Skip to main content

Advertisement

Log in

Resistivity-based chloride-induced corrosion rate prediction models and hypothetical framework for interpretation of resistivity measurements in cracked RC structures

  • Original Article
  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

To present resistivity-based chloride-induced corrosion rate prediction models and hypothetical framework for interpretation of resistivity measurements in cracked RC structures. Parallel corrosion experiments were carried out by exposing one half of 210 beam specimens (120 × 130 × 375 mm) to accelerated laboratory corrosion (cyclic 3 days wetting with 5 % NaCl solution followed by 4 days air-drying) while the other half were left to undergo natural corrosion in a marine tidal zone. The specimens were cast using five concretes made using two w/b ratios (0.40 and 0.55) and three binders (100 % CEM I 42.5N (PC), 50/50 PC/GGBS and 70/30 PC/FA). Other variables in the experiments included cover depth (20 and 40 mm), crack width (0, 0.4 and 0.7 mm). Corrosion rate and resistivity were monitored bi-weekly in the specimens. The results relevant to this paper are presented and discussed. Experimental results (both natural and accelerated) show that there is an inverse relationship between corrosion rate and concrete resistivity in both cracked and uncracked RC structures. The results also show that for a given concrete resistivity value, corrosion rate of steel in concrete of a given binder type and w/b ratio increases with increase in crack width. Furthermore, for a given crack width, corrosion rate in cracked concrete is also shown to be influenced by concrete quality. Resistivity-based chloride-induced corrosion rate prediction models for cracked RC structures are proposed. This paper also advocates for the improvement in the interpretation of concrete resistivity measurements with respect to steel corrosion in cracked RC structures. A hypothetical framework to aid in this is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18

Similar content being viewed by others

References

  1. Akatsuka Y, Seki H, Asaoka K (1966) Crack width and reinforcement corrosion in reinforced concrete attacked by sea-water. Cement and Concrete Association, No. 266 (January), pp 38–43

  2. Akhavan A, Shafaatian SMH, Rajabipour F (2012) Quantifying the effects of crack width, tortuosity, and roughness on water permeability. Cem Concr Res 42(2):313–320

    Article  Google Scholar 

  3. Alexander MG, Ballim Y, Stanish K (2008) A framework for use of durability indexes in performance-based design and specifications for reinforced concrete structures. Mater Struct 41(5):921–936

    Article  Google Scholar 

  4. Alonso C, Andrade C, Gonzalez JA (1988) Relation between resistivity and corrosion rate of reinforcements in carbonated mortar made with several cement types. Cem Concr Res 18(5):687–698

    Article  Google Scholar 

  5. Alonso C, Castellote M, Andrade C (2002) Chloride threshold dependence of pitting potential of reinforcements. Electrochim Acta 47(21):3469–3481

    Article  Google Scholar 

  6. Andrade C (2004) Calculation of initiation and propagation periods of service life of reinforcements by using the electrical resistivity. In: Weiss J, Kovler K, Marchand J, Mindess S (eds) Proceedings if the international RILEM symposium on concrete science and engineering (pro048): a tribute to Arnon Bentur

  7. Andrade C, Alonso C (1996) Corrosion rate monitoring in the laboratory and on-site. Constr Build Mater 10(5):315–328

    Article  Google Scholar 

  8. Andrade C, Alonso C, Garcia AM (1990) Oxygen availability in the corrosion of reinforcements. Adv Cem Res 3(11):127–132

    Article  Google Scholar 

  9. Andrade C, D’Andrea R, Castillo A, Castellote M (2009) The use of electrical resistivity as NDT method for the specification of the durability of reinforced concrete. In: Proceedings of the international conference on non-destructive testing in civil engineering (NDTCE’09). June 30th–July 3rd, 2009, Nantes, France

  10. Andrade C, Gonzalez JA (1998) Relation between concrete resistivity and corrosion rate of reinforcements in carbonated mortar made with several cement types. Cem Concr Res 18(5):687–698

    Google Scholar 

  11. Angst U, Elsener B, Larsen CK, Vennesland Ø (2009) Critical chloride content in reinforced concrete: a review. Cem Concr Res 39(12):1122–1138

