Skip to main content
Log in

Toward the Rational Design of Open-Framework Materials

  • Technical Feature
  • Published:
MRS Bulletin Aims and scope Submit manuscript

Abstract

In spite of the enormous level of interest in open-framework materials (materials with porous channel structures, such as zeolites), the mechanisms by which they are formed are in many cases poorly understood. As a consequence, our ability to design reaction conditions that might lead to the formation of particular crystal architectures is quite limited. This article discusses the state of the art in this area, with particular emphasis on our joint work that was recently recognized by the 2004 S miya Award from the International Union of Materials Research Societies (IUMRS) and presented at the 2004 Materials Research Society Spring Meeting/IUMRS 9th International Conference on Electronic Materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A.K. Cheetham, G. Férey, and T. Loiseau, Angew. Chem. Int. Ed. 38 (1999) p. 3268.

    Article  CAS  Google Scholar 

  2. C.N.R. Rao, S. Natarajan, and R. Vaid-hayanathan, Angew. Chem. Int. Ed. 43 (2004) p. 1466.

    Article  CAS  Google Scholar 

  3. M. Eddaoudi, D.B. Moler, H. Li, B. Chen, T.M. Reineke, M. O’Keefe, and O.M. Yaghi, Acc. Chem. Res. 34 (2001) p. 319.

    Article  CAS  Google Scholar 

  4. S.T. Wilson, B.M. Lok, C.A. Messina, T.R. Cannon, and E.M. Flanigen, J. Am. Chem. Soc. 104 (1982) p. 1146.

    Article  CAS  Google Scholar 

  5. M.E. Davis and R.F. Lobo, Chem. Mater. 4 (1992) p. 756.

    Article  CAS  Google Scholar 

  6. D.W. Lewis, G. Sankar, J.K. Wyles, J.M. Thomas, C.R.A. Catlow, and D.J. Willock, Angew. Chem. Int. Ed. 36 (1997) p. 2675.

    Article  CAS  Google Scholar 

  7. J.-S. Chang, J.-S. Hwang, S.H. Jhung, S.-E. Park, G. Férey, and A.K. Cheetham, Angew. Chem. Int. Ed. 43 (2004) p. 2819.

    Article  CAS  Google Scholar 

  8. S. Natarajan, M.P. Attfield, and A.K. Cheetham, Angew. Chem. Int. Ed. 36 (1997) p. 978.

    Article  CAS  Google Scholar 

  9. N. Guillou, Q. Gao, P.M. Forster, J.-S. Chang, M. Nogues, S.-E. Park, G. Férey, and A.K. Cheetham, Angew. Chem. Int. Ed. 40 (2001) p. 2831.

