Abstract
There are numerous applications of nanoporous materials, including gas storage, separation, and purification. In recent years, the number of available nanoporous materials has increased substantially, with new material classes, such as metal-organic frameworks and microporous organic polymers, joining the traditional adsorbents, which include activated carbons, porous silicas, and zeolites. The determination of the gas adsorption properties of these materials is critical to both the development of new materials for targeted applications and the assessment of the suitability of a material for a particular technology. In this article, we provide an overview of nanoporous materials and their gas adsorption properties, existing and future applications for new materials, adsorption measurement methods, and the experimental challenges involved in the determination of gas adsorption both at elevated pressures and from multicomponent mixtures.
Similar content being viewed by others
References
D.M. Ruthven, Principles of Adsorption and Adsorption Processes (Wiley, New York, 1984).
R.T. Yang, Gas Separation by Adsorption Processes (Imperial College Press, London, UK, 1997).
O. Talu, Adv. Colloid Interface Sci. 76 – 77, 227 (1998).
D.M. Ruthven, Ind. Eng. Chem. Res. 39 (7), 2127 (2000).
S. Sircar, A.L. Myers, in Handbook of Zeolite Science and Technology, S.M. Auerbach, K.A. Carrado, P.K. Dutta, Eds. (Marcel Dekker, New York, 2003), p. 1354.
S. Sircar, Ind. Eng. Chem. Res. 45 (16), 5435 (2006).
S. Sircar, Ind. Eng. Chem. Res. 46 (10), 2917 (2007).
U. Ciesla, F. Schüth, Microporous Mesoporous Mater. 27 131 (1999).
K.J. Edler, in Porous Materials, D.W. Bruce, D. O’Hare, R.I. Walton, Eds. (Wiley, Chichester, UK, 2011), p. 69.
M. Kondo, T. Yoshitomi, H. Matsuzaka, S. Kitagawa, K. Seki, Angew. Chem. Int. Ed. 36 (16), 1725 (1997).
H. Li, M. Eddaoudi, T.L. Groy, O.M. Yaghi, J. Am. Chem. Soc. 120, 8571 (1998).
H. Li, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Nature 402, 276 (1999).
G. Férey, Chem. Soc. Rev. 37, 191 (2008).
L.R. MacGillivray, Ed., Metal-Organic Frameworks: Design and Application (Wiley, New Jersey, 2010).
S.S. Han, H. Furukawa, O.M. Yaghi, W.A. Goddard, J. Am. Chem. Soc. 130, 11580 (2008).
N.B. McKeown, P.M. Budd, K.J. Msayib, B.S. Ghanem, H.J. Kingston, C.E. Tattershall, S. Makhseed, K.J. Reynolds, D. Fritsch, Chem. Eur. J. 11, 2610 (2005).
N.B. McKeown, P.M. Budd, D. Book, Macromol. Rapid Comm. 28, 995(2007).
J.-X. Jiang, A.I. Cooper, Top. Curr. Chem. 293, 1 (2010).
K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquérol, T. Siemieniewska, Pure Appl. Chem. 57 (4), 603 (1985).
H.K. Chagger, F.E. Ndaji, M.L. Sykes, K.M. Thomas, Carbon 33, 1405 (1995).
R.F. Lobo, in Handbook of Zeolite Science and Technology, S.M. Auerbach, K.A. Carrado, P.K. Dutta, Eds. (Marcel Dekker, New York, 2003), p. 80.
K. Egeblad, C.H. Christensen, M. Kustova, C.H. Christensen, Chem. Mater. 20, 946 (2008).
S. Lopez-Orozco, A. Inayat, A. Schwab, T. Selvam, W. Schwieger, Adv. Mater. 23 (22–23), 2602 (2011).
A.C. Pierre, G.M. Pajonk, Chem. Rev. 102, 4243 (2002).
M.P. Suh, H.J. Park, T.K. Prasad, D.-W. Lim, Chem. Rev. 112, 782 (2012).
Q.-R. Fang, T.A. Makal, M.D. Young, H.-C. Zhou, Comments Inorg. Chem. 31, 165 (2010).