    Article  Google Scholar 

  12. Arya C, Ofori-Darko FK (1996) Influence of crack frequency on reinforcement corrosion in concrete. Cem Concr Res 26(3):333–353

    Article  Google Scholar 

  13. Azar JH, Janaherian A, Pishvaie MR, Bidhendi MN (2008) An approach to defining tortuosity and cementation factor in carbonate reservoir rocks. J Petrol Sci Eng 60(2):125–313

    Article  Google Scholar 

  14. Broomfield JP (2007) Corrosion of steel in concrete: understanding, investigation and repair, 2nd edn. Taylor & Francis, Oxford

    Google Scholar 

  15. Buenfeld NR, Newman JB (1986) The development and stability of surface layers on concrete exposed to sea-water. Cem Concr Res 16(5):721–732

    Article  Google Scholar 

  16. Buenfeld NR, Newman JB, Page CL (1986) The resistivity of mortars immersed in sea-water. Cem Concr Res 16(4):511–524

    Article  Google Scholar 

  17. Bürchler D, Elsener B, Böhni H (1996) Electrical resistivity and dielectric properties of hardened cement and mortar. Institute of Materials Chemistry and Corrosion, Swiss Federal Institute of Technology, ETH Hönggerber, CH-8093 Zurich, Switzerland

  18. Clear CA (1985) Cement and Concrete Association, Technical Report No. 559, England

  19. Cohen MD, Bentur A (1988) Durability of Portland cement-silica fume pastes in magnesium sulphate and sodium sulphate solutions. ACI Mater J 85(3):148–157

    Google Scholar 

  20. DuraCrete (1998) Modelling of degradation. The European Union—Brite Euram III Project BE95-1347, Document BE95-1347/R4-5

  21. Feliu V, Gonzalez JA, Feliu S (2007) Corrosion estimates from transient response to a potential step. Corros Sci 49(8):3241–3255

    Article  Google Scholar 

  22. Ferreira RM, Jalali S (2006) Quality control based on electrical resistivity measurements. In: Proceedings of the European symposium on serviceability of concrete structures, 12–14 June 2006, Helsinki, Finland, pp. 325–332

  23. Gjørv OE (1986) Diffusion of dissolved oxygen through concrete. Mater Perform 25(12):39–44

    Google Scholar 

  24. Glass G, Page C, Short N, Yu S (1993) An investigation of galvanostatic transient methods used to monitor the corrosion rate of steel in concrete. Corros Sci 35(5–8):1585–1592

    Article  Google Scholar 

  25. Gonzalez JA, Miranda JM, Feliu S (2004) Consideration on the reproducibility of potential and corrosion rate measurements in reinforced concrete. Corros Sci 46(10):2467–2485

    Article  Google Scholar 

  26. Gowers KR, Millard SG (1999) Measurement of concrete resistivity for assessment of corrosion severity of steel using Wenner technique. ACI Mater J 96(5):536–541

    Google Scholar 

  27. Gulikers J (2005) Theoretical considerations on the supposed linear relationship between concrete resistivity and corrosion rate of steel reinforcement. Mater Corros 56(6):393–403

    Article  Google Scholar 

  28. Hassanien A, Glass G, Buenfeld N (1998) The use of small electrochemical perturbations to assess the corrosion of steel in concrete. NDT & E International 31(4):265–272

    Article  Google Scholar 

  29. Hearn N (1991) A recording permeameter for measuring time-sensitive permeability of concrete. Advances in Cementitious Materials (Ceramic Transactions), Mindess S (ed) vol 16, Published by the American Ceramic Society (July 1991), ISBN-13:978-0944904336, pp 463–475

  30. Hope BB, Ip AK, Manning DG (1985) Corrosion and electrical impedance in concrete. Cem Concr Res 15(3):525–534

    Article  Google Scholar 

  31. Hornbostel K, Larsen CK, Geiker MR (2013) Relationship between concrete resistivity and corrosion rate: a literature review. Cem Concr Compos 39(5):60–72

