Abstract
The quenching of chemiluminescence between cyclohexane and methylsilicone solid polymer was applied to the determination of water in nonaqueous solutions using a flow injection method. The proposed system comprises one single flow line and is expected to serve as a rapid, simple and highly selective method. The analytical time required was less than 4 s for a single run. Although 10(v/v)% tetrahydrofuran and 10(v/v)% acetonitrile gave interfering signals of a few percent to the quenching response of a 0.7(v/v)% solution of water, thirty five ionic species (such as metal ions) did not interfere with the quenching signal of water, even when their concentration was as large as 1×10-2 M. The detection limit was 0.1(v/ v)%for 10 μl sample injection, and the relative standard deviation was 2.3% in 10 repeated runs involving 10 μl injections of 1.0(v/v)% solutions of water. The present method was compared with that of Karl Fischer by analyzing actual samples, coolant and hydraulic fluids used for automobiles; the values obtained by the two methods agreed well with each other.
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Ishii, M. Rapid and Selective Determination of Water in Nonaqueous Solutions by Flow Injection Method Using Quenching Reaction of Chemiluminescence between Cyclohexane and Methylsilicone Solid Polymer. ANAL. SCI. 7, 703–707 (1991). https://doi.org/10.2116/analsci.7.703
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DOI: https://doi.org/10.2116/analsci.7.703