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Simultaneous displacement of a nitro group during coupling of diazotized o-nitroaniline with phenols

  • Research Article
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Central European Journal of Chemistry

Abstract

During the diazo-coupling reaction, nucleophilic displacement of a nitro group was also observed. This was the main reaction (1→7) when the starting amine bore either a chlorine or methoxy group at the para position (1b–c). The newly prepared compounds (7) might serve as convenient building blocks in synthesis of some heterocycles.

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Authors and Affiliations

  1. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Research Group for Alkaloid Chemistry, 1111, Budapest, Hungary

    Renata Farkas, Mercedesz Törincsi, Pal Kolonits & Lajos Novak

  2. Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, 1111, Budapest, Hungary

    Jenö Fekete

  3. ISDIN, 08006, Barcelona, Spain

    Oscar Jimenez Alonso

Authors
  1. Renata Farkas
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  2. Mercedesz Törincsi
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  3. Pal Kolonits
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  4. Jenö Fekete
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  5. Oscar Jimenez Alonso
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  6. Lajos Novak
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Correspondence to Lajos Novak.

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Farkas, R., Törincsi, M., Kolonits, P. et al. Simultaneous displacement of a nitro group during coupling of diazotized o-nitroaniline with phenols. cent.eur.j.chem. 8, 300–307 (2010). https://doi.org/10.2478/s11532-009-0150-8

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  • DOI: https://doi.org/10.2478/s11532-009-0150-8

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