Abstract
Sodium ions can be used as efficient chemical ionization agents in electrospray mass spectrometry of a wide variety of neutral metal bipyridine complexes. This ionization method was successfully permitted the identification of a neutral metal complex generated during the photochemical ligand substitution reaction: [Re(bpy)(CO)3P(OEt)3]++Cl– ® Re(bpy)(CO)2P(OEt)3Cl+CO by sodium adduct formation to produce an electrospray-active species [Re(bpy)(CO)2P(OEt)3Cl+Na]+.
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Hori, H., Ishihara, J., Koike, K. et al. Electrospray Mass Spectrometric Detection of Neutral Metal Bipyridine Complexes Using Sodium Ions and Its Application in the Analysis of a Photochemical Ligand Substitution Reaction. ANAL. SCI. 14, 287–292 (1998). https://doi.org/10.2116/analsci.14.287
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DOI: https://doi.org/10.2116/analsci.14.287