Abstract
Two-dimensional (2D) transition-metal dichalcogenides (TMDs) consist of over 40 compounds. Complex metal TMDs assume the 1T phase where the transition-metal atom coordination is octahedral. The 2H phase is stable in semiconducting TMDs where the coordination of metal atoms is trigonal prismatic. Stability issues have hampered the study of interesting phenomena in two-dimensional 1T phase TMDs. Phase conversion in TMDs involves transformation by chemistry at room temperature and pressure. It is possible to convert 2H phase 2D TMDs to the 1T phase or locally pattern the 1T phase on the 2H phase. The chemically converted 1T phase 2D TMDs exhibit interesting properties that are being exploited for catalysis, source and drain electrodes in field-effect transistors, and energy storage. We summarize the key properties of 2D 1T phase TMDs and their applications as electrodes for energy and electronics.
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M. Py, R. Haering, Can. J. Phys. 61, 76 (1983).
P. Joensen, R. Frindt, S.R. Morrison, Mater. Res. Bull. 21, 457 (1986).
J. Heising, M.G. Kanatzidis, J. Am. Chem. Soc. 121, 638 (1999).
G. Eda, T. Fujita, H. Yamaguchi, D. Voiry, M. Chen, M. Chhowalla, ACS Nano 6, 7311 (2012).
G. Eda, H. Yamaguchi, D. Voiry, T. Fujita, M. Chen, M. Chhowalla, Nano Lett. 11, 5111 (2011).
X. Qian, J. Liu, L. Fu, J. Li, Science 346, 1344 (2014).
B. Schönfeld, J. Huang, S. Moss, Acta Crystallogr. B Struct. Sci. 39, 404 (1983). Figure 4. Precise control of phase conversion of MoS 2 single-layer triangles. (a) The dark regions represent the 1T phase, while the lighter regions are the 2H phase. (b) Photoluminescence map of the patterned triangle is shown. The bright regions represent the semiconducting phase, and the darker regions represent the metallic 1T phase where the luminescence is quenched. Data reprinted with permission from Reference 24. © 2014 American Institute of Physics.
M. Calandra, Phys. Rev. B Condens. Matter 88, 245428 (2013).
M. Kan, J. Wang, X. Li, S. Zhang, Y. Li, Y. Kawazoe, Q. Sun, P. Jena, J. Phys. Chem. C 118, 1515 (2014).
H.-L. Tsai, J. Heising, J.L. Schindler, C.R. Kannewurf, M.G. Kanatzidis, Chem. Mater. 9, 879 (1997).
D. Yang, R. Frindt, J. Phys. Chem. Solids 57, 1113 (1996).
J. Heising, M.G. Kanatzidis, J. Am. Chem. Soc. 121, 11720 (1999).
P. Joensen, E. Crozier, N. Alberding, R. Frindt, J. Phys. C Solid State Phys. 20, 4043 (1987).
S.J. Sandoval, D. Yang, R. Frindt, J. Irwin, Phys. Rev. B Condens. Matter 44, 3955 (1991).
D. Voiry, H. Yamaguchi, J. Li, R. Silva, D.C. Alves, T. Fujita, M. Chen, T. Asefa, V.B. Shenoy, G. Eda, Nat. Mater. 12, 850 (2013).
A.N. Enyashin, G. Seifert, Comput. Theor. Chem. 999, 13 (2012).
Y. Cheng, A. Nie, Q. Zhang, L.-Y. Gan, R. Shahbazian-Yassar, U. Schwingenschlogl, ACS Nano 8, 11447 (2014).
A.N. Enyashin, L. Yadgarov, L. Houben, I. Popov, M. Weidenbach, R. Tenne, M. Bar-Sadan, G. Seifert, J. Phys. Chem. C 115, 24586 (2011).
Y.-C. Lin, D.O. Dumcenco, Y.-S. Huang, K. Suenaga, Nat. Nanotechnol. 9, 391 (2014).
L. Wang, Z. Xu, W. Wang, X. Bai, J. Am. Chem. Soc. 136, 6693 (2014).
Y. Kang, S. Najmaei, Z. Liu, Y. Bao, Y. Wang, X. Zhu, N.J. Halas, P. Nordlander, P.M. Ajayan, J. Lou, Adv. Mater. 26, 6467 (2014).
