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Hydrogen-bonding network in the organic salts of 4-nitrobenzoic acid

  • Research Article
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Central European Journal of Chemistry

Abstract

The crystal structures of six novel salts of 4-nitrobenzoic acid — namely, 2-hydroxyethylammonium 4-nitrobenzoate (I), 2-hydroxypropylammonium 4-nitrobenzoate (II), 1-(hydroxymethyl)propylammonium 4-nitrobenzoate (III), 3-hydroxypropylammonium 4-nitrobenzoate (IV), bis-(2-hydroxyethylammonium) 4-nitrobenzoate (V), morpholinium 4-nitrobenzoate (VI) — containing the same anion but different cations have been studied. The ionic forms of I-VI serve as building blocks of the supramolecular architecture, and in crystals they are held together via ionic N-H···O and O-H···O hydrogen bonds. In the crystal packing the building blocks of I-III are self-assembled via N-H...O, O-H···O and C-H...O hydrogen bonds to form the chains which are further consolidated into two-dimensional layers by the same type of interactions. In IV-VI the chain-like structures have been generated by building blocks.

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Authors and Affiliations

  1. Institute of Applied Physics, Academy of Sciences of Moldova, MD-2028, Kishinev, Moldova

    Yurii M. Chumakov & Yurii A. Simonov

  2. Institute of Chemistry Timisoara, Romanian Academy, RO-300223, Timisoara, Romania

    Mata Grozav & Manuela Crisan

  3. IMEM-CNR, Parco Area dele Scienze, I-43010, Fontanini-Parma, Italy

    Gabriele Bocelli

  4. Institute of Organoelement Compounds, Russian Academy of Sciences, R-117 813, Moscow, Russia

    Andrey A. Yakovenko & Dmitry Lyubetsky

Authors
  1. Yurii M. Chumakov
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  2. Yurii A. Simonov
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  3. Mata Grozav
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  4. Manuela Crisan
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  5. Gabriele Bocelli
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  6. Andrey A. Yakovenko
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  7. Dmitry Lyubetsky
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Chumakov, Y.M., Simonov, Y.A., Grozav, M. et al. Hydrogen-bonding network in the organic salts of 4-nitrobenzoic acid. cent.eur.j.chem. 4, 458–475 (2006). https://doi.org/10.2478/s11532-006-0023-3

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  • DOI: https://doi.org/10.2478/s11532-006-0023-3

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