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Crystal Structure of Dibenzoyl Diselenide

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Abstract

C14H10O2Se2 is monoclinic, P2i/c. The unit-cell dimensions at 293 K are a = 12.795(2), b = 12.126(2), c = 9.0179(13)Å, β = 107.074(6)°, V = 1337.5(3)Å3, and Z = 4. The R value is 0.048 for 2319 observed reflections. The dihedral angle between the plane C4–C7(O2)-Se1 and C9–C8(O1)-Se2 is 85.6(2)°, keeping the Se atom unshared electron pairs in a more stable configuration with the rest of the molecule. The packing in the crystal is entirely due to van der Waals forces.

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Authors and Affiliations

  1. Departamento de Quimica Inorgánica, Escuela Nacional de Ciencias Biologicas, I. P. N. Prolongation Carpioy Plan de Ayala 11340, México D. F., Mexico

    Federico Martinez Ramos

  2. Departamento de Bioquimica, Instituto de Quimica, Circuito Exterior, C. U., Coyoacán, México D. F., 04510, México

    Manuel Soriano-Garcia

  3. Centro de Graduados e Investigation del Instituto Tecnologico de Tijuana, Blvd. Industrial S/N, Tijuana, Baja California, México

    Gerardo Aguirre Hernandez

Authors
  1. Federico Martinez Ramos
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  2. Manuel Soriano-Garcia
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  3. Gerardo Aguirre Hernandez
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Ramos, F.M., Soriano-Garcia, M. & Hernandez, G.A. Crystal Structure of Dibenzoyl Diselenide. ANAL. SCI. 19, 965–966 (2003). https://doi.org/10.2116/analsci.19.965

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  • DOI: https://doi.org/10.2116/analsci.19.965

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