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The Adsorption and Chemistry of Tripropyl phosphate (TPP) into Microporous and Mesoporous NaX Zeolites

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Abstract

Adsorption and chemistry of tripropylphosphate (TPP) in mesoporous NaX zeolite, which was templated by cationic templated polymer (polydiallyldimethylammonium chloride, PDADMAC) with two different length chains, was investigated. The structural properties of the zeolites were characterized by X-ray diffraction (XRD) and nitrogen adsorption analysis. The chemical activities of different zeolites toward the decomposition of TPP were determined with solid state 31P NMR spectra. After exposure of zeolites to TPP was sufficient and equilibrium was reached, a stoichiometric amount of water was also adsorbed and hydrolysis was observed. The TPP decomposition yields in different NaX zeolites were compared.

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Authors and Affiliations

  1. Department of Chemistry, State University of New York, Binghamton University, Vestal Parkway East, 13902-6000, Binghamton, NY, USA

    Qingguo Meng, C. Doetschman David, Min-Hong Lee, T. Schulte Jürgen & W. Kanyi Charles

  2. Department of Chemistry, University of Crete, PO Box 2208, 71003, Heraklion, Greece

    K. Rizos Apostolos & Apostolos Spyros

Authors
  1. Qingguo Meng
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  2. C. Doetschman David
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  3. K. Rizos Apostolos
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  4. Min-Hong Lee
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  5. T. Schulte Jürgen
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  6. Apostolos Spyros
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  7. W. Kanyi Charles
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Correspondence to Qingguo Meng.

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Meng, Q., David, C.D., Apostolos, K.R. et al. The Adsorption and Chemistry of Tripropyl phosphate (TPP) into Microporous and Mesoporous NaX Zeolites. MRS Online Proceedings Library 1304, 415 (2011). https://doi.org/10.1557/opl.2011.431

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  • DOI: https://doi.org/10.1557/opl.2011.431

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