    Article  Google Scholar 

  32. Hunkeler F (1996) The resistivity of pore water solution: a decisive parameter of rebar corrosion and repair methods. Constr Build Mater 10:381–389

    Article  Google Scholar 

  33. Kessler RJ, Powers RG, Vivas E, Paredes MA, Virmani YP (2008) Surface resistivity as an indicator of concrete chloride penetration resistance. In: Proceedings of the international concrete bridge conference, St. Louis, MO, 4–7 May 2008

  34. Lim Y, Noguchi T, Lee H, Shin S (2010) Advanced resistivity method for corrosion evaluation directly above a reinforcement bar. In: Proceedings of the international conference on sustainable building Asia, 24–26 February 2010, Seoul, Korea

  35. López W, González JA (1993) Influence of the degree of pore saturation on the resistivity of concrete and the corrosion rate of steel reinforcement. Cem Concr Res 23(2):368–376

    Article  Google Scholar 

  36. Mackechnie JR (1996) Predictions of reinforced concrete durability in the marine environment. PhD Thesis, Department of civil engineering, University of Cape Town

  37. Mackechnie JR (2001) Predictions of reinforced concrete durability in the marine environment. Research Monograph No. 1, Department of civil engineering, University of Cape Town and the University of Witwatersrand

  38. Malhotra VM (1987) Properties of fresh and hardened concrete incorporating ground granulated blast furnace slag. In: Malhotra VM (ed) Supplementary cementing materials for concrete. Minister of Supply and Services, Canada, pp 291–336

    Google Scholar 

  39. Marta K-K, Jezierski W (2005) Evaluation of concrete resistance to chloride ion penetration by means of electrical resistivity monitoring. J Eng Manag 11(2):109–114

    Google Scholar 

  40. McCarter WJ, Chrisp TM, Starrs G, Blewett J (2003) Characterization and monitoring of cement-based systems using intrinsic electrical property measurements. Cem Concr Res 33(2):197–206

    Article  Google Scholar 

  41. Millard SG, Ghassemi MH, Bugey J, Jafar MI (1990) Assessing the electrical resistivity of concrete structures for corrosion durability studies, corrosion of reinforcement in concrete (Page, Treadaway, Bamforth (eds)), Elsevier, London, pp 303–313

  42. Neville AM (2002) Autogenous healing: a concrete miracle? Concr Int 24(11):76–82

    Google Scholar 

  43. Nygaard PV, Geiker MR (2005) Amethod for measuring the chloride threshold level required to initiate reinforcement corrosion in concrete. Mater Struct 38:489–494

    Article  Google Scholar 

  44. Østvik JM (2004) Thermal aspects of corrosion of steel in concrete. PhD Thesis, Department of structural engineering, N - 7034 Trondheim, Norway, The Norwegian University of Science and Technology

  45. Otieno MB (2008) Corrosion propagation in cracked and uncracked concrete. Masters Dissertation, Department of civil engineering, University of Cape Town

  46. Otieno MB, Alexander MG, Beushausen H-D (2010) Corrosion in cracked and uncracked concrete—influence of crack width, concrete quality and crack re-opening. Mag Concr Res 62(6):393–404

    Article  Google Scholar 

  47. Otieno MB, Alexander MG, Beushausen H-D (2010) Suitability of various measurement techniques for assessing corrosion in cracked concrete. ACI Mater J 107(5):481–489

    Google Scholar 

  48. Otieno MB, Beushausen H-D, Alexander MG (2012) Towards incorporating the influence of cover cracking on steel corrosion in RC design codes—the concept of performance-based crack width limits. Mater Struct 45(12):1805–1816

    Article  Google Scholar 

  49. Pettersson K, Jorgensen O (1996) The effect of cracks on reinforcement corrosion in high-performance concrete in a marine environment. Third ACI/CANMET international conference on the performance of concrete in marine environment. St. Andrews, Canada, pp 185–200

  50. Polder R, Andrade C, Elsener B, Vennesland O, Gulikers J, Weidert R, Raupach M (2000) Test methods for onsite measurement of resistivity of concrete. Mater Struct 33(10):603–611