K.-A.N. Duerloo, Y. Li, E.J. Reed, Nat. Commun. 5, 4214 (2014).
R. Kappera, D. Voiry, S.E. Yalcin, B. Branch, G. Gupta, A.D. Mohite, M. Chhowalla, Nat. Mater. 13, 1128 (2014).
R. Kappera, D. Voiry, S.E. Yalcin, W. Jen, M. Acerce, S. Torrel, B. Branch, S. Lei, W. Chen, S. Najmaei, APL Mater. 2, 092516 (2014).
D. Voiry, M. Salehi, R. Silva, T. Fujita, M. Chen, T. Asefa, V.B. Shenoy, G. Eda, M. Chhowalla, Nano Lett. 13, 6222 (2013).
Y. Iwasa, J. Ye, Y. Zhang, Science 338, 1193 (2012).
N.F. Yuan, K.F. Mak, K. Law, Phys. Rev. Lett. 113, 097001 (2014).
M.A. Lukowski, A.S. Daniel, F. Meng, A. Forticaux, L. Li, S. Jin, J. Am. Chem. Soc. 135, 10274 (2013).
B. Mahler, V. Hoepfner, K. Liao, G.A. Ozin, J. Am. Chem. Soc. 136, 14121 (2014).
U. Maitra, U. Gupta, M. De, R. Datta, A. Govindaraj, C. Rao, Angew. Chem. Int. Ed. 52, 13057 (2013).
H. Wang, Z. Lu, S. Xu, D. Kong, J.J. Cha, G. Zheng, P.-C. Hsu, K. Yan, D. Bradshaw, F.B. Prinz, Y. Cui, Proc. Natl. Acad. Sci. U.S.A. 110, 19701 (2013).
M.S. Whittingham, F.R. Gamble, Mater. Res. Bull. 10, 363 (1975).
M.B. Dines, Mater. Res. Bull. 10, 287 (1975).
Y. Liang, R. Feng, S. Yang, H. Ma, J. Liang, J. Chen, Adv. Mater. 23, 640 (2011).
J. Xiao, D. Choi, L. Cosimbescu, P. Koech, J. Liu, J.P. Lemmon, Chem. Mater. 22, 4522 (2010).
G.S. Bang, K.W. Nam, J.Y. Kim, J. Shin, J.W. Choi, S.-Y. Choi, ACS Appl. Mater. Interfaces 6, 7084 (2014).
K. Chang, W. Chen, ACS Nano 5, 4720 (2011).
H. Hwang, H. Kim, J. Cho, Nano Lett. 11, 4826 (2011).
M.R. Lukatskaya, O. Mashtalir, C.E. Ren, Y. Dall’Agnese, P. Rozier, P.L. Taberna, M. Naguib, P. Simon, M.W. Barsoum, Y. Gogotsi, Science 341, 1502 (2013).
O. Mashtalir, M. Naguib, V.N. Mochalin, Y. Dall’Agnese, M. Heon, M.W. Barsoum, Y. Gogotsi, Nat. Commun. 4, 1716 (2013).
M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, M.W. Barsoum, Adv. Mater. 23, 4248 (2011).
M. Naguib, O. Mashtalir, J. Carle, V. Presser, J. Lu, L. Hultman, Y. Gogotsi, M.W. Barsoum, ACS Nano 6, 1322 (2012).
M. Naguib, V.N. Mochalin, M.W. Barsoum, Y. Gogotsi, Adv. Mater. 26, 992 (2014).
M. Ghidiu, M.R. Lukatskaya, M.-Q. Zhao, Y. Gogotsi, M.W. Barsoum, Nature 516, 78 (2014).
L. Cao, S. Yang, W. Gao, Z. Liu, Y. Gong, L. Ma, G. Shi, S. Lei, Y. Zhang, S. Zhang, Small 9, 2905 (2013).
J.M. Soon, K.P. Loh, Electrochem. Solid-State Lett. 10, A250 (2007).
