Abstract
Microstructures and mechanical properties of the Mg–4Y–2.5Nd–0.6Zr (wt%) alloy in the as-cast, as-rolled, and rolled-T5 conditions have been investigated. Results showed that the as-cast sample mainly consisted of the α-Mg matrix, network-like Mg41Nd5 phase, and cuboid-shaped Mg24Y5 particles. For the as-rolled sample, the thermally stable Mg24Y5 particles located at both grain boundaries and matrix, and the average grain size was greatly refined to about 15 μm. Yield strength, ultimate tensile strength, and elongation of as-rolled samples were 290 MPa, 235 MPa, and 10%, respectively. They were enhanced by 48.7%, 56.7%, and 38.9% correspondingly compared with those of the as-cast sample. After isothermal aging at 250 °C for 4 h, the optimal mechanical properties can be obtained. Besides, the tensile strengths of as-rolled and rolled-T5 samples decreased gradually with a gradual increase of ductility from room temperature to 300 °C. Quasicleavage and cleavage fracture were the fracture patterns of as-rolled and rolled-T5 samples, respectively, at room temperature. For samples under the two conditions, fracture mode similarly changed with the increase of test temperatures, and ductile fracture can be observed at higher temperature.
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References
L.L. Rokhlin: Magnesium Alloys Containing Rear Earth Metals (Taylor and Francis, London, 2003).
B.L. Mordike and T. Ebert: Magnesium: Properties-applications-potential. Mater. Sci. Eng., A 302, 37 (2001).
W.P. Li, H. Zhou, and Z.F. Li: Effect of gadolinium on microstructure and rolling capability of AZ31 alloy. J. Alloys Compd. 475, 227 (2009).
L. Lin, L.J. Chen, and Z. Liu: Tensile strength improvement of an Mg-12Gd-3Y(wt%) alloy processed by hot extrusion and free forging. J. Mater. Sci. 43, 4493 (2008).
W.J. Ding, D.Q. Li, Q.D. Wang, and Q. Li: Microstructure and mechanical properties of hot-rolled Mg-Zn-Nd-Zr alloys. Mater. Sci. Eng., A 483–484, 228 (2008).
T. Homma, N. Kunito, and S. Kamado: Fabrication of extraordinary high-strength magnesium alloy by hot extrusion. Scr. Mater. 61, 644 (2009).
K. Liu and J. Meng: Microstructures and mechanical properties of the extruded Mg-4Y-2Gd-xZn-0.4Zr alloys. J. Alloys Compd. 509, 3299 (2011).
J.H. Zhang, Z. Leng, S.J. Liu, J.Q. Li, M.L. Zhang, and R.Z. Wu: Microstructure and mechanical properties of Mg-Gd-Dy-Zn alloy with long period stacking ordered structure or stacking faults. J. Alloys Compd. 509, 7717 (2011).
J.F. Nie and B.C. Muddle: Characterisation of strengthening precipitate phases in a Mg-Y-Nd alloy. Acta Mater. 48, 1691 (2000).
A.R. Wu and C.Q. Xia: Study of the microstructure and mechanical properties of Mg-rare earth alloys. Mater. Des. 28, 1963 (2007).
L.D. Wang, C.Y. Xing, X.L Hou, Y.M. Wu, J.F. Sun, and L.M. Wang: Microstructures and mechanical properties of as-cast Mg-5Y-3Nd-Zr-xGd (x=0, 2 and 4 wt.%) alloys. Mater. Sci. Eng., A 527, 1891 (2010).
C. Antion, P. Donnadieu, F. Perrard, A. Deschamps, C. Tassin, and A. Pisch: Hardening precipitation in a Mg-4Y-3RE alloy. Acta Mater. 51, 5335 (2003).
P.H. Fu, L.M. Peng, H.Y. Jiang, Z.Y. Zhang, and C.Q. Zhai: Fracture behavior and mechanical properties of Mg-4Y-2Nd-1Gd-0.4Zr(wt.%) alloy at room temperature. Mater. Sci. Eng., A 486, 572 (2008).
T. Mohri, M. Mabuchi, N. Satio, and M. Nakamura: Microstructure and mechanical properties of a Mg-4Y-3RE alloy processed by thermo-mechanical treatment. Mater. Sci. Eng., A 257, 287 (1998).
X.Y. Fang, D.Q. Yi, J.F. Nie, X.J. Zhang, B. Wang, and L.R. Xiao: Effect of Zr, Mn and Sc additions on the grain size of Mg-Gd alloy. J. Alloys Compd. 470, 311 (2009).
R.L. Xin, L. Li, K. Zeng, B. Song, and Q. Liu: Structural examination of aging precipitation in a Mg-Y-Nd alloy at different temperatures. Mater. Charact. 62, 535 (2011).
