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Synthesis and characterization of multilayer graphene oxide on yttria-zirconia ceramics for dental implant

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Abstract

In order to expand the family and improve the bioactivity of oral implant ceramics, the phase structures, mechanical and wetting properties of the hot-pressed yttria-zirconia/multilayer graphene oxide composite (3Y-ZrO2/GO) ceramics were investigated. GO was uniformly distributed in 3Y-ZrO2 powders, forming the C–O–Zr bond during the sintering process. In comparison to raw 3Y-ZrO2 ceramics, the flexural strength and fracture toughness improved up to 200% (1489.96 ± 35.71 MPa) in ZG3 (with 0.15 wt% GO) and 40.9% (8.95 ± 0.59 MPa m1/2) in ZG2 (with 0.1 wt% GO), respectively, while the relative density and Vickers hardness increased slightly. The toughening mechanisms included crack deflection, crack bridging, and GO put-out. Meanwhile, the composite ceramics were transformed into a more hydrophilic direction and indicated a good wetting property. In consideration of mechanical and wetting properties, the ZG3 would be a favorable alternative to the yttria-zirconia ceramic (Y-TZP) in dental implant applications. The results are expected to serve as a technical guidance for the fabrication and evaluation of dental implants.

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Acknowledgment

This project was supported by the National Natural Science Foundation of China (Grant No. 51175304) and the Shandong Provincial Natural Science Foundation, China (Grant Nos ZR2017MEE052 and ZR2018ZB0105). The authors thank all the former researches contributed to this study.

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Authors and Affiliations

  1. Key Laboratory of High Efficiency and Clean Mechanical Manufacture (Ministry of Education), School of Mechanical Engineering, Shandong University, Jinan, 250061, P.R. China

    Cheng Zhang, Zhaoliang Jiang, Li Zhao & Wenping Liu

  2. SDU & Rice Joint Center for Carbon Nanomaterials, Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan, 250061, P. R. China

    Pengchao Si

  3. Department of Prosthodontics, School and Hospital of Stomatology, Cheeloo College of Medicine, Shandong University, Jinan, 250012, P.R. China

    Jing Lan

  4. Shandong Key Laboratory of Oral Tissue Regeneration and Shandong Engineering, Laboratory for Dental Materials and Oral Tissue Regeneration, Jinan, 250012, P.R. China

    Jing Lan

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  1. Cheng Zhang
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Correspondence to Zhaoliang Jiang.

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Zhang, C., Jiang, Z., Zhao, L. et al. Synthesis and characterization of multilayer graphene oxide on yttria-zirconia ceramics for dental implant. Journal of Materials Research 35, 2466–2477 (2020). https://doi.org/10.1557/jmr.2020.199

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