L. Song, J. Zhang, L. Sun, F. Xu, F. Li, H. Zhang, X. Si, C. Jiao, Z. Li, S. Liu, Y. Liu, H. Zhou, D. Sun, Y. Du, Z. Cao, Z. Gabelica, Energy Environ. Sci. 5, 7508 (2012).
X. Feng, X. Ding, D. Jiang, Chem. Soc. Rev. 41, 6010 (2012).
W. Zhang, C. Li, Y.P. Yuan, L.G. Qiu, A.J. Xie, Y.H. Shen, J.F. Zhu, J. Mater. Chem. 20, 6413 (2010).
S.-Y. Ding, W. Wang, Chem. Soc. Rev. 42, 548 (2013).
R.G. Loucks, R.M. Reed, S.C. Ruppel, D.M. Jarvie, J. Sediment. Res. 79 (12), 848 (2009).
C.M. White, D.H. Smith, K.L. Jones, A.L. Goodman, S.A. Jikich, R.B. LaCount, S.B. DuBose, E. Ozdemir, B.I. Morsi, K.T. Schroeder, Energy Fuels 19 (3), 659 (2005).
Y.B. Melnichenko, L. He, R. Sakurovs, A.L. Kholodenko, T. Blach, M. Mastalerz, A.P. Radli n´ ski, G. Cheng, D.F.R. Mildner, Fuel 91 (1), 200 (2012).
A. Busch, Y. Gensterblum, Int. J. Coal Geol. 87, 49 (2011).
M.W. Ackley, S.U. Rege, H. Saxena, Microporous Mesoporous Mater. 61, 25 (2003).
A.J. Fletcher, K.M. Thomas, M.J. Rosseinsky, J. Solid State Chem. 178 (8), 2491 (2005).
J. Jagiełło, P. Sanghani, T.J. Bandosz, J.A. Schwarz, Carbon 30 (3), 507 (1992).
X.B. Zhao, B. Xiao, A.J. Fletcher, K.M. Thomas, J. Phys. Chem. B 109, 8880 (2005).
K.K. Tanabe, S.M. Cohen, Chem. Soc. Rev. 40, 498 (2011).
L.D. Gelb, K.E. Gubbins, R. Radhakrishnan, M. Sliwinska-Bartkowiak, Rep. Prog. Phys. 62, 1573 (1999).
P.A. Monson, Microporous Mesoporous Mater. 160, 47 (2012).
D.H. Everett, J.C. Powl, J. Chem. Soc. Faraday Trans. 1 72, 619 (1976).
K. Kaneko, K. Murata, Adsorption 3, 197 (1997).
D.M. Ruthven, Chem. Ing. Tech. 83 (1–2), 44 (2011).
K.M. Thomas, Dalton Trans. 1487 (2009).
D.P. Broom, Hydrogen Storage Materials: The Characterisation of Their Storage Properties (Springer, London, UK, 2011).
K. Konstas, T. Osl, Y. Yang, M. Batten, N. Burke, A.J. Hill, M.R. Hill, J. Mater. Chem. 22, 16698 (2012).
T.A. Makal, J.-R. Li, W. Lu, H.-C. Zhou, Chem. Soc. Rev. 41, 7761 (2012).
J.-R. Li, J. Sculley, H.-C. Zhou, Chem. Rev. 112, 869 (2012).
J.-R. Li, R.J. Kuppler, H.-C. Zhou, Chem. Soc. Rev. 38, 1477 (2009).
X. Zhao, B. Xiao, A.J. Fletcher, K.M. Thomas, D. Bradshaw, M.J. Rosseinsky, Science 306, 1012 (2004).
S. Tedds, A. Walton, D.P. Broom, D. Book, Faraday Discuss. 151, 75 (2011).
P. Voser, Energy Strategy Rev. 1, 3 (2012).
D. Lozano-Castelló, J. Alcañiz-Monge, M.A. de la Casa-Lillo, D. Cazorla-Amorós, A. Linares-Solano, Fuel 81, 1777 (2002).
V.C. Menon, S. Komarneni, J. Porous Mater. 5 (1), 43 (1998).
