Abstract
A highly spectrophotometric method for the determination of aluminum was developed. This method used the color reaction between m-carboxyphenylfluorone (MCPF) as a novel chemical probe and aluminum in the presence of a surfactant, poly(N-vinylpyrrolidone) (PVP, K-90) (0.03 - 1.40 μg of aluminum in a final volume of 10 ml at 561 nm). The proposed method showed excellent sensitivity (molar absorptibity of 1.70 × 105 1 mol-1 cnr1) and reproducibility (within-day precision: RSD = 0.35% n = 6, between-day precision: RSD = 0.44% n = 6). Linearity was achieved over the range 3 - 140 μg L-1 with a correlation coefficient of 0.9999, and the effects of foreign substances were low.
Similar content being viewed by others
References
H. H. Malluche, Nephrol Dial. Transplant, 2002, 77, 21.
N. M. Roberts, A. Clough, J. P. Bellia, and J. Y. Kim, J. Inorg. Biochem., 1998, 69, 171.
P. Fattoretti, B. Freddari, M. Balietti, E. Moccheduani, J. Scancar, P. Zambenedetti, and P. Zatta, J. Alzheimers. Dis., 2003, 5, 437.
T. P. Flaten, A. G. Alfrey, J. D. Birchall, J. Savory, and R. A. Yokel, J. Toxicol Environ. Health, 1996, 48, 527.
World Health Organization, Environmental Health Criteria 194, Aluminium, Genova: WHO, 1997.
A. G. Alfrey, G. R. LeGendre, and W. D. Kaehny, N. Engl J. Med., 1976, 294, 184.
F. R. Alderman and H. J. Gitelman, Clin. Chem., 1980, 26, 258.
M. Bettinelli, U. Baroni, F. Fontana, and P. Poisetti, Analyst [London], 1985, 110, 19.
F. Y. Leung and A. R. Henderson, Clin. Chem., 1982, 28, 2139.
W. Frech, A. Cedergren, C. Cederberg, and J. Vessman, Clin. Chem., 1982, 28, 2259.
N. Violante, F. Petrucci, P. Delle Femmine, and S. Caroli, Microchem. J., 1992, 46, 199.
D. Blazejak-Ditges, Z. Anal. Chem., 1969, 246, 241.
Z. Marczenko and M. Jarosz, Analyst [London], 1982, 107, 1431.
K. Watanabe, H. Yoshizawa, and K. Kawagaki, Bunseki Kagaku, 1981, 30, 640.
N. M. Zolotukhina and T. M. Erenpreis, Zavodsk. Lab., 1979, 45, 257.
I. Mori, T. Yabuki, Y. Fujita, and T. Matsuo, Anal. Lett., 1997, 30, 953.
I. Mori, Y. Fujita, M. Toyoda, and K. Tanaka, Anal. Lett., 1992, 25, 2377.
I. Mori, Y. Fujita, M. Toyoda, and M. Kashiwagi, Fresenius’ Z. Anal. Chem., 1991, 340, 57.
Y. Fujita, I. Mori, and M. Toyoda, Anal. Sci., 1990, 6, 607.
C. Lieberman, Chem. Ber., 1901, 34, 2299.
A. Iwasa and T. Yonemoto, Bunseki Kagaku, 1992, 41, T7.
A. Iwasa, T. Yonemoto, I. Matsubara, and K. Nakagawa, Bunseki Kagaku, 1987, T113.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kamino, S., Yamaguchi, T., Mori, T. et al. Spectrophotometric Determination of Aluminum with m-Carboxyphenylfluorone, a Novel Chemical Probe, and Its Application. ANAL. SCI. 21, 1549–1552 (2005). https://doi.org/10.2116/analsci.21.1549
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2116/analsci.21.1549