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Solvent Extraction of Some Metal Ions with P-T-Butylcalix[6]Arene

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Abstract

Hexameric p-t-butylcalix[6]arene(tbca, HmL,m=2 or 1) in the various solvents has shown an ability to extract silver(I), pal ladiunI(II) and nickel(II) from the ammonia alkaline solution.The results from liquid liquid extraction study suggested the formation of the 1:1 metal (Ag, Pd and Ni) to tbca complex as the extracted species. A percent extraction (% E) pattern of Pd(II)>Ni(II)>Ag(I) was obtained in 1,2-di eh 1oroethane, dichloromethane and nitrobenzene solvents. The order of high extractabi 1 ity (pH=11.7 and pH=13.5) corresponds to increase of dielectric constant except ni trobenzene.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kobe University, Rokkodai-machi, Nada-ku, Kobe, 657, Japan

    Yoshitaka Masuda, Tetuya Sawano & Eiichi Sekioo

Authors
  1. Yoshitaka Masuda
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  2. Tetuya Sawano
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  3. Eiichi Sekioo
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Masuda, Y., Sawano, T. & Sekioo, E. Solvent Extraction of Some Metal Ions with P-T-Butylcalix[6]Arene. ANAL. SCI. 7 (Suppl 1), 31–34 (1991). https://doi.org/10.2116/analsci.7.Supple_31

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  • DOI: https://doi.org/10.2116/analsci.7.Supple_31

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