Abstract
In the present work, the pyroelectric performance of [Bi0.48Na0.4032K0.0768]Sr0.04(Ti0.975Nb0.025)O3 (BNT-2.5Nb) ceramics is investigated. At room temperature, the value of pyroelectric coefficient found as 13.2 × 10−4 C/m2 K which is higher than many lead-free ferroelectric materials. Further, the pyroelectric figures of merit (FOMs) for detectivity (Fd), voltage responsivity (Fv), current responsivity (Fi), and energy harvesting (Fe*) are calculated. BNT-2.5Nb ceramics show pyroelectric open circuit voltage as 0.45 V when it was exposed to temporal temperature gradient. This work result indicates that the Nb-doping in Bi0.5Na0.5TiO3-based composition can be beneficial for lead-free pyroelectric device applications.
Similar content being viewed by others
References
Bauer, S., Ploss, B.: A method for the measurement of the thermal, dielectric, and pyroelectric properties of thin pyroelectric films and their applications for integrated heat sensors. J. Appl. Phys. 68(12), 6361–6367 (1990)
Whatmore, R.: Pyroelectric devices and materials. Rep. Prog. Phys. 49(12), 1335 (1986)
Patel, S., Chauhan, A., Vaish, R.: Electrocaloric behavior and temperature-dependent scaling of dynamic hysteresis of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 ceramics. Int. J. Appl. Ceram. Technol. 12(4), 899–907 (2015)
Charlot, B., Coudouel, D., Very, F., Combette, P., Giani, A.: Droplet generation for thermal transient stimulation of pyroelectric PZT element. Sens. Actuators A: Phys. 225, 103–110 (2015)
Bowen, C., Taylor, J., Le Boulbar, E., Zabek, D., Topolov, V.Y.: A modified figure of merit for pyroelectric energy harvesting. Mater. Lett. 138, 243–246 (2015)
Wang, Z.L., Wu, W.: Nanotechnology-enabled energy harvesting for self-powered micro/nanosystems. Angew. Chem. Int. Ed. 51(47), 11700–11721 (2012)
Vaish, M., Sharma, M., Vaish, R., Chauhan, V.S.: Electrical energy generation from hot/cold air using pyroelectric ceramics. Integr. Ferroelectr. 167(1), 90–97 (2015)
Madhar, N.A., Ilahi, B., Vaish, M.: Pyroelectric energy harvesting using (Ba0.85Ca0.15)(Zr0.1Ti0.89Fe0.01)O3 ceramics. Integr. Ferroelectr. 167(1), 176–183 (2015)
Lang, S.B.: Pyroelectricity: from ancient curiosity to modern imaging tool. Phys. Today. 58(8), 31 (2005)
Zhang, G., Jiang, S., Zeng, Y., Zhang, Y., Zhang, Q., Yu, Y.: High pyroelectric properties of porous Ba0.67Sr0.33TiO3 for uncooled infrared detectors. J. Am. Ceram. Soc. 92(12), 3132–3134 (2009)
Patel, S., Chauhan, A., Kundu, S., Madhar, N.A., Ilahi, B., Vaish, R., et al.: Tuning of dielectric, pyroelectric and ferroelectric properties of 0.715Bi0.5Na0.5TiO3-0.065BaTiO3-0.22SrTiO3 ceramic by internal clamping. AIP Adv. 5(8), 087145 (2015)
Patel, S., Chauhan, A., Vaish, R.: Large pyroelectric figure of merits for Sr-modified Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics. Solid State Sci. 52, 10–18 (2016)
Wang, X., Wu, J., Xiao, D., Zhu, J., Cheng, X., Zheng, T., et al.: Giant piezoelectricity in potassium-sodium niobate lead-free ceramics. J. Am. Chem. Soc. 136(7), 2905–2910 (2014)
Liu, L., Huang, Y., Su, C., Fang, L., Wu, M., Hu, C., et al.: Space-charge relaxation and electrical conduction in K0.5Na0.5NbO3 at high temperatures. Appl. Phys. A. 104(4), 1047 (2011)
Li, J., Wang, F., Leung, C.M., Or, S.W., Tang, Y., Chen, X., et al.: Large strain response in acceptor-and donor-doped Bi0.5Na0.5TiO3-based lead-free ceramics. J. Mater. Sci. 46(17), 5702 (2011)
Liu, Z., Ren, W., Nie, H., Peng, P., Liu, Y., Dong, X., et al.: Pressure driven depolarization behavior of Bi0.5Na0.5TiO3 based lead-free ceramics. Appl. Phys. Lett. 110(21), 212901 (2017)
Kang, S.-I., Lee, J.-H., Kim, J.-J., Lee, H.Y., Cho, S.-H.: Effect of sintering atmosphere on densification and dielectric characteristics in Sr0.5Ba0.5Nb2O6 ceramics. J. Eur. Ceram. Soc. 24(6), 1031–1035 (2004)
Gao, J., Hu, X., Zhang, L., Li, F., Zhang, L., Wang, Y., et al.: Major contributor to the large piezoelectric response in (1-x)Ba (Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 ceramics: domain wall motion. Appl. Phys. Lett. 104(25), 252909 (2014)
Wang, X., Tang, X., Chan, H.: Electromechanical and ferroelectric properties of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-BaTiO3 lead-free piezoelectric ceramics. Appl. Phys. Lett. 85(1), 91–93 (2004)
Zuo, R., Ye, C., Fang, X., Li, J.: Tantalum doped 0.94Bi0.5Na0.5TiO3-0.06BaTiO3 piezoelectric ceramics. J. Eur. Ceram. Soc. 28(4), 871–877 (2008)
Guo, F.-F., Yang, B., Zhang, S.-T., Liu, X., Zheng, L.-M., Wang, Z., et al.: Morphotropic phase boundary and electric properties in (1-x)Bi0.5Na0.5TiO3-xBiCoO3 lead-free piezoelectric ceramics. J. Appl. Phys. 111(