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Transparent and conductive F-Doped SnO2 nanostructured thin films by sequential nebulizer spray pyrolysis

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Abstract

Transparent conductive oxides (TCOs) are a key component in many optoelectronic applications such as solar cells, flat panel displays, sensors, touch screens, light-emitting diodes, frost-resistant surfaces, and smart windows. The high electronic conductivity and high optical transmission are essential properties of TCOs for these applications. Owing to chemical inertness and high-temperature tolerance, F-doped tin oxide (FTO) films have much demand in a variety of electrochemical devices. In this work, transparent and electrically conductive FTO thin films are prepared on soda-lime glass substrates. The films are fabricated by sequential nebulized spray pyrolysis with the help of a homemade low-cost spray gun. The surface morphology of the films is analyzed using scanning electron micrographs (SEMs). It is found that the surface is homogeneous and FTO crystallite sizes are in the order of ~ 10 nm. XRD pattern of the FTO films exhibits 2θ peaks for corresponding SnO2 crystal planes at 26.64° (110), 33.90° (101), 37.95° (200), 51.87° (211), 56.17° (200), 60.05° (310), 61.89° (301). The crystallite sizes calculated from XRD data are in agreement with that of SEM. Optical transparency and bandgap energies are evaluated by UV visible spectroscopy. The FTO films with 15 Ω cm−2 sheet resistance were used to prepare quasi-solid-state dye-sensitized solar cells with a TiO2 photoelectrode. The solar cell showed a ~ 5% energy conversion efficiency with high short-term stability.

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References

  1. D. Solís-Cortés, R. Schrebler, E. Navarrete-Astorga, M. López-Escalante, F. Martín, J.R. Ramos-Barrado, E.A. Dalchiele, J. Alloys Compd. 808, 151776 (2019). https://doi.org/10.1016/j.jallcom.2019.151776

    Article  CAS  Google Scholar 

  2. T. Minami, MRS Bull. 25, 38–44 (2000)

    Article  CAS  Google Scholar 

  3. B. Han et al., Adv. Mater. 26(6), 873–877 (2014). https://doi.org/10.1002/adma.201302950

    Article  CAS  Google Scholar 

  4. A.C. Zhou, ACS Nano 4(1), 11–14 (2010). https://doi.org/10.1021/nn901903b

    Article  CAS  Google Scholar 

  5. S. Abdullahi, A.U. Moreh, B. Hamza, U. Sadiya, Z. Abdullahi, M.A. Wara, H. Kamaluddeen, M.A. Kebbe, U.F. Monsurat, IJIAS. 9, 947–955 (2014)

    Google Scholar 

  6. L. Dominici, F. Michelotti, T.M. Brown et al., Opt. Express 17(12), 10155–10167 (2009). https://doi.org/10.1364/OE.17.010155

    Article  CAS  Google Scholar 

  7. S.-W. Feng, Y.-H. Wang, C.-Y. Tsai, T.-H. Cheng, H.-C. Wang, Sci. Rep. 10(1), 1–8 (2020). https://doi.org/10.1038/s41598-020-67274-1

    Article  CAS  Google Scholar 

  8. T. Minami, Semicond. Sci. Technol. 20(4), S35 (2005). https://doi.org/10.1088/0268-1242/20/4/004

    Article  CAS  Google Scholar 

  9. Z. Chen, W. Li, R. Li, Y. Zhang, G. Xu, H. Cheng, Langmuir 29(45), 13836–13842 (2013). https://doi.org/10.1021/la4033282

    Article  CAS  Google Scholar 

  10. L.H. Lalasari, T. Arini, L. Andriyah, F. Firdiyono, A.H. Yuwono, AIP Conf. Proc. 1964(1), 020001 (2018). https://doi.org/10.1063/1.5038283

    Article  CAS  Google Scholar 

  11. T. Dhakal et al., Sol. Energy 86(5), 1306–1312 (2012). https://doi.org/10.1016/j.solener.2012.01.022

    Article  CAS  Google Scholar 

  12. S. Sarker, H.W. Seo, Y.K. Jin, M.A. Aziz, D.M. Kim, Mater. Sci. Semicond. Process. 93, 28–35 (2019). https://doi.org/10.1016/j.mssp.2018.12.023

    Article  CAS  Google Scholar 

  13. B. Russo, G.Z. Cao, Appl. Phys. A. 90(2), 311–315 (2008). https://doi.org/10.1007/s00339-007-4274-4

    Article  CAS  Google Scholar 

  14. D. Keller, H. Barad, E. Rosh-Hodesh, A. Zaban, D. Cahen, MRS Commun. 8(3), 1358–1362 (2018). https://doi.org/10.1557/mrc.2018.179

    Article  CAS  Google Scholar 

  15. A. Purwanto, H. Widiyandari, A. Jumari, Thin Solid Films 520(6), 2092–2095 (2012). https://doi.org/10.1016/j.tsf.2011.08.041

    Article  CAS  Google Scholar 

  16. N.S. Khalid, W. Zaki, W. Suhaimizan, M.K. Bin Ahmad, Adv. Mater. Res. 1109, 11–14 (2015). https://doi.org/10.4028/www.scientific.net/AMR.1109.11

    Article  Google Scholar 

  17. S. Saehana, Z. Arifin, Nasar, IOP Conf. Ser. Mater. Sci. Eng. 622(1), 012032 (2019). https://doi.org/10.1088/1757-899X/622/1/012032

  18. T.M.W.J. Bandara, L. DeSilva, J. Ratnasekera, K. Hettiarachchi, A. Wijerathna, M. Thakurdesai, J. Preston, I. Albinsson, B. Mellander, Renew. Sust. Energ. Rev. 103, 282–290 (2019). https://doi.org/10.1016/j.rser.2018.12.052

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics and Post Graduate Institute of Science, Faculty of Science, University of Peradeniya, Peradeniya, Sri Lanka

    T. M. W. J. Bandara, A. A. A. P. Aththanayake & P. Samarasekara

  2. National Institute of Fundamental Studies, Hantana Road, Kandy, Sri Lanka

    G. R. A. Kumara & K. Tennakone

  3. University of West Georgia, Carrollton, USA

    L. Ajith DeSilva

  4. Department of Physics, Georgia State University, Atlanta, USA

    K. Tennakone

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  1. T. M. W. J. Bandara
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  2. A. A. A. P. Aththanayake
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  3. G. R. A. Kumara
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  5. L. Ajith DeSilva
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  6. K. Tennakone
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Correspondence to T. M. W. J. Bandara.

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Bandara, T.M.W.J., Aththanayake, A.A.A.P., Kumara, G.R.A. et al. Transparent and conductive F-Doped SnO2 nanostructured thin films by sequential nebulizer spray pyrolysis. MRS Advances 6, 417–421 (2021). https://doi.org/10.1557/s43580-021-00017-0

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  • DOI: https://doi.org/10.1557/s43580-021-00017-0

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