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HPLC Retention Behaviors of p-Electron Rich Compounds on Ni2+- and Cu2+-Phthalocyanine Derivatives Bound to Silica Gels in Polar Eluents

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Abstract

The effect of the central metal of columns packed with silica gels binding Ni2+- and Cu2+-phthalocyanine derivatives (Ni-and Cu-PCSDs) on the retention behavior of poly-aromatic-hydrocarbons (PAHs) thereof in a polar eluent was examined. The retention factors of PAHs on the Ni- and Cu-PCSDs in 80% methanol showed a good linear correlation. The Cu-PCSD column exhibited the π-π interactions for PAHs, while the Ni-PCSD column exhibited the π-d interactions for PAHs in addition to the π-π interaction for PAHs. Further, an investigation of the retention behavior of anthracene derivatives having different substituents revealed that the Ni- and Cu-PCSD columns could recognize the differences of substituents only in a polar eluent.

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Authors and Affiliations

  1. Faculty of Medicine, Kagawa University, Ikenobe, Miki-cho, Kagawa, 761-0793, Japan

    Ikuko Tsukamoto, Madoka Saito & Masaki Mifune

  2. Department of Pharmaceutical Chemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima-Naka, Okayama, 700-8530, Japan

    Madoka Saito, Minako Yamane, Kenji Kawata & Yuji Kitamura

  3. Department of Pharmaceutical Sciences, Graduate School of Medicine and Dentistry and Pharmaceutical Sciences, Okayama University, Tsushima-Naka, Okayama, 700-8530, Japan

    Youji Kitamura & Yutaka Saito

  4. Faculty of Pharmaceutical Sciences, Mukogawa Women’s University, Koshien Kubancho, Nishinomiya, 663-8179, Japan

    Jun Haginaka

Authors
  1. Ikuko Tsukamoto
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  2. Madoka Saito
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  3. Minako Yamane
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  4. Kenji Kawata
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  5. Yuji Kitamura
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  6. Youji Kitamura
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  7. Masaki Mifune
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  8. Yutaka Saito
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  9. Jun Haginaka
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Correspondence to Ikuko Tsukamoto.

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Tsukamoto, I., Saito, M., Yamane, M. et al. HPLC Retention Behaviors of p-Electron Rich Compounds on Ni2+- and Cu2+-Phthalocyanine Derivatives Bound to Silica Gels in Polar Eluents. ANAL. SCI. 22, 1035–1038 (2006). https://doi.org/10.2116/analsci.22.1035

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  • DOI: https://doi.org/10.2116/analsci.22.1035

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