As described by the nonlinear acoustic theory [20], the cracks of concrete could produce both the classical nonlinearity expressed by the power series of the strain and the nonclassical hysteresis nonlinearity containing the term of strain rate. The even harmonic is only caused by the classical nonlinearity and the odd harmonic is caused by both the classical and nonclassical nonlinearity [20]. Since only the second harmonic is measured in this work, the material nonlinearity is assumed to solely come from the quadratic order of strain in the constitutive relationship [21, 22]. The measurement of quadratic nonlinear parameter is thus the key step for the nonlinear ultrasonic characterization of material defects. As follows, the theoretical background of nonlinear parameter measurements based on the Rayleigh surface wave is concisely presented and more details can be referred to previous publications [23,24,25,26].
First, the Rayleigh wave is assumed to propagate along the x axis of an isotropic, macroscopically homogeneous, and nonlinear elastic half space and z axis refers to the distance to the surface.
Because of the existence of the shear and longitudinal wave, the linear displacement in z axis can be expressed as [23]
$$u_{z} (\omega ) = iA_{1} \frac{{b_{1} }}{{k_{R} }}\left( {e^{{b_{1} z}} - \frac{{2k_{R}^{2} }}{{k_{R}^{2} + b_{2}^{2} }}e^{{b_{2} z}} } \right)e^{{i\left\{ {k_{R} (x - C_{R} t)} \right\}}}$$
(1)
where C
R
is the speed of the Rayleigh wave, ω = C
R
k
R
is the fundamental frequency, \(b_{1} = \sqrt {k_{R}^{2} - k_{L}^{2} }\) and \(b_{2} = \sqrt {k_{R}^{2} - k_{S}^{2} }\). k
L
, k
S
and k
R
are the wave numbers of the longitudinal wave, the shear wave and the Rayleigh wave.
Analogously, we can calculate the displacement of the second harmonic as [22, 23]
$$u_{z} (2\omega ) = iA_{2} \frac{{b_{1} }}{{k_{R} }}\left( {e^{{b_{1} z}} - \frac{{2k_{R}^{2} }}{{k_{R}^{2} + b_{2}^{2} }}e^{{b_{2} z}} } \right)e^{{i\left\{ {k_{R} (x - C_{R} t)} \right\}}}$$
(2)
It has been demonstrated that the quadratic nonlinear parameter is related to the out-of-plane displacement of the Rayleigh waves at the surface (z = 0) as shown in Eq. (3) [22]
$$\beta = \frac{{u_{z} (2\omega )\left| {_{z = 0} } \right.}}{{u_{z}^{2} (\omega )\left| {_{z = 0} } \right.}}\frac{{8b_{i} i}}{{k_{1}^{2} k_{R} x}}\left( {1 - \frac{{2k_{R}^{2} }}{{k_{R}^{2} + b_{2}^{2} }}} \right)$$
(3)
Combine Eqs. (1), (2) and (3), then simplify the equation, the relationship of A
1, A
2 and β can be obtained as follows [17]
$$\beta \propto \frac{{A_{2} x}}{{A_{1}^{2} }}$$
(4)
Since the propagating distance x is constant in the SHG measurements of this work, the nonlinear parameter β used in this work is expressed as
$$\beta = \frac{{A_{2} }}{{A_{1}^{2} }}$$
(5)