15, 1179 (1999)

    Article  CAS  Google Scholar 

  23. Y. Cheng, D.J. Schiffrin, J. Electroanal. Chem. 429, 37 (1997)

    Article  CAS  Google Scholar 

  24. H. Katano, H. Kuboyama, M. Senda, J. Electroanal. Chem. 483, 117 (2000)

    Article  CAS  Google Scholar 

  25. L. Tomaszewski, Z. Ding, D. J. Fermin, H. M. Cacote, C. M. Pereira, F. Silva, H.H. Girault, J. Electroanal. Chem. 453, 171 (1998)

    Article  CAS  Google Scholar 

  26. A. Benvidi, S.N. Lanjwani, Z. Ding, Electrochim. Acta 55, 2196 (2010)

    Article  CAS  Google Scholar 

  27. A.J. Blake, M.H.M. Cacote, F.A. Devillanova, A. Garau, F. Isaia, V. Lippolis, C.V. Pereira, F. Silva, L. Tei, Eur. J. Inorg. Chem. 7, 816 (2002)

    Google Scholar 

  28. E.S. Ferreira, A. Garau, V. Lippolis, C.M. Pereira, F. Silva, J. Electroanal. Chem. 587, 155 (2006)

    Article  CAS  Google Scholar 

  29. H. Bingol, E.G. Akgemci, M. Ersoz, T. Atalay, Electroanal. 19, 1327 (2007)

    Article  CAS  Google Scholar 

  30. T. Atalay, E. Ozkan, Thermochim. Acta 246, 193 (1994)

    Article  CAS  Google Scholar 

  31. V. Marecek, Z. Samec, J. Electroanal. Chem. 185, 263 (1985)

    Article  CAS  Google Scholar 

  32. J. Koryta, Electrochim. Acta. 29, 445 (1984)

    Article  CAS  Google Scholar 

  33. A. Berthod, S.C. Broch, J. Chromatogr. A 1037, 3 (2004)

    Article  CAS  Google Scholar 

  34. I.V. Tetko, J. Gasteiger, R. Todeschini, A. Mauri, D. Livingstone, P. Ertl, V.A. Palyulin, E.V. Radchenko, N.S. Zefirov, A.S. Makarenko, V.Y. Tanchuk, V.V. Prokopenko, J. Comput. Aid. Mol. Des. 19, 453 (2005)

    Article  CAS  Google Scholar 

  35. G. Steyaert, G. Lisa, P. A. Carrupt, B. Testa, F. Reymond, H.H. Girault, J. Chem. Soc. Faraday Trans. 93, 401 (1997)

    Article  CAS  Google Scholar 

  36. A. Sherburn, M. Platt, D.W.M. Arrigan, N.M. Boaga, R.A.W. Dryfe, Analyst 128, 1187 (2003)

    Article  CAS  Google Scholar 

  37. H. Katano, M. Senda, Anal. Sci. 12, 683 (1996)

    Article  CAS  Google Scholar 

  38. F. Reymond, G. Lagger, P. Carrupt, H.H. Girault, J.Electroanal. Chem. 451, 59 (1998)

    Article  CAS  Google Scholar 

  39. G. Lagger, L. Tomaszewski, M.D. Osborne, B.J. Seddon, H.H. Girault, J. Electroanal. Chem. 451, 29 (1998)

    Article  CAS  Google Scholar 

  40. H. Matsuda, Y. Yamada, K. Kanamori, Y. Kudo, Y. Takeda, Bull. Chem. Soc. Jpn., 64, 1497 (1991)

    Article  CAS  Google Scholar 

  41. Y. Cheng, D.J. Schiffrin, J. Electroanal. Chem. 429, 37 (1997)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Selcuk University, 42099, Meram/Konya, Turkey

    Haluk Bingol & Tevfik Atalay

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  1. Haluk Bingol
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  2. Tevfik Atalay
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Correspondence to Haluk Bingol.

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Bingol, H., Atalay, T. Interfacial transfer of Cd2+ assisted by 4′ — morpholino-acetophenone-4-phenyl-3-thiosemicarbazone across the water/1,2-dichloroethane interface. cent.eur.j.chem. 8, 1134–1139 (2010). https://doi.org/10.2478/s11532-010-0089-9

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