Abstract
(Pb0.87−0.07xBa0.10+0.07x)La0.02(Zr0.7Sn0.15Ti0.15)O3 ceramics with 0 ≤ x ≤1 were prepared by conventional solid-state reaction process, and their dielectric and electric field–induced pyroelectric properties were systemically investigated. Compared with conventional pyroelectric materials, (Pb0.87−0.07xBa0.10+0.07x)La0.02(Zr0.7Sn0.15Ti0.15)O3 ceramics exhibited higher pyroelectric coefficient and figure of merit, which are beneficial for the development of pyroelectric devices. The specimens with x = 0.65 showed good pyroelectric properties for practical applications. When a 500 V/mm dc bias field was applied, they showed the maximum pyroelectric coefficient of 12,200 μC/m2K and the figure of merit of 106 × 10−5 Pa−0.5 at 45 °C, which are larger than those observed from conventional pyroelectric materials. Improvement of pyroelectric property is beneficial for the development of infrared detectors.
Similar content being viewed by others
REFERENCES
F. Jin, G.W. Auner, R. Naik, N.W. Schubring, J.V. Mantese, A.B. Catalan, and A.L. Micheli: Giant effective pyroelectric coefficients from graded ferroelectric devices. Appl. Phys. Lett. 73, 2838 (1998).
J.T. Wang and C. Zhang: Pyroelectric properties of 0.7PbMg1/3(Nb0.9Ta0.1)2/3O3-0.3PbTiO3 ceramics. J. Appl. Phys. 98, 054103 (2005).
L.H. Liu, X.B. Li, X. Wu, Y.J. Wang, W.N. Di, D. Lin, X.Y. Zhao, H.S. Luo, and N. Neumann: Dielectric, ferroelectric, and pyroelectric characterization of Mn-doped 0.74Pb(Mg1/3Nb2/3)O3-0.26PbTiO3 crystals for infrared detection applications. Appl. Phys. Lett. 95, 192903 (2009).
C.G. Wu, Y.R. Li, J. Zhu, X.Z. Liu, and W.L. Zhang: Great enhancement of pyroelectric properties for Ba0.65Sr0.35TiO3 films on Pt–Si substrates by inserting a self-buffered layer. J. Appl. Phys. 105, 044107 (2009).
Y.H. Juna, T.Y. Kima, and H.M. Jang: (Ba, Sr)TiO3 system under DC-bias field: I. Improvement on the thermostability of pyroelectric response by Zr-substitution. Ferroelectrics 193, 109 (1997).
R. Watton and M.A. Todd: Induced pyroelectricity in sputtered lead scandium tantalate films and their merit for IR detector arrays. Ferroelectrics 118, 279 (1991).
K. Yoon, S.C. Hwang, and D.H. Kang: Dielectric and field-induced strain behaviour of (Pb1-xBax) ZrO3 ceramics. J. Mater. Sci. 32, 17 (1997).
R.W. Whatmore: Pyroelectric devices and materials. Rep. Prog. Phys. 49, 1335 (1986).
P. Yang and D.A. Payne: The effect of external field symmetry on the antiferroelectric–ferroelectric phase transformation. J. Appl. Phys. 80, 4001 (1996).
A. Yu. Tuflin, V.V. Shvartsman, G.M. Kaleva, and E.D. Politova: Investigation of dielectric and ferroelectric properties of the Pb(Sn,Zr,Ti)O3 ceramics. Ferroelectrics 299, 145 (2004).
S.E. Park, K. Markowski, S. Yoshikawa, and L.E. Cross: Effect on electrical properties of barium and strontium additions in the lead lanthanum zirconate stannate titanate system. J. Am. Ceram. Soc. 80, 407 (1997).
N. Zhang, Z. Xu, Y.J. Feng, and X. Yao: Dielectric and relaxor ferroelectric properties of Ba-doped Pb(Zr,Ti)O3 ceramics. J. Electroceram. 21, 609 (2008).
Z. Ujma, J. Handerek, M. Paweeczyk, and D. Dmytrow: Phase composition and dielectric properties of lead barium zirconate solid solutions. Ferroelectrics 129, 127 (1992).
Z.L. Chen, X. Yao, and L.E. Cross: Depolarization behavior and reversible pyroelectricity in lead scandium–tantalate ceramics under DC biases. Ferroelectrics 49, 213 (1983).
W.L. Zhong: Ferroelectrics Physics (Science Publishing Company, Beijing, 1998), pp. 74–79.
B.P. Pokharel and D. Pandey: Dielectric studies of phase transitions in (Pb1-xBax)ZrO3. J. Appl. Phys. 88, 5364 (2000).
D.S. Kang, M.S. Han, S.G. Lee, and S.H. Song: Dielectric and pyroelectric properties of barium strontium calcium titanate ceramics. J. Eur. Ceram. Soc. 23, 515 (2003).
ACKNOWLEDGMENTS
The authors thank Analytical and Testing Center of Huazhong University of Science and Technology. This work has been supported by the Graduate Student Creational Fund (HF-08-08-2011-185).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, Q., Jiang, S. & Zeng, Y. Dielectric and electric field–induced pyroelectric behavior of (Pb0.87−0.07xBa0.10+0.07x)La0.02(Zr0.7Sn0.15Ti0.15)O3 ceramics. Journal of Materials Research 26, 1436–1440 (2011). https://doi.org/10.1557/jmr.2011.128
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2011.128