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Determination of Sulfate Ion with 2-Aminoperimidine Hydrobromide Using an Optode Based on Tetrabromophenolphthalein Ethyl Ester Membrane

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Abstract

An optode method for the determination of sulfate ion was developed. The optode membrane is 2-nitrophenyl octyl etherplasticized poly(vinyl chloride) membrane containing tetrabromophenolphthalein ethyl ester. The method is based on formation of an ion associate between the excess of 2-aminoperimidine hydrobromide (Ap) and sulfate ion in the sample solution, and detection of the concentration of the remaining Ap ion by the optode. Under the optimal conditions, a good linear relationship was found to exist between the absorbance of the optode membrane, and concentrations of sulfate ion in a concentration range from 20 to 400 μM. The developed optode method was applied to the determination of sulfate ion in environmental water samples.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Shibaura Institute of Technology, Toyosu, Koto, Tokyo, 135-8548, Japan

    Takashi Masadome & Hidekazu Ishikawa

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  1. Takashi Masadome
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  2. Hidekazu Ishikawa
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Correspondence to Takashi Masadome.

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Masadome, T., Ishikawa, H. Determination of Sulfate Ion with 2-Aminoperimidine Hydrobromide Using an Optode Based on Tetrabromophenolphthalein Ethyl Ester Membrane. ANAL. SCI. 34, 383–385 (2018). https://doi.org/10.2116/analsci.34.383

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  • DOI: https://doi.org/10.2116/analsci.34.383

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