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Characterization of nanocrystalline Ti films deposited by DC magnetron sputtering onto FTO glass substrate

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Abstract

Titanium (Ti) thin films were deposited by DC magnetron sputtering at conventional conditions with different substrate temperature, deposition rate, and inert gas pressure. The compositional, structural, morphological, and optical properties of the Ti films were investigated. It is shown that the films were crystalline with α-Ti phase and hcp structure only. The crystallinity increased with increase in substrate and deposition rate. Analysis of the atomic force microscopy images shows that the films were uniform, crack free, and adhered well to the substrate. It is found that, a strong relation existed between the structural and optical properties of the films. The optical properties of the Ti films were most influenced under the deposition conditions. From this dependence, the optimum deposition conditions are obtained to prepare metallic, crystalline, and dense Ti films with smooth surface under conventional conditions.

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References

  1. G. Lütjering and J.C. Williams: Titanium (Springer, Berlin, Germany, 2003).

    Book  Google Scholar 

  2. M. Textor, C. Sittig, V. Frauchiger, S. Tosatti, and D.M. Brunette: Titanium in Medicine (Springer-Verlag, Heidelberg, 2001); p. 172.

    Google Scholar 

  3. M. Balazic, J. Kopac, M.J. Jackson, and W. Ahmed: Review: Titanium and titanium alloy applications in medicine. Int. J. Nano Biomater. 1, 3 (2007).

    Article  CAS  Google Scholar 

  4. S. Berger, A. Ghicov, Y-C. Nah, and P. Schmuki: Transparent TiO2 nanotube electrodes via thin layer anodization: Fabrication and use in electrochromic devices. Langmuir 25, 4841 (2009).

    Article  CAS  Google Scholar 

  5. O.K. Varghese, M. Paulose, and C.A. Grimes: Long vertically aligned titania nanotubes on transparent conducting oxide for highly efficient solar cells. Nat. Nanotechnol. 4, 592 (2009).

    Article  CAS  Google Scholar 

  6. Y. Ji, K-C. Lin, H. Zheng, C-C. Liu, L. Dudik, J. Zhu, and C. Burda: Solar-light photo amperometric and photocatalytic properties of quasi-transparent TiO2 nanoporous thin films. ACS Appl. Mater. Interfaces 2, 3075 (2010).

    Article  CAS  Google Scholar 

  7. X. Chen, J-S. Wang, H-Y. Li, K-L. Huang, and G-S. Sun: Characterization of TiO2 nanotube arrays prepared via anodization of titanium films deposited by DC magnetron sputtering. Res. Chem. Intermed. 37, 441 (2011).

    Article  CAS  Google Scholar 

  8. J. Avelar-Batista, A. Wilson, A. Davison, A. Matthews, and K. Fancey: Gas scattering effects and microstructural evaluation of electron beam evaporated titanium coatings in neon and argon at different gas pressures. Vacuum 72, 225 (2003).

    Article  CAS  Google Scholar 

  9. T. Tsuchiya, M. Hirata, and N. Chiba: Young’s modulus, fracture strain, and tensile strength of sputtered titanium thin films. Thin Solid Films 484, 245 (2005).

    Article  CAS  Google Scholar 

  10. M. Passeggi, L. Vergara, S. Mendoza, and J. Ferrón: Passivation and temperature effects on the oxidation process of titanium thin films. Surf. Sci. 507, 825 (2002).

    Article  Google Scholar 

  11. Y. Jeyachandran, B. Karunagaran, S.K. Narayandass, D. Mangalaraj, T. Jenkins, and P. Martin: Properties of titanium thin films deposited by dc magnetron sputtering. Mater. Sci. Eng., A 431, 277 (2006).

    Article  Google Scholar 

  12. M. Chinmulgund, R.B. Inturi, and J.A. Barnard: Effect of Ar gas pressure on growth, structure, and mechanical properties of sputtered Ti, Al, TiAl, and Ti3Al films. Thin Solid Films 270, 260 (1995).

