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Starch-based foam composite materials: Processing and bioproducts

  • Next-Generation Biopolymers: Advanced Functionality and Improved Sustainability
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Abstract

Starch is an abundant, biodegradable, renewable, and low-cost commodity that has been explored as a replacement for petroleum-based plastics. By itself, starch is a poor replacement for plastics because of its moisture sensitivity and brittle properties. Using starch as a fermentation feedstock, various promising biodegradable plastic products have been developed that rival petroleum-based plastics and are poised to enter the marketplace or are already in production. Other starch-based plastics are blends with other compatible resins or are based on chemical treatments that improve the functional properties of various products. While these approaches are very promising, there are efforts under way to develop viable products from starch by using different processing technologies and by combining starch with other materials to make functional composites. This article focuses on different technologies for making starch-based foam materials and the use of reinforcing fibers and nanoparticles for making composites that can substitute for some petroleum-based foam products.

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References

  1. D. Le Corre, J. Bras, A. Dufresne, Biomacromolecules 11, 1139 (2010).

    Article  CAS  Google Scholar 

  2. R.P. Ellis, M.P. Cochrane, M.F.B. Dale, C.M. Duffus, A. Lynn, I.M. Morrison, R.D.M. Prentice, J.S. Swanston, S.A. Tiller, J. Sci. Food Agric. 77, 289 (1998).

    Article  CAS  Google Scholar 

  3. R.L. Whistler, in Starch: Chemistry and Technology, R.L. Whistler, J.N. Bemiller, E.F. Paschall, Eds. (Academic Press, New York, 1984), pp. 1–9.

  4. D. French, in Starch: Chemistry and Technology, R.L. Whistler, J.N. Bemiller, E.F. Paschall, Eds. (Academic Press, Orlando, 1984), pp. 183–247.

  5. T.-Y. Huang, K.-J. Duan, S.-Y. Huang, C. Chen, J. Ind. Microbiol. Biotechnol. 33, 701 (2006).

    Article  CAS  Google Scholar 

  6. G. Reddy, M. Altaf, B.J. Naveena, M. Venkateshwar, E.V. Kumar, Biotechnol. Adv. 26, 22 (2008).

    Article  CAS  Google Scholar 

  7. Agricultural Yearbook (U.S. Department of Agriculture, Economic Research Service, 2010).

  8. R.L. Shogren, G.F. Fanta, W.M. Doane, Starch – Stärke 45, 276 (1993).

    Article  CAS  Google Scholar 

  9. C.L. Swanson, R.L. Shogren, G.F. Fanta, S.H. Imam, J. Polym. Environ. 1, 155 (1993).

    Article  CAS  Google Scholar 

  10. A. Guzman, N. Gnutek, H. Janik, Chem. Chem. Technol. 5, 115 (2011).

    Article  Google Scholar 

  11. R.C. Thompson, Y. Olsen, R.P. Mitchell, A. Davis, S.J. Rowland, A.W.G. John, D. McGonigle, A.E. Russell, Science 304, 838 (2004).

    Article  CAS  Google Scholar 

  12. K.L. Law, S. Morét-Ferguson, N.A. Maximenko, G. Proskurowski, E.E. Peacock, J. Hafner, C.M. Reddy, Science 329, 1185 (2010).

    Article  CAS  Google Scholar 

  13. Municipal Solid Waste in the United States. Publication 5306P (Office of Solid Waste, U.S. Environmental Protection Agency, 2010).

  14. J.S. Horvath, Geotext. Geomembr. 13, 263 (1994).

    Article  Google Scholar 

  15. M. Mariotti, C. Alamprese, M.A. Pagani, M. Lucisano, J. Cereal Sci. 43, 47 (2006).

    Article  Google Scholar 

  16. G.M. Glenn, A.K. Klamczynski, K.M. Holtman, J. Shey, B.-S. Chiou, J. Berrios, D. Wood, W.J. Orts, S.H. Imam, J. Agric. Food. Chem. 55, 3936 (2007).