E.G. da Silveira Firmiano, A.C. Rabelo, C.J. Dalmaschio, A.N. Pinheiro, E.C. Pereira, W.H. Schreiner, E.R. Leite, Adv. Energy Mater. 4, 1301380 (2014).
S. Ratha, C.S. Rout, ACS Appl. Mater. Interfaces 5, 11427 (2013).
Z. Wang, T. Chen, W. Chen, K. Chang, L. Ma, G. Huang, D. Chen, J.Y. Lee, J. Mater. Chem. A 1, 2202 (2013).
X. Cao, Y. Shi, W. Shi, X. Rui, Q. Yan, J. Kong, H. Zhang, Small 9, 3433 (2013).
L. David, R. Bhandavat, G. Singh, ACS Nano 8, 1759 (2014).
X. Peng, L. Peng, C. Wu, Y. Xie, Chem. Soc. Rev. 43, 3303 (2014).
B. Luo, Y. Fang, B. Wang, J. Zhou, H. Song, L. Zhi, Energy Environ. Sci. 5, 5226 (2012).
X. Wang, X. Shen, Z. Wang, R. Yu, L. Chen, ACS Nano 8, 11394 (2014).
M. Mortazavi, C. Wang, J. Deng, V.B. Shenoy, N.V. Medhekar, J. Power Sources 268, 279 (2014).
Y.-X. Wang, K.H. Seng, S.-L. Chou, J.-Z. Wang, Z. Guo, D. Wexler, H.-K. Liu, S.-X. Dou, Chem. Commun. 50, 10730 (2014).
B.L. Ellis, L.F. Nazar, Curr. Opin. Solid State Mater. Sci. 16, 168 (2012).
M. Acerce, D. Voiry, M. Chhowalla, Nat. Nanotechnol. 10, 313 (2015).
J. Feng, X. Sun, C. Wu, L. Peng, C. Lin, S. Hu, J. Yang, Y. Xie, J. Am. Chem. Soc. 133, 17832 (2011).
H. Tributsch, J. Bennett, J. Electroanal. Chem. Interfacial Electrochem. 81, 97 (1977).
H. Tributsch, Ber. Bunsenges Phys. Chem. 81, 361 (1977).
B. Hinnemann, P.G. Moses, J. Bonde, K.P. Jørgensen, J.H. Nielsen, S. Horch, I. Chorkendorff, J.K. Nørskov, J. Am. Chem. Soc. 127, 5308 (2005).
T.F. Jaramillo, K.P. Jørgensen, J. Bonde, J.H. Nielsen, S. Horch, I. Chorkendorff, Science 317, 100 (2007).
J. Bonde, P.G. Moses, T.F. Jaramillo, J.K. Nørskov, I. Chorkendorff, Faraday Discuss. 140, 219 (2009).
D. Merki, H. Vrubel, L. Rovelli, S. Fierro, X. Hu, Chem. Sci. 3, 2515 (2012).
J. Kibsgaard, Z. Chen, B.N. Reinecke, T.F. Jaramillo, Nat. Mater. 11, 963 (2012).
D. Kong, H. Wang, J.J. Cha, M. Pasta, K.J. Koski, J. Yao, Y. Cui, Nano Lett. 13, 1341 (2013).
Z. Chen, D. Cummins, B.N. Reinecke, E. Clark, M.K. Sunkara, T.F. Jaramillo, Nano Lett. 11, 4168 (2011).
Y. Li, H. Wang, L. Xie, Y. Liang, G. Hong, H. Dai, J. Am. Chem. Soc. 133, 7296 (2011).
L. Liao, J. Zhu, X. Bian, L. Zhu, M.D. Scanlon, H.H. Girault, B. Liu, Adv. Funct. Mater. 23, 5326 (2013).
E.G. Firmiano, M.A. Cordeiro, A.C. Rabelo, C.J. Dalmaschio, A.N. Pinheiro, E.C. Pereira, E.R. Leite, Chem. Commun. 48, 7687 (2012).
