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A Selective Joint Determination of Salicylic Acid in Actinidia chinensis Combining a Molecularly Imprinted Monolithic Column and a Graphene Oxide Modified Electrode

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Abstract

A new combination between selective polymer monolith microextraction (PMME) and sensitive differential pulse voltammetry (DPV) was developed for the determination of the phytohormone salicylic acid (SA) in Actinidia chinensis. A molecularly imprinted monolithic column (MIMC) thermally in-situ polymerized in a micropipette tip by using SA as a template, 4-vinyl pyridine (4-VP) as a functional monomer and ethylene glycol dimethacrylate (EGDMA) as a crosslinker in the mixed porogen of toluene and dodecanol, was employed for the microextraction of SA. The prepared MIMC was characterized by a Fourier transform infrared spectrometer (FI-TR), scanning electron microscope (SEM) and thermo gravimetric analysis (TGA). The results confirmed the binary continuous structure of the porous network. The extracted SA was determined by DPV on a graphene oxide (GO) modified electrode. The joint conditions between MIMC and DPV were investigated practically. Under the optimum conditions, SA could be determined selectively and sensitively in a linear range from 0.1 to 60.0 μg g−1. The limit of detection was 0.03 μg g−1 and the recoveries were between 86.2 and 105.2%. The proposed joint method was successfully used to determine SA in Actinidia chinensis.

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Acknowledgments

This research is supported by the National Nature Science Foundation of China (No. 61301048) and the Natural Science Fund for Creative Research Groups of Hubei Province of China (No. 2011CDA111).

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Authors and Affiliations

  1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules & College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, PR China

    Can Zhou, Jianxiong Chen, Xueping Dang, Xiwen Ma, Youhong Ai, Jianlin Huang & Huaixia Chen

  2. Hubei Key Laboratory of Medical Information Analysis and Tumor Diagnosis & Treatment, Wuhan, 430062, PR China

    Jianxiong Chen, Xueping Dang & Xiwen Ma

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  1. Can Zhou
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  2. Jianxiong Chen
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  3. Xueping Dang
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  4. Xiwen Ma
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  5. Youhong Ai
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  6. Jianlin Huang
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  7. Huaixia Chen
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Correspondence to Xueping Dang or Huaixia Chen.

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Zhou, C., Chen, J., Dang, X. et al. A Selective Joint Determination of Salicylic Acid in Actinidia chinensis Combining a Molecularly Imprinted Monolithic Column and a Graphene Oxide Modified Electrode. ANAL. SCI. 34, 823–829 (2018). https://doi.org/10.2116/analsci.18P025

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  • DOI: https://doi.org/10.2116/analsci.18P025

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