T. Düren, L. Sarkisov, O.M. Yaghi, R.Q. Snurr, Langmuir 20, 2683 (2004).
W. Zhou, Chem. Rec. 10, 200 (2010).
Y. He, W. Zhou, R. Krishna, B. Chen, Chem. Commun. 48, 11813 (2012).
D. Yuan, W. Lu, D. Zhao, H.-C. Zhou, Adv. Mater. 23, 3723 (2011).
O.K. Farha, A.O. Yazaydin, I. Eryazici, C.D. Malliakas, B.G. Hauser, M.G. Kanatzidis, S.T. Nguyen, R.Q. Snurr, J.T. Hupp, Nat. Chem. 2, 944 (2010).
H. Furukawa, N. Ko, Y.B. Go, N. Aratani, S.B. Choi, E. Choi, A.O. Yazaydin, R.Q. Snurr, M. O’Keeffe, J. Kim, O.M. Yaghi, Science 329, 424 (2010).
Z. Guo, H. Wu, G. Srinivas, Y. Zhou, S. Xiang, Z. Chen, Y. Yang, W. Zhou, M. O’Keeffe, B. Chen, Angew. Chem. Int. Ed. 50, 3178 (2011).
C.E. Wilmer, M. Leaf, C.Y. Lee, O.K. Farha, B.G. Hauser, J.T. Hupp, R.Q. Snurr, Nat. Chem. 4, 83 (2012).
H. Wu, W. Zhou, T. Yildirim, J. Am. Chem. Soc. 131, 4995 (2009).
S. Ma, D. Sun, J.M. Simmons, C.D. Collier, D. Yuan, H.-C. Zhou, J. Am. Chem. Soc. 130, 1012 (2008).
R. Sakurovs, S. Day, S. Weir, G. Duffy, Energy Fuels 21, 992 (2007).
R. Sakurovs, S. Day, S. Weir, G. Duffy, Int. J. Coal Geol. 73, 250 (2008).
R. Sakurovs, S. Day, S. Weir, Energy Fuels 24, 1781 (2010).
Modern Shale Gas Development in the United States: A Primer (U.S. Department of Energy, Washington, DC, 2009).
D.M. Kargbo, R.G. Wilhelm, D.J. Campbell, Environ. Sci. Technol. 44, 5679 (2010).
M. Kuhn, F. Umbach, Strategic Perspectives of Unconventional Gas: A Game Changer with Implications for the EU’s Energy Security (EUCERS, King’s College London, UK, 2011).
H.-W. Häring, Ed., Industrial Gases Processing (Wiley, Weinheim, Germany, 2008).
I.P. O’koye, M. Benham, K.M. Thomas, Langmuir 13, 4054 (1997).
C.R. Reid, I.P. O’koye, K.M. Thomas, Langmuir 14, 2415 (1998).
C.R. Reid, K.M. Thomas, Langmuir 15, 3206 (1999).
J.D. Figueroa, T. Fout, S. Plasynski, H. McIlvried, R.D. Srivastava, Int. J. Greenhouse Gas Control 2, 9 (2008).
S.I. Plasynski, J.T. Litynski, H.G. McIlvried, R.D. Srivastava, Crit. Rev. Plant Sci. 28, 123 (2009).
J. Ciferno, J. Litynski, S. Plasynski, J. Murphy, G. Vaux, R. Munson, J. Marano, DOE/NETL Carbon Dioxide Capture and Storage RD&D Roadmap (National Energy Technology Laboratory, Pittsburgh, 2010).
L. Espinal, B.D. Morreale, MRS Bull. 37, 431 (2012).
S. Choi, J.H. Drese, C.W. Jones, ChemSusChem 2, 796 (2009).
S. Keskin, T.M. van Heest, D.S. Sholl, ChemSusChem 3, 879 (2010).
D.M. D’Alessandro, B. Smit, J.R. Long, Angew. Chem. Int. Ed. 49, 6058 (2010).
J.-R. Li, Y. Ma, M.C. McCarthy, J. Sculley, J. Yu, H.-K. Jeong, P.B. Balbuena, H.-C. Zhou, Coord. Chem. Rev. 255 (15–16), 1791 (2011).
