Abstract
Engineers and scientists are in search of new construction materials to advance exploration in space and to reduce our CO2 emissions on Earth. Biopolymer-bound Soil Composite (BSC), a promising novel construction material, is being investigated for extrusion-based 3D printing applications that could both assist in lunar habitat construction and reduce earth-based CO2 emissions. For extrusion-based 3D printing applications, knowledge of BSC structuration is required. In this study, we evaluated the formation of a crust on the outer surface of BSC test specimens at various desiccation levels and the effect of the crust on the strength of the specimens. We measured the crust depth, determined the crust moisture content, and performed uniaxial compressive strength testing for selected specimens. We found that the depth of the BSC crust develops linearly with overall desiccation level and is the source of the specimen’s initial strength and stiffness. Additionally, we found that the crust begins to form when the biopolymer solution concentration at the specimen surface reaches a critical value and then moves inward with moisture loss. A methodology for modeling BSC structuration is developed based on knowledge of the BSC mixture design, the level of BSC desiccation, and the crust-forming biopolymer solution concentration.
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Notes
The water concentration was calculated by dividing the mass of water by the total mass (water, soil, and biopolymer). This value is not the same as the moisture content, defined in BSC research as the mass ratio of water to soil [4]. The initial BSC mixture had a water concentration of 11.5% and moisture content of 14.3%.
The use of a quadratic growth function resulted in better model agreement with experimental data compared to a linear or cubic growth function, and the nonlinear function is consistent with surface drying profiles found in the literature [20].
The [%w/w]BP*(r = R) = 100% assumption can only be valid in an environment with no water vapor (0% R.H.); however, this approximation is suitable for most drying environments.
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Acknowledgements
The authors would like to thank the John A. Blume Earthquake Engineering Center at Stanford University for laboratory equipment funding and other resources. The authors would also like to acknowledge the U.S. Army for partially funding this research through the Advanced Civil Schooling (ACS) program. Additionally, the authors would like to thank SSERVI-NASA for supplying the BP-1 lunar regolith simulant. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the United States Army or NASA.
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Biggerstaff, A., Lepech, M. & Loftus, D. Determining the structuration of biopolymer-bound soil composite. Mater Struct 55, 190 (2022). https://doi.org/10.1617/s11527-022-02004-9
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DOI: https://doi.org/10.1617/s11527-022-02004-9