Abstract
A direct, low-cost methodology for the fabrication of porous SiC/C foams was developed, based on the foam replica technique, using sucrose and tetraethyl orthosilicate as precursor materials. The resulting highly porous structures contained up to 96% SiC, showing a specific capacitance of 43.65 F/g, a specific energy density of 1.51 Wh/kg, and a power density of 35.16 W/kg at 0.14 A/g. Most interestingly, these foams exhibited a wide potential stability window (2 V), a unique trait for carbonaceous materials, which we believe had not been previously reported, and therefore, warrants further investigation for supercapacitor applications, such as electric double-layer capacitors.
Graphical abstract
Similar content being viewed by others
Data availability
Data will be made available on reasonable request.
References
G. Longoria, M. Lynch, J. Curtis, Green hydrogen for heating and its impact on the power system. Int. J. Hydrogen Energy 46(53), 26725–26740 (2021)
L. Dogaru, The main goals of the fourth industrial revolution. Renewable energy perspectives. Procedia Manuf. 46, 397–401 (2020)
Y. Zhang et al., High-performance supercapacitor electrodes based on NiMoO4 nanorods. J. Mater. Res. 34(14), 2435–2444 (2019)
D. Castelvecchi, Electric cars and batteries: how will the world produce enough? Nat. News Featur. 596, 336–339 (2021)
A. Dhanabalan et al., Porous SnO2/CNT composite anodes: influence of composition and deposition temperature on the electrochemical performance. J. Mater. Res. 25(8), 1554–1560 (2010)
Y. Wang et al., Recent progress in carbon-based materials for supercapacitor electrodes: a review. J. Mater. Sci. 56(1), 173–200 (2021)
J. Yin et al., Synthesis strategies of porous carbon for supercapacitor applications. Small Methods 4(3), 1900853 (2020)
W. Chen et al., Rapid single-step synthesis of porous carbon from an agricultural waste for energy storage application. Waste Manag. 102, 330–339 (2020)
E.J. Brandon, M.C. Smart, W.C. West, Low-temperature performance of electrochemical capacitors using acetonitrile/methyl formate electrolytes and activated carbon fabric electrodes. J. Mater. Res. 35(2), 113–121 (2020)
X. Gao et al., Synthesis and electrochemical properties of benzoxazine-based heteroatom-doped carbon materials. J. Mater. Res. 34(7), 1219–1228 (2019)
X. Liu et al., A porous SiC/C composite material constructed by the ordered mesoporous SiC interfacing with the ordered mesoporous carbon and its supercapacitor performance. J. Alloys Compd. 881, 160442 (2021)
M.A. Azam et al., Recent advances in biomass-derived carbon, mesoporous materials, and transition metal nitrides as new electrode materials for supercapacitor: a short review. Int. J. Energy Res. 45, 8335–8346 (2021)
J. Zhang et al., Synthesis and capacitive properties of carbonaceous sphere@MnO2 rattle-type hollow structures. J. Mater. Res. 25(8), 1476–1484 (2010)
P. Beker, G. Rosenman, Bioinspired nanostructural peptide materials for supercapacitor electrodes. J. Mater. Res. 25(8), 1661–1666 (2010)
K. Charoensook et al., Preparation of activated carbon derived from oil palm empty fruit bunches and its modification by nitrogen doping for supercapacitors. J. Porous Mater. 28, 9–18 (2021)
T.E. Rufford et al., A comparative study of chemical treatment by FeCl3, MgCl2, and ZnCl2 on microstructure, surface chemistry, and double-layercapacitance of carbons from waste biomass. J. Mater. Res. 25(8), 1451–1459 (2010)
T.K. Nguyen, S. Aberoumand, D.V. Dao, Advances in Si and SiC materials for high-performance supercapacitors toward integrated energy storage systems. Small 17(49), e2101775 (2021)
E. Tee et al., Supercapacitors based on activated silicon carbide-derived carbon materials and ionic liquid. J. Electrochem. Soc. 163, A1317–A1325 (2016)
A.J. Roberts, R.C.T. Slade, Effect of specific surface area on capacitance in asymmetric carbon/α-MnO2 supercapacitors. Electrochim. Acta 55(25), 7460–7469 (2010)
S. Karamveer, V.K. Thakur, S.S. Siwal, Synthesis and overview of carbon-based materials for high performance energy storage application: a review. Mater. Today: Proc. 56, 9–17 (2022)
F. Darus et al., Techniques for fabrication and construction of three-dimensional bioceramic scaffolds: effect on pores size, porosity and compressive strength. Ceram. Int. 44(15), 18400–18407 (2018)
Poonam et al., Review of supercapacitors: materials and devices. J. Energy Storage 21, 801–825 (2019)
A.N. Popova, Crystallographic analysis of graphite by X-Ray diffraction. Coke Chem. 60(9), 361–365 (2017)
K. Kundu et al., Boron-doped silicon carbide (SiC) thin film on silicon (Si): a novel electrode material for supercapacitor application. J. Mater. Sci.: Mater. Electron. 31(20), 17943–17952 (2020)
A.R. Aref Laleh et al., Bimodal porous carbon electrodes derived from polyfurfuryl alcohol/phloroglucinol for ionic liquid based electrical double layer capacitors. J. Mater. Res. 33, 1–10 (2017)
J. Deng et al., UZnCl2-DES assisted synthesis of phenolic resin-based carbon aerogels for capacitors. J. Porous Mater. 27(3), 789–800 (2020)
J. Zhao, A.F. Burke, Electrochemical capacitors: performance metrics and evaluation by testing and analysis. Adv. Energy Mater. 11(1), 2002192 (2021)
N. Challagulla et al., Hierarchical activated carbon fibers as a sustainable electrode and natural seawater as a sustainable electrolyte for high-performance supercapacitor. Energ. Technol. 8(9), 2000417 (2020)
J. Heikenfeld et al., Wearable sensors: modalities, challenges, and prospects. Lab Chip 18(2), 209–386 (2017)
Acknowledgments
We gratefully acknowledge financial support from Vicerrectoría de Investigación y Extensión (VIE) at Universidad Industrial de Santander.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
All authors declare that they have no conflicts of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Bayona-Becerra, M., Aceros-Cabezas, J., Güiza-Argüello, V. et al. A direct and low-cost approach to synthesizing SiC/C foams from renewable sources for energy storage applications. MRS Communications 13, 240–247 (2023). https://doi.org/10.1557/s43579-023-00335-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/s43579-023-00335-4