Abstract
A method for activating ISE is proposed that can allow determination of the fluoride concentration at ng mL−1 level with good precision and accuracy. Fluoride ISE is activated in 0.5 mol L−1 HClO4 medium and then fluoride is determined in the same medium. The linear range for the determination of fluoride is between 1.00 × 10−2–1.00 × 10−7 mol L−1, and the detection limit of the method is 1.0 ng mL−1. The advantage of this method is that it is free from the use of TISAB solution while being, time-saving and labor-saving. A mechanism study of the activation of FISE in HClO4 medium is explained. The method has been used for the determination of trace fluoride in milk and flour with satisfactory results.
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Shi, Sx., Zhu, Zg., Suo, R. et al. Rapid Method for the Determination of Trace Fluoride and Activation of Ion-Selective Electrode. ANAL. SCI. 19, 671–673 (2003). https://doi.org/10.2116/analsci.19.671
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DOI: https://doi.org/10.2116/analsci.19.671