    Article  CAS  Google Scholar 

  13. J.A. Thornton: Influence of apparatus geometry and deposition conditions on the structure and topography of thick sputtered coatings. J. Vac. Sci. Technol. 11, 666 (1974).

    Article  CAS  Google Scholar 

  14. O. Durst, J. Ellermeier, and C. Berger: Influence of plasma-nitriding and surface roughness on the wear and corrosion resistance of thin films (PVD/PECVD). Surf. Coat. Technol. 203, 848 (2008).

    Article  CAS  Google Scholar 

  15. T. Godfroid, R. Gouttebaron, J. Dauchot, P. Leclere, R. Lazzaroni, and M. Hecq: Growth of ultrathin Ti films deposited on SnO2 by magnetron sputtering. Thin Solid Films 437, 57 (2003).

    Article  CAS  Google Scholar 

  16. S. Muraishi, T. Aizawa, and H. Kuwahara: Fabrication of nanostructured titanium thin films via N ion implantation and post annealing treatment. Surf. Coat. Technol. 188, 260 (2004).

    Article  Google Scholar 

  17. V. Chawla, R. Jayaganthan, A. Chawla, and R. Chandra: Microstructural characterizations of magnetron sputtered Ti films on glass substrate. J. Mater. Process. Technol. 209, 3444 (2009).

    Article  CAS  Google Scholar 

  18. M. Einollahzadeh-Samadi and R. Dariani: Effect of substrate temperature and deposition rate on the morphology and optical properties of Ti films. Appl. Surf. Sci. 280, 263 (2013).

    Article  CAS  Google Scholar 

  19. R. Sailor and G. McCarthy: North Dakota University, Fargo, ND, ICDD, Grant-in-Aid, 1993.

  20. B.D. Cullity: Elements of X-ray Diffraction, 2nd ed. (Addison-Wesley Pub. Com. Inc., Reading, MA, 1978).

    Google Scholar 

  21. S. Andersson, B. Collen, U. Kuylenstierna, A. Magneli, A. Magnéli, H. Pestmalis, and S. Åsbrink: Phase analysis studies on the titanium-oxygen system. Acta Chem. Scand. 11, 1641 (1957).

    Article  CAS  Google Scholar 

  22. T. Sonoda, A. Watazu, J. Zhu, W. Shi, K. Kato, and T. Asahina: Structure and mechanical properties of pure titanium film deposited onto TiNi shape memory alloy substrate by magnetron DC sputtering. Thin Solid Films 459, 212 (2004).

    Article  CAS  Google Scholar 

  23. T. Zhang, Z. Zhong, J. Zhou, and F. Sun: Substrate temperature effects on the structural and optical properties of TiO2-doped ZnO films for organic photovoltaic devices. Appl. Mech. Mater. 275, 1964 (2013).

    Article  Google Scholar 

  24. F. Klabunde, M. Löhmann, J. Bläsing, and T. Drüsedau: The influence of argon pressure on the structure of sputtered molybdenum: From porous amorphous to a new type of highly textured film. J. Appl. Phys. 80, 6266 (1996).

    Article  CAS  Google Scholar 

  25. K. Sasaki and N. Nafarizal: Enhancement of Ti+ density in high-pressure magnetron sputtering plasmas. J. Phys. D: Appl. Phys. 43, 124012 (2010).

    Article  Google Scholar 

  26. G. Williamson and W. Hall: X-ray line broadening from filed aluminium and wolfram. Acta Metall. 1, 22 (1953).

    Article  CAS  Google Scholar 

  27. C-P. Liu and H-G. Yang: Deposition temperature and thickness effects on the characteristics of dc-sputtered ZrNx films. Mater. Chem. Phys. 86, 370 (2004).

    Article  CAS  Google Scholar 

  28. H. Savaloni and H. Kangarloo: Influence of film thickness, substrate temperature and nano-structural changes on the optical properties of UHV deposited Ti thin films. J. Phys. D: Appl. Phys. 40, 203 (2007).