    Article  Google Scholar 

  51. Princigallo A, Breugel K, Levita G (2003) Influence of the aggregate on the electrical conductivity of Portland cement concretes. Cem Concr Res 33(11):1755–1763

    Article  Google Scholar 

  52. Raupach M (1996) Chloride-induced macrocell corrosion of steel in concrete—theoretical background and practical consequences. Constr Build Mater 10(5):329–338

    Article  Google Scholar 

  53. Riding KA, Poole JL, Schindler AK, Juenger MCG, Folliard KJ (2008) Simplified concrete resistivity and rapid chloride permeability test method. ACI Mater J 105(4):390–394

    Google Scholar 

  54. Rodriguez J, Ramírez E, Gonzalez JA (1994) Methods for studying corrosion in reinforced concrete. Mag Concr Res 47(167):81–90

    Article  Google Scholar 

  55. Rose JH (1987) Effect of cementitious blastfurnace slag on chloride permeability of concrete. ACI Special Publication, vol 102 (September), pp. 107–126

  56. Scott AN, Alexander MG (2007) The influence of binder type, cracking and cover on corrosion rates of steel in chloride-contaminated concrete. Mag Concr Res 59(7):495–505

    Article  Google Scholar 

  57. Sengul O, Gjørv O (2008) Electrical resistivity measurements for quality control during concrete construction. ACI Mater J 105(6):541–547

    Google Scholar 

  58. Shi C (2004) Effect of mixing proportions of concrete on its electrical conductivity and the rapid chloride permeability test (ASTM C1202 or ASSHTO T277) results. Cem Concr Res 34(3):537–545

    Article  Google Scholar 

  59. Silva BJ, Jalali S, Fereira RM (2006) Estimating electrical resistivity based on early-age measurements. In: Proceedings of the international RILEM workshop on performance-based evaluation and indicators for concrete durability. Madrid, pp 111–119

  60. Stansbury EE, Buchanan RA (2000) Fundamentals of electrochemical corrosion. ASM Int, Ohio

    Google Scholar 

  61. Streicher PE, Alexander MG (1995) A chloride conduction test for concrete. Cem Concr Res 25(6):1284–1294

    Article  Google Scholar 

  62. Tuutti K (1982) Corrosion of steel in concrete. Stockholm, Swedish Cement and Concrete Research Institute, S-100 44 Stockholm, Report No. CBI Research 4:82, ISSN 0346-6906, p 468

  63. Weydert R, Gehlen C (1999) Electrolytic resistivity of cover concrete: relevance, measurement and interpretation. In: Proceedings of CIB W078 workshop on information technology in construction, 31 May–3 June 1999

  64. Whiting DA, Nagi MA (2003) Electrical resistivity of concrete: a literature review. Portland Cement Association, Illinois

    Google Scholar 

  65. Woelfl GA, Lauer K (1979) The electrical resistivity of concrete with the emphasis on the use of electrical resistance for measuring moisture content. Cem Concr Aggreg 1(2):64–67

    Article  Google Scholar 

  66. Xiao L, Li Z (2008) Early-age hydration of fresh concrete monitored by non-contact electrical resistivity measurement. Cem Concr Res 38(3):312–319

    Article  Google Scholar 

Download references

Acknowledgments

The authors wish to acknowledge with gratitude the financial support over the period of this work (2009–2013) received from: The University of Cape Town, the erstwhile Cement and Concrete Institute (C&CI), The National Research Foundation (NRF), Sika (SA) Pty Ltd., PPC Ltd, AfriSam, The Tertiary Education Support Programme (TESP) of ESKOM, and the Water Research Commission (WRC).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Otieno.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Otieno, M., Beushausen, H. & Alexander, M. Resistivity-based chloride-induced corrosion rate prediction models and hypothetical framework for interpretation of resistivity measurements in cracked RC structures. Mater Struct 49, 2349–2366 (2016). https://doi.org/10.1617/s11527-015-0653-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1617/s11527-015-0653-z

Keywords

Navigation