M. Yamasaki, T. Anan, S. Yoshimoto, and Y. Kawamura: Mechanical properties of warm-extruded Mg-Zn-Gd alloy with coherent 14H long periodic stacking ordered structure precipitate. Scr. Mater. 53, 799 (2005).
J.L. Wang, H.W. Dong, L.D. Wang, Y.M. Wu, and L.M. Wang: Effect of hot rolling on the microstructure and mechanical properties of Mg-5Al-0.3Mn-2Nd alloy. J. Alloys Compd. 507, 178 (2010).
T. Itoi, T. Seimiya, Y. Kawamura, and M. Hirohashi: Long period stacking structures observed in Mg97Zn1Y2 alloy. Scr. Mater. 51, 107 (2004).
I.A. Anyanwu, S. Kamado, and Y. Kojima: Creep properties of Mg-Gd-Y-Zr alloys. Mater. Trans. 42, 1206 (2001).
K. Liu, J.H. Zhang, W. Sun, X. Qiu, H.Y. Lu, D.X. Tang, L.L. Rokhlin, F.M. Elkin, and J. Meng: Precipitates formed in a Mg-7Y-4Gd-0.5Zn-0.4Zr alloy during isothermal ageing at 250°C. Mater. Chem. Phys. 117, 107 (2009).
X. Gao, S.M. He, X.Q. Zeng, L.M. Peng, W.J. Ding, and J.F. Nie: Microstructure evolution in a Mg-15Gd-0.5Zr(wt.%) alloy during isothermal aging at 250°C. Mater. Sci. Eng., A 431, 322 (2006).
M. Mabuchi and K. Higashi: Strengthening mechanisms of Mg-Si alloys. Acta Mater. 44, 4611 (1996).
Z. Yang, J.P. Li, Y.C. Guo, T. Liu, F. Xia, Z.W. Zeng, and M.X. Liang: Precipitation process and effect on mechanical properties of Mg-9Gd-3Y-0.6Zn-0.5Zr alloy. Mater. Sci. Eng., A 454–455, 274 (2007).
J.F. Nie: Effects of precipitate shape and orientation on dispersion strengthening in magnesium alloys. Scr. Mater. 48, 1009 (2003).
S.M. He, X.Q. Zeng, L.M. Peng, X. Gao, J.F. Nie,and W.J. Ding: Microstructure and strengthening mechanism of high strength Mg-10Gd-2Y-0.5Zr alloy. J. Alloys Compd. 427, 316 (2007).
E. Abe, Y. Kawamura, K. Hayashi, and A. Inoue: Long-period ordered structure in a high-strength nanocrystalline Mg-1at%Zn-2at%Y alloy studied by atomic-resolution Z-contrast STEM. Acta Mater. 50, 3845 (2002).
A. Jäger, P. Lukáč, V. Gärtnerová, J. Bohlen, and K.U. Kainer: Tensile properties of hot rolled AZ31 Mg alloy sheets at elevated temperatures. J Alloys Compd. 378, 184 (2004).
S.B. Yi, S. Zaefferer, and H-G. Brokmeier: Mechanical behaviour and microstructural evolution of magnesium alloy AZ31 in tension at different temperatures. Mater. Sci. Eng., A 424, 275 (2006).
J.C. Tan and M.J. Tan: Superplasticity and grain boundary sliding characteristics in two stage deformation of Mg-3Al-1Zn alloy sheet. Mater. Sci. Eng., A 339, 81 (2003).
K-J. Li and Q-A. Li: Microstructure and superior mechanical properties of cast Mg-12Gd-2Y-0.5Sm-0.5Sb-0.5Zr alloy. Mater. Sci. Eng., A 528, 5453 (2011).
K. Liu, L.L. Rokhlin, F.M. Elkin, D.X. Tang, and J. Meng: Effect of ageing treatment on the microstructures and mechanical properties of the extruded Mg-7Y-4Gd-1.5Zn-0.4Zr alloy. Mater. Sci. Eng., A 527, 828 (2010).
ACKNOWLEDGMENTS
This work was supported partly by the Natural Science Foundation of China (Grant No. 51074186) and the Open-End Fund for the Valuable and Precision Instruments of Central South University. The authors would like to thank Professor Ding Daoyun for providing writing assistance to the article and the anonymous reviewers for supplying the helpful comments.
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Wang, X., Liu, C., Xu, L. et al. Microstructure and mechanical properties of the hot-rolled Mg–Y–Nd–Zr alloy. Journal of Materials Research 28, 1386–1393 (2013). https://doi.org/10.1557/jmr.2013.109
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DOI: https://doi.org/10.1557/jmr.2013.109