J. Liu, P.K. Thallapally, B.P. McGrail, D.R. Brown, J. Liu, Chem. Soc. Rev. 41, 2308 (2012).
M. Kanniche, R. Gros-Bonnivard, P. Jaud, J. Valle-Marcos, J.-M. Amann, C. Bouallou, Appl. Therm. Eng. 30 (1), 53 (2010).
T.C. Drage, C.E. Snape, L.A. Stevens, J. Wood, J. Wang, A.I. Cooper, R. Dawson, X. Guo, C. Satterley, R. Irons, J. Mater. Chem. 22, 2815 (2012).
A.C. Kizzie, A.G. Wong-Foy, A.J. Matzger, Langmuir 27, 6368 (2011).
E.J. Granite, H.W. Pennline, Ind. Eng. Chem. Res. 41, 5470 (2002).
B. Chen, X. Zhao, A. Putkham, K. Hong, E.B. Lobkovsky, E.J. Hurtado, A.J. Fletcher, K.M. Thomas, J. Am. Chem. Soc. 130 (20), 6411 (2008).
J.W. McBain, A.M. Bakr, J. Am. Chem. Soc. 48 (3), 690 (1926).
S. Brunauer, The Adsorption of Gases and Vapors. Volume I: Physical Adsorption (Princeton University Press, Princeton, 1943).
F. Rouquerol, J. Rouquerol, K. Sing, Adsorption by Powders and Porous Solids (Academic Press, London, UK, 1999).
J.U. Keller, R. Staudt, Gas Adsorption Equilibria: Experimental Methods and Adsorption Isotherms (Springer, New York, 2005).
S. Kiefer, E. Robens, J. Therm. Anal. Cal. 94, 613 (2008).
S. Lowell, J.E. Shields, M.A. Thomas, M. Thommes, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density (Springer, Dordrecht, Germany, 2004).
J. Kärger, D.M. Ruthven, D.N. Theodorou, Diffusion in Nanoporous Materials (Wiley, Weinheim, Germany, 2012).
C.R. Reid, K.M. Thomas, J. Phys. Chem. B 105, 10619 (2001).
J. Klafter, M.F. Shlesinger, Proc. Natl. Acad. Sci. U.S.A. 83, 848 (1986).
X. Zhao, S. Villar-Rodil, A.J. Fletcher, K.M. Thomas, J. Phys. Chem. B 110 (20), 9947 (2006).
A.J. Fletcher, Y. Uygur, K.M. Thomas, J. Phys. Chem. C 111, 8349 (2007).
A.J. Fletcher, E.J. Cussen, D. Bradshaw, M.J. Rosseinsky, K.M. Thomas, J. Am. Chem. Soc. 126 (31), 9750 (2004).
J. Crank, The Mathematics of Diffusion, 2 nd ed. (Oxford University Press, Oxford, UK, 1975).
J.M. Zielinski, C.G. Coe, R.J. Nickel, A.M. Romeo, A.C. Cooper, G.P. Pez, Adsorption 13, 1 (2007).
A. Qajar, M. Peer, R. Rajagopalan, H.C. Foley, Int. J. Hydrogen Energy 37, 9123 (2012).
F.M. Nelsen, F.T. Eggertsen, Anal. Chem. 30 (8), 1387 (1958).
A.J. Fletcher, M.J. Benham, K.M. Thomas, J. Phys. Chem. B 106, 7474 (2002).
O. Talu, Chem. Ing. Tech. 83 (1–2), 67 (2011).
R.M. Rynders, M.B. Rao, S. Sircar, AIChE J. 43 (10), 2456 (1997).
G.O. Wood, Carbon 40, 685 (2002).
P. Lodewyckx, G.O. Wood, S.K. Ryu, Carbon 42, 1351 (2004).
M.D. LeVan, in Adsorption: Science and Technology, A.E. Rodrigues, M.D. LeVan, D. Tondeur, Eds. (Kluwer, Dordrecht, The Netherlands, 1989), p. 149.