    Article  CAS  Google Scholar 

  17. W. Wiedmann, E. Strobel, Starch – Stärke 43, 138 (1991).

    Article  CAS  Google Scholar 

  18. L.S. Lai, J.L. Kokini, Biotechnol. Progr. 7, 251 (1991).

    Article  CAS  Google Scholar 

  19. N.L. Lacourse, P.A. Altieri, U.S. Patent #4863655 (1989).

  20. Y. Nabar, N. Ramani, M. Schindler, Polym. Eng. Sci. 46, 438 (2006).

    Article  CAS  Google Scholar 

  21. G.M. Glenn, A. Klamczynski, K.M. Holtman, B.-S. Chiou, W.J. Orts, D. Wood, J. Biobased Mater. Bioenergy 1, 360 (2007).

    Article  Google Scholar 

  22. K.F. Tiefenbacher, J. Macromol. Sci. Part A Pure Appl. Chem. 30, 727 (1993).

    Article  Google Scholar 

  23. P.J. Andersen, S.K. Hodson, U.S. Patent #6030673 (2000).

  24. P.J. Andersen, S.K. Hodson, U.S. Patent #5,545,450 (1996).

  25. P.J. Andersen, S.K. Hodson, U.S. Patent #5,683,772 (1997).

  26. P.J. Andersen, S.K. Hodson, U.S. Patent #5,618,341 (1997).

  27. G.M. Glenn, W.J. Orts, G.A.R. Nobes, Ind. Crops Prod. 14, 201 (2001).

    Article  CAS  Google Scholar 

  28. S. Mishra, T. Rai, Food Hydrocolloids 20, 557 (2006).

    Article  CAS  Google Scholar 

  29. S.-H. Yoo, J.-L. Jane, Carbohydr. Polym. 49, 297 (2002).

    Article  CAS  Google Scholar 

  30. L. Chen, S. Imam, S. Gordon, R. Greene, J. Polym. Environ. 5, 111 (1997).

    Article  CAS  Google Scholar 

  31. R.L. Shogren, J.W. Lawton, K.F. Tiefenbacher, L. Chen, J. Appl. Polym. Sci. 68, 2129 (1998).

    Article  CAS  Google Scholar 

  32. J. Shey, S.H. Imam, G.M. Glenn, W.J. Orts, Ind. Crops Prod. 24, 34 (2006).

    Article  CAS  Google Scholar 

  33. G.M. Glenn, W.J. Orts, G.A.R. Nobes, G.M. Gray, Ind. Crops Prod. 14, 125 (2001).

    Article  CAS  Google Scholar 

  34. J.M. Green, P.D. Millner, R.E. Green, R. Townsend. In Food And Biobased Cafeteriaware Composting For Federal Facilities in WDC. Eds. R. Reynnells, P.D. Millner, C. Bailey. (2005); http://www.csrees.usda.gov/nea/plants/pdfs/cafeteriaware.pdf.