    Article  CAS  Google Scholar 

  10. S. Natarajan, M. Eswaramoorthy, A.K. Cheetham, and C.N.R. Rao, J. Chem. Soc., Chem. Commun. (1998) p. 1561.

  11. S. Ayyappan, X. Bu, A.K. Cheetham, and C.N.R. Rao, Chem. Mater. 10 (1998) p. 3308.

    Article  CAS  Google Scholar 

  12. S. Ayyappan, A.K. Cheetham, S. Natarajan, and C.N.R. Rao, J. Solid State Chem. 139 (1998) p. 207.

    Article  CAS  Google Scholar 

  13. S. Ayyappan, X. Bu, A.K. Cheetham, S. Natarajan and C.N.R. Rao, J. Chem. Soc., Chem. Commun. (1998) p. 2181.

  14. S. Natarajan and A.K. Cheetham, J. Solid State Chem. 140 (1998) p. 435.

    Article  CAS  Google Scholar 

  15. C.N.R. Rao, S. Natarajan, and S. Neeraj, J. Am. Chem. Soc. 122 (2000) p. 2810.

    Article  CAS  Google Scholar 

  16. S. Neeraj, P.M. Forster, C.N.R. Rao, and A.K. Cheetham, J. Chem. Soc., Chem. Commun. (2001) p. 2716.

  17. S. Neeraj, C.N.R. Rao, and A.K. Cheetham, J. Mater. Chem. 14 (2004) p. 814.

    Article  CAS  Google Scholar 

  18. S. Neeraj and A.K. Cheetham, J. Chem. Soc., Chem. Commun. (2002) p. 1738.

  19. S. Ayyappan, A.K. Cheetham, S. Natarajan, and C.N.R. Rao, Chem. Mater. 10 (1998) p. 3746.

    Article  CAS  Google Scholar 

  20. S. Natarajan, R. Vaidhyanathan, C.N.R. Rao, S. Ayyappan, and A.K. Cheetham, Chem. Mater. 11 (1999) p. 1633.

    Article  CAS  Google Scholar 

  21. R. Vaidhyanathan, S. Natarajan, A.K. Cheetham, and C.N.R. Rao, Chem. Mater. 1 1 (1999) p. 3636.

    Article  CAS  Google Scholar 

  22. S. Neeraj, M.L. Noy, C.N.R. Rao, and A.K. Cheetham, Solid State Sci. 4 (2002) p. 1231.

    Article  CAS  Google Scholar 

  23. M. Dan, K. Shivashankar, A.K. Cheetham, and C.N.R. Rao, J. Solid State Chem. 174 (2003) p. 60.

    Article  CAS  Google Scholar 

  24. P.M. Forster and A.K. Cheetham, Angew. Chem. Int. Ed. 41 (2002) p. 457.

    Article  CAS  Google Scholar 

  25. R. Vaidhyanathan, S. Natarajan, and C.N.R. Rao, J. Chem. Soc. Dalton Trans. (2003) p. 1459.

  26. S. Ayyappan, G. Diaz de Delgado, A.K. Cheetham, G. Férey, and C.N.R. Rao, J. Chem. Soc. Dalton Trans. (1999) p. 2905.

  27. M. Dan, J.N. Behera, and C.N.R. Rao, J. Mater. Chem. 14 (2004) p. 1257.

    Article  CAS  Google Scholar 

  28. D. Udayakumar and C.N.R. Rao, J. Mater. Chem. 13 (2003) p. 1635.

    Article  CAS  Google Scholar 

  29. J.N. Behera, A.A. Ayi, and C.N.R. Rao, Chem. Commun. (2004) p. 968.

  30. C.N.R. Rao, S. Natarajan, A. Choudhury, S. Neeraj, and A.A. Ayi, Acc. Chem. Res. 34 (2001) p. 80.

    Article  CAS  Google Scholar 

  31. A. Choudhury and C.N.R. Rao, Chem. Commun. (2003) p. 366.

  32. M. Dan, D. Udayakumar, and C.N.R. Rao, Chem. Commun. (2003) p. 2212.

  33. P.M. Forster, A.M. Burbank, C. Livage, G. Férey, and A.K. Cheetham, J. Chem. Soc., Chem. Commun. (2004) p. 368.

  34. N. Stock and T. Bein, Angew. Chem. Int. Ed. 43 (2004) p. 749.

    Article  CAS  Google Scholar 

  35. R. Vaidhyanathan, S. Natarajan, and C.N.R. Rao, J. Chem. Soc., Dalton Trans. (2001) p. 699.

  36. C. Mellot-Draznieks, J.M. Newsam, A.M. Gorman, C.M. Freeman, and G. Férey, Angew. Chem. Int. Ed. 39 (2000) p. 2270.

    Article  CAS  Google Scholar 

  37. C. Mellot-Draznieks, S. Girard, and G. Férey, J. Am. Chem. Soc. 124 (2002) p. 15326.

    Article  CAS  Google Scholar 

  38. M.G. Walawalkar, H.W. Roesky, R. Murugavel, Acc. Chem. Res. 32 (1999) p. 117.

    Article  CAS  Google Scholar 

  39. R. Vaidhyanathan, S. Natarajan, and C.N.R. Rao, Chem. Mater. 13 (2001) p. 3524.

    Article  CAS  Google Scholar 

  40. N. Masciocchi, F. Castelli, P.M. Forster, M.M. Tafoya, and A.K. Cheetham, Inorg. Chem. 42 (2003) p. 6147.

    Article  CAS  Google Scholar 

Download references

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cheetham, A.K., Rao, C.N.R. Toward the Rational Design of Open-Framework Materials. MRS Bulletin 30, 93–98 (2005). https://doi.org/10.1557/mrs2005.27

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/mrs2005.27

Keywords

Navigation