    Article  CAS  Google Scholar 

  29. C. Grovenor, H. Hentzell, and D. Smith: The development of grain structure during growth of metallic films. Acta Metall. 32, 773 (1984).

    Article  CAS  Google Scholar 

  30. H. Qi, L. Huang, Z. Tang, C. Cheng, J. Shao, and Z. Fan: Roughness evolution of ZrO2 thin films grown by reactive ion beam sputtering. Thin Solid Films 444, 146 (2003).

    Article  CAS  Google Scholar 

  31. J. Als-Nielsen and D. McMorrow: Elements of Modern X-ray Physics (John Wiley & Sons, 2011).

  32. H. Zhang, C. Ma, and Q. Zhang: Scaling behavior and structure transition of ZrO2 films deposited by RF magnetron sputtering. Vacuum 83, 1311 (2009).

    Article  CAS  Google Scholar 

  33. Y. Wang and K. Zhang: Variation of the structural and optical properties of sol–gel TiO2 thin films with different treatment temperatures. J. Surf. Coat. Technol. 140, 155 (2001).

    Article  Google Scholar 

  34. T. Ganguli and A. Ingale: Raman and photoluminescence investigations of disorder in ZnSe films deposited on n-GaAs. Phys. Rev. B 60, 11618 (1999).

    Article  CAS  Google Scholar 

  35. B. Barnes, J. Kelly, J. MacKay, E. Mateeva, W. O’Brien, and M. Lagally: Correlations among sputter pressure, thickness, and coercivity in co/cu magnetic thin films sputfer-deposited on si [001]. Presented at IEEE Magnetics Conference, Toronto, Ontario, 2000.

  36. H. Bennett, J.M. Bennett, and M. Nagel: Question of the polarization of infrared radiation from the clear sky. J. Opt. Soc. Am. 51, 237 (1961).

    Article  Google Scholar 

  37. V. Lucarini, J.J. Saarinen, K.E. Peiponen, and E.M. Vartiainen: Kramers kronig relations. In Optical Materials Research, W.T. Rhodes ed. (Springer, Berlin, Germany, 2004).

  38. S. Yoon, H. Kim, M. Kim, H. Lee, and D. Yoon: Effect of substrate temperature on surface roughness and optical properties of Ta2O5 using ion-beam sputtering. Thin Solid Films 475, 239 (2005).

    Article  CAS  Google Scholar 

  39. R. Pandian, G. Natarajan, S. Rajagopalan, M. Kamruddin, and A. Tyagi: On the phase formation of titanium oxide thin films deposited by reactive DC magnetron sputtering: Influence of oxygen partial pressure and nitrogen doping. Appl. Phys. A 116, 1905 (2014).

    Article  CAS  Google Scholar 

  40. F. Lai, M. Li, H. Wang, H. Hu, X. Wang, J. Hou, Y. Song, and Y. Jiang: Optical scattering characteristic of annealed niobium oxide films. Thin Solid Films 488, 314 (2005).

    Article  CAS  Google Scholar 

  41. J.A. Thornton: Influence of substrate temperature and deposition rate on structure of thick sputtered Cu coatings. J. Vac. Sci. Technol. 12, 830 (1975).

    Article  CAS  Google Scholar 

  42. J.M. Garnett: Philos. Trans. R. Soc. London 203, 385 (1904).

    Article  CAS  Google Scholar 

  43. S.Y. Lee, H. Chang, T. Ogi, F. Iskandar, and K. Okuyama: Measuring the effective density, porosity, and refractive index of carbonaceous particles by tandem aerosol techniques. Carbon 49, 2163–2172 (2011).

    Article  CAS  Google Scholar 

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Correspondence to Reza Sabet Dariani.

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Einollahzadeh-Samadi, M., Dariani, R.S. & Abdi, M. Characterization of nanocrystalline Ti films deposited by DC magnetron sputtering onto FTO glass substrate. Journal of Materials Research 30, 3093–3103 (2015). https://doi.org/10.1557/jmr.2015.249

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