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Crystal Structure of Bis(2-(2-thiazolylazo)-4-methylphenol)cobalt(III)chloride

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Abstract

The reaction between CoCl2·6H2O and 2–1-(2-thiazolylazo)-p-cresol (TAC) in acetone resulted in six coordinated cobalt(III) complex, [Co(TAC)2]Cl3. Two TAC ligands coordinate with cobalt ion forming four five membered chelate rings. The cobalt ion is octahedrally coordinated by a phenolic oxygen, azo nitrogen and nitrogen in thiazole rings. Three chloride ions are disordered.

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Authors and Affiliations

  1. Laboratory of Crystallography and Gemmology, Department of Chemistry, Faculty of Science, Kasetsart University, Thailand

    Lumduan Mangsup & Sutatip Siripaisarnpipat

  2. Department of Physics, Faculty of Science and Technology, Thammasart University, Thailand

    Narongsuk Chaichit

Authors
  1. Lumduan Mangsup
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  2. Sutatip Siripaisarnpipat
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  3. Narongsuk Chaichit
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† To whom correspondence should be addressed.

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Mangsup, L., Siripaisarnpipat, S. & Chaichit, N. Crystal Structure of Bis(2-(2-thiazolylazo)-4-methylphenol)cobalt(III)chloride. ANAL. SCI. 19, 1345–1346 (2003). https://doi.org/10.2116/analsci.19.1345

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  • DOI: https://doi.org/10.2116/analsci.19.1345

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