J. Yang, D. Voiry, S.J. Ahn, D. Kang, A.Y. Kim, M. Chhowalla, H.S. Shin, Angew. Chem. Int. Ed. 52, 13751 (2013).
D. Merki, S. Fierro, H. Vrubel, X. Hu, Chem. Sci. 2, 1262 (2011).
H. Vrubel, D. Merki, X. Hu, Energy Environ. Sci. 5, 6136 (2012).
Y.H. Chang, C.T. Lin, T.Y. Chen, C.L. Hsu, Y.H. Lee, W. Zhang, K.H. Wei, L.J. Li, Adv. Mater. 25, 756 (2013).
T.-Y. Chen, Y.-H. Chang, C.-L. Hsu, K.-H. Wei, C.-Y. Chiang, L.-J. Li, Int. J. Hydrogen Energy 38, 12302 (2013).
X. Huang, Z. Zeng, S. Bao, M. Wang, X. Qi, Z. Fan, H. Zhang, Nat. Commun. 4, 1444 (2013).
M.S. Faber, R. Dziedzic, M.A. Lukowski, N.S. Kaiser, Q. Ding, S. Jin, J. Am. Chem. Soc. 136, 10053 (2014).
M.S. Faber, M.A. Lukowski, Q. Ding, N.S. Kaiser, S. Jin, J. Phys. Chem. C 118, 21347 (2014).
S. Peng, L. Li, X. Han, W. Sun, M. Srinivasan, S.G. Mhaisalkar, F. Cheng, Q. Yan, J. Chen, S. Ramakrishna, Angew. Chem. Int. Ed. 53, 12594 (2014).
D.-Y. Wang, M. Gong, H.-L. Chou, C.-J. Pan, H.-A. Chen, Y. Wu, M.-C. Lin, M. Guan, J. Yang, C.-W. Chen, J. Am. Chem. Soc. 137, 1587 (2015).
C. Tang, Z. Pu, Q. Liu, A.M. Asiri, X. Sun, Electrochim. Acta 153, 508 (2015).
D. Kong, J.J. Cha, H. Wang, H.R. Lee, Y. Cui, Energy Environ. Sci. 6, 3553 (2013).
H.-Y. Chang, S. Yang, J. Lee, L. Tao, W.-S. Hwang, D. Jena, N. Lu, D. Akinwande, ACS Nano 7, 5446 (2013).
S. Das, H.-Y. Chen, A.V. Penumatcha, J. Appenzeller, Nano Lett. 13, 100 (2012).
B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, A. Kis, Nat. Nanotechnol. 6, 147 (2011).
H. Wang, L. Yu, Y.-H. Lee, Y. Shi, A. Hsu, M.L. Chin, L.-J. Li, M. Dubey, J. Kong, T. Palacios, Nano Lett. 12, 4674 (2012).
Y. Yoon, K. Ganapathi, S. Salahuddin, Nano Lett. 11, 3768 (2011).
S. Kim, A. Konar, W.-S. Hwang, J.H. Lee, J. Lee, J. Yang, C. Jung, H. Kim, J.-B. Yoo, J.-Y. Choi, Nat. Commun. 3, 1011 (2012).
H. Peelaers, C.G. Van de Walle, Phys. Rev. B Condens. Matter 86, 241401 (2012).
L. Yu, Y.-H. Lee, X. Ling, E.J.G. Santos, Y.C. Shin, Y. Lin, M. Dubey, E. Kaxiras, J. Kong, H. Wang, T. Palacios, Nano Lett. 14, 3055 (2014).
T. Roy, M. Tosun, J.S. Kang, A.B. Sachid, S.B. Desai, M. Hettick, C.C. Hu, A. Javey, ACS Nano 8, 6259 (2014).
Y.T. Lee, K. Choi, H.S. Lee, S.W. Min, P.J. Jeon, D.K. Hwang, H.J. Choi, S. Im, Small 10, 2356 (2014).
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Chhowalla, M., Voiry, D., Yang, J. et al. Phase-engineered transition-metal dichalcogenides for energy and electronics. MRS Bulletin 40, 585–591 (2015). https://doi.org/10.1557/mrs.2015.142
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DOI: https://doi.org/10.1557/mrs.2015.142