Skip to main content

Physical Chemistry and Engineering for Adsorptive Gas Storage in Nanoporous Solids

  • Chapter
  • First Online:
Nanoporous Materials for Gas Storage

Part of the book series: Green Energy and Technology ((GREEN))

Abstract

Adsorption gas storage is examined from physical chemistry point of view. Net, excess, and absolute adsorption are defined, and their relation to gas storage capacity is examined. Experimental techniques for measuring adsorption isotherms are detailed. Net adsorption particularly stands out among possible thermodynamic choices since it directly shows the advantage of having the adsorbent in a storage cylinder. In addition to storage capacity, engineering implications of Henry’s law constant, heat of adsorption, and multicomponent adsorption are examined with examples to inform material scientists who develop materials.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 139.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 179.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Gibbs JW (1928) The collected works of J. W. Gibbs. Longmans and Green, New York

    Google Scholar 

  2. Gumma S, Talu O (2003) Gibbs dividing surface and helium adsorption. Adsorption J 9:17–28

    Article  Google Scholar 

  3. Talu O, Myers AL (2001) Molecular simulation of adsorption: Gibbs dividing surface and comparison to experiment. AIChE J 47:1160–1168

    Article  Google Scholar 

  4. Gumma S, Talu O (2010) Net adsorption: a thermodynamic framework for supercritical gas adsorption and storage in porous solids. Langmuir 26(22):17013–17023

    Article  Google Scholar 

  5. Talu O (2013) Net adsorption of gas/vapor mixtures in microporous solids. J Phys Chem C 117:13059–13071

    Article  Google Scholar 

  6. Coolidge AS (1934) Adsorption at high pressures. J Am Chem Soc 56:554–561

    Article  Google Scholar 

  7. McBain JW, Britton GT (1930) The nature of sorption by charcoal of gases and vapors under great pressure. J Am Chem Soc 52:2198–2222

    Article  Google Scholar 

  8. Zlotea C, Moretto P, Steriotis T (2009) A round Robin characterization of the hydrogen sorption properties of a carbon based material. Int J Hydrog Energy 34:3044–3057

    Article  Google Scholar 

  9. Herbst A, Harting P (2002) Thermodynamic description of excess isotherms in high-pressure adsorption of methane, argon and nitrogen. Adsorption J 8:111–123

    Article  Google Scholar 

  10. Ustinov EA, Do DD, Herbst A, Staudt R, Harting P (2002) Modelling of gas adsorption equilibrium over wide range of pressure: A thermodynamic approach based on equation of state. J Colloid Interface Sci 250:49–62

    Article  Google Scholar 

  11. Li Y, Yang RT (2007) Gas adsorption and storage in metal-organic framework MOF-177. Langmuir 23:12937–12944

    Article  MathSciNet  Google Scholar 

  12. Talu O (1993) Gas storage process. US Patent 5,247,971

    Google Scholar 

  13. Chang KJ, Talu O (1996) Behavior and performance of adsorptive natural gas storage cylinders during discharge. App Thermal Eng 16:356–374

    Article  Google Scholar 

  14. Talu O (2011) Measurement and analysis of mixture adsorption equilibrium in porous solids. Chem Ing Tech 83:67–82

    Article  Google Scholar 

  15. Rouquerol J et al (1994) Recommendations for the characterization of porous solids. Pure Appl Chem 66(8):1739–1758

    Article  Google Scholar 

  16. Talu O, Kabel RL (1987) Isosteric heat of adsorption and the vacancy solution model. AIChE J 33:510–514

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Orhan Talu .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Singapore Pte Ltd.

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Talu, O. (2019). Physical Chemistry and Engineering for Adsorptive Gas Storage in Nanoporous Solids. In: Kaneko, K., Rodríguez-Reinoso, F. (eds) Nanoporous Materials for Gas Storage. Green Energy and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-13-3504-4_4

Download citation

  • DOI: https://doi.org/10.1007/978-981-13-3504-4_4

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-13-3503-7

  • Online ISBN: 978-981-13-3504-4

  • eBook Packages: EnergyEnergy (R0)

Publish with us

Policies and ethics