  35. R.C. Hoseney, K. Zeleznak, A. Abdelrahman, J. Cereal Sci. 1, 43 (1983).

    Article  Google Scholar 

  36. H.E. Huff, F. Hsieh, I.C. Peng, J. Food Sci. 57, 1164 (1992).

    Article  Google Scholar 

  37. A.P. Klamczynski, B.E. Knuckles, G.M. Glenn, J. Food Process. Preserv. 28, 433 (2004).

    Article  CAS  Google Scholar 

  38. G.M. Glenn, W.J. Orts, Ind. Crops Prod. 13, 135 (2001).

    Article  CAS  Google Scholar 

  39. N.J. Atkin, R.M. Abeysekera, S.L. Cheng, A.W. Robards, Carbohydr. Polym. 36, 173 (1998).

    Article  CAS  Google Scholar 

  40. G. Richardson, S. Kidman, M. Langton, A.-M. Hermansson, Carbohydr. Polym. 58, 7 (2004).

    Article  CAS  Google Scholar 

  41. G.M. Glenn, D.W. Irving, Cereal Chem. 72, 155 (1995).

    CAS  Google Scholar 

  42. G.M. Glenn, A.P. Klamczynski, D.F. Woods, B.S. Chiou, W.J. Orts, S.H. Imam, J. Agric. Food. Chem. 58, 4180 (2010).

    Article  CAS  Google Scholar 

  43. K. El-Tahlawy, R.A. Venditti, J.J. Pawlak, Carbohydr. Polym. 67, 319 (2007).

    Article  CAS  Google Scholar 

  44. A.I. Bolivar, R.A. Venditti, J.J. Pawlak, K. El-Tahlawy, Carbohydr. Polym. 69, 262 (2007).

    Article  CAS  Google Scholar 

  45. G.M. Glenn, A.P. Klamczynski, C. Ludvik, J. Shey, S.H. Imam, B.-S. Chiou, T. McHugh, G. DeGrandi-Hoffman, W. Orts, D. Wood, R. Offeman, J. Agric. Food. Chem. 54, 3297 (2006).

    Article  CAS  Google Scholar 

  46. R.G. Buttery, G.M. Glenn, D.J. Stern, J. Agric. Food. Chem. 47, 5206 (1999).

    Article  CAS  Google Scholar 

  47. G.M. Glenn, D.J. Stern. (The United States of America as represented by the Secretary of Agriculture, 1999), Vol. 5958589, pp. 1–9.

  48. G.M. Glenn, A.P. Klamczynski, D.F. Woods, B. Chiou, W.J. Orts, S.H. Imam, J. Agric. Food. Chem. 58, 4180 (2010).

    Article  CAS  Google Scholar 

  49. G.J.L. Griffin, in Fillers and Reinforcements for Plastics (American Chemical Society, 1974), Vol. 134, pp. 159–170.

  50. S. Lim, J.L.Jane, S. Rajagopalan, P.A. Seib, Biotechnol. Progr. 8, 51 (1992)

  51. A. Dufresne, J.-Y. Cavaille, W. Helbert, Macromolecules 29, 7624 (1996).

    Article  CAS  Google Scholar 

  52. H.L.N. Angellier, S. Molina-Boisseau, L. Lebrun, A. Dufresne, Macromolecules 38, 3783 (2005).

    Article  CAS  Google Scholar 

  53. H.M. Park, W.K. Lee, C.Y. Park, W.J. Cho, C.S. Ha, J. Mater. Sci. 38, 909 (2003).

    Article  CAS  Google Scholar 

  54. B.-S. Chiou, E. Yee, G.M. Glenn, W.J. Orts, Carbohydr. Polym. 59, 467 (2005).

    Article  CAS  Google Scholar 

  55. W.J. Orts, J. Shey, S.H. Imam, G.M. Glenn, M.E. Guttman, J.-F. Revol, J. Polym. Environ. 13, 301 (2005).

    Article  CAS  Google Scholar 

  56. A. Dufresne, D. Dupeyre, M.R. Vignon, J. Appl. Polym. Sci. 76, 2080 (2000)

  57. A. Dufresne, M.R. Vignon, Macromolecules 31, 2693 (1998).

    Article  CAS  Google Scholar 

  58. G.M. Glenn, A. Klamczynski, B.-S. Chiou, W.J. Orts, S.H. Imam, D.F. Wood, Starch – Stärke 60, 476 (2008).

    Article  CAS  Google Scholar 

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Correspondence to Gregory M. Glenn.

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Glenn, G.M., Imam, S.H. & Orts, W.J. Starch-based foam composite materials: Processing and bioproducts. MRS Bulletin 36, 696–702 (2011). https://doi.org/10.1557/mrs.2011.205

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  • DOI: https://doi.org/10.1557/mrs.2011.205

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