A. Badalyan, P. Pendleton, H. Wu, Rev. Sci. Instrum. 72 (7), 3038 (2001).
P. Pendleton, A. Badalyan, Adsorption 11, 61 (2005).
E.L. Fuller, J.A. Poulis, A.W. Czanderna, E. Robens, Thermochim. Acta 29, 315 (1979).
S. Sircar, Ind. Eng. Chem. Res. 38, 3670 (1999).
S. Sircar, AIChE J. 47 (5), 1169 (2001).
W. Zhou, H. Wu, M.R. Hartman, T. Yildirim, J. Phys. Chem. C 111 (44), 16131 (2007).
P van Hemert, H. Bruining, E.S.J. Rudolph, K.A.A. Wolf, J.G. Maas, Rev. Sci. Instrum. 80, 035103 (2009).
Y. Gensterblum, P. van Hemert, P. Billemont, A. Busch, D. Charriére, D. Li, B.M. Krooss, G. de Weireld, D. Prinz, K.-H.A.A. Wolf, Carbon 47 (13), 2958 (2009).
H. Furukawa, M.A. Miller, O.M. Yaghi, J. Mater. Chem. 17, 3197 (2007).
L.J. Murray, M. Dinc a˘, J.R. Long, Chem. Soc. Rev. 38, 1294 (2009).
P.J. Hall, S. Brown, J. Fernandez, J.M. Calo, Carbon 38, 1257 (2000).
S. Scaife, P. Kluson, N. Quirke, J. Phys. Chem. B 104, 313 (2000).
D. Lozano-Castelló, D. Cazorla-Amorós, A. Linares-Solano, Chem. Eng. Technol. 26 (8), 852 (2003).
K. Murata, M. El-Merraoui, K. Kaneko, J. Chem. Phys. 114 (9), 4196 (2001).
O. Talu, A.L. Myers, AIChE J. 47 (5), 1160 (2001).
T. Düren, Y.-S. Bae, R.Q. Snurr, Chem. Soc. Rev. 38, 1237 (2009).
S. Keskin, J. Liu, R.B. Rankin, J.K. Johnson, D.S. Sholl, Ind. Eng. Chem. Res. 48, 2355 (2009).
Z. Xiang, D. Cao, J. Lan, W. Wang, D.P. Broom, Energy Environ. Sci. 3, 1469 (2010).
J.G. Bell, K. Angus, C. Todd, K.M. Thomas, Ind. Eng. Chem. Res. 52 (3), 1335 (2013).
K.C. Stylianou, J. Rabone, S.Y. Chong, R. Heck, J. Armstrong, P.V. Wiper, K.E. Jelfs, S. Zlatogorsky, J. Bacsa, A.G. McLennan, C.P. Ireland, Y.Z. Khimyak, K.M. Thomas, D. Bradshaw, M.J. Rosseinsky, J. Am. Chem. Soc. 134, 20466 (2012).
K.A. Cychosz, R. Ahmad, A.J. Matzger, Chem. Sci. 1, 293 (2010).
E.Q. Procopio, F. Linares, C. Montoro, V. Colombo, A. Maspero, E. Barea, J.A.R. Navarro, Angew. Chem. Int. Ed. 49, 7308 (2010).
J. Cai, Y. Xing, X. Zhao, RSC Adv. 2, 8579 (2012).
S.-C. Xiang, Z. Zhang, C.-G. Zhao, K. Hong, X. Zhao, D.-R. Ding, M.-H. Xie, C.-D. Wu, M.C. Das, R. Gill, K.M. Thomas, B. Chen, Nat. Commun. 2, 204 (2011).
E.D. Bloch, W.L. Queen, R. Krishna, J.M. Zadrozny, C.M. Brown, J.R. Long, Science 335, 1606 (2012).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Broom, D.P., Thomas, K.M. Gas adsorption by nanoporous materials: Future applications and experimental challenges. MRS Bulletin 38, 412–421 (2013). https://doi.org/10.1557/mrs.2013.105
Published:
Issue Date:
DOI: https://doi.org/10.1557/mrs.2013.105