Abstract
Both 206Pb-labeled trimethyllead (TML) and triethyllead (TEL) were synthesized from 206Pb-enriched metallic Pb certified reference material (NIST SRM 983) and iodomethane or iodoethane through a one-process reaction in a closed system using centrifuge tubes, respectively. Organolead compounds in an urban dust reference material (BCR CRM 605) were extracted with an acetic acid/methanol (1:1) solution, which was mechanically shaken for 24 h. After adjusting the pH of the extracted solution to pH 5, the extracted organolead compounds were derivatized by tetrabutylammonium tetrabutylborate (TATB) and measured with GC-ICPMS. The analytical results of TML and TEL for BCR CRM 605 were 8.22 ± 0.04 μg kg-1 (mean ± standard deviation, n = 3) and 1.12 ± 0.06 μg kg-1, respectively. The analytical results of TML agreed well with the certified value (7.9 ± 1.2 μg kg-1).
Similar content being viewed by others
References
J. Yoshinaga, “Organometallic Compounds in the Environment”, ed. P. Craig, 2002, Wiley, Chichester.
W. R. A. De Jonghe, D. Chakraborti, and F. C. Adams, Environ. Sci. TechnoL, 1981, 15, 1217.
M. Burke, Environ. Sci. Technol., 2004, 38, 326A.
I. Salma, W. Maenhautc, S. Dubtsovc, E. Zemplén-Pappd, and G. Záraya, Microchem. J., 2000, 67, 127.
R. M. Harrison and D. P. H. Laxen, Environ. Sci. TechnoL, 1978, 12, 1384.
O. J. Nielsen, D. J. O’Farrell, J. J. Treacy, and H. W. Sidebottom, Environ. Sci. TechnoL, 1991, 25, 1098.
M. Radojevic, and R. M. Harrison, Atmos. Environ., 1987, 21, 2403.
C. A. Ponce de Leon, M. Montes-Bayon, and J. A. Caruso, J. Chromatogr, A, 2002, 974, 1.
J. Ruiz, Encinar, P. Rodriguez-Gonzalez, J. I. G. Alonso, and A. Sanz-Medel, TrAC Trends Anal. Chem., 2003, 22, 108.
B. Bouyssiere, J. Szpunar, and R. Lobinski, Spectrochim. Acta, Part B, 2002, 57B, 805.
N. Poperechna, and K. G. Heumann, Anal. Chem., 2005, 77, 511.
N. Poperechna, and K. G. Heumann, Anal. Bioanal. Chem., 2005, 383, 153.
K. Inagaki, A. Takatsu, T. Watanabe, T. Kuroiwa, Y. Aoyagi and K. Okamoto, Anal. Bioanal. Chem., 2004, 378, 1265.
K. Inagaki, A. Takatsu, T. Watanabe, T. Kuroiwa, Y. Aoyagi, and K. Okamoto, Analyst, 2003, 128, 265.
M. Monperrus, R. C. Rodriguez Martin-Doimeadios, J. Scancar, D. Amourox, and O. F. X. Ronard, Anal. Chem., 2003, 75, 4095.
J. Quarnstrom, L. Lambertssin, S. Harvarinasab, P. Hultman, and W. Freeh, Anal. Chem., 2003, 75, 4120.
A. V. Hirner, Anal. Bioanal. Chem., 2006, 385, 555.
I. Ahmad, Y. K. Chau, P. T. Wong, A. J. Carty, and L. Taylor, Nature, 1980, 287, 716.
A. W. P. Jarvie and A. P. Whitmore, Environ. TechnoL Lett., 1981, 2, 197.
L. J. Snyder and J. M. Bentz, Nature, 1982, 296, 228.
K. Bergmann, and B. Neidhart, Fresenius J. Anal. Chem., 1996, 356, 57.
I. A. Leal-Granadillo, J. I. G. Alonso, and A. Sanz-Medel, Anal. Chim. Acta, 2000, 423, 21.
J. R. Encinar, I. L. Granadillo, J. I. G. Alonso, and A. Sanz-Medel, J. Anal. At. Spectrom., 2001, 16, 475.
J. W. Huang, G. Ilgan, and E. Matzner, Anal. Chim. Acta, 2003, 493, 23.
P. Jitaru, I. Goenaga, A. Heidi, and J. Freddy, J. Anal. At. Spectrom., 2004, 19, 867.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yabutani, T., Motonaka, J., Inagaki, K. et al. Simultaneous Determination of Trimethyl- and Triethyllead in Urban Dust by Species-specific Isotope Dilution/Gas Chromatography-Inductively Coupled Plasma Mass Spectrometry. ANAL. SCI. 24, 791–794 (2008). https://doi.org/10.2116/analsci.24.791
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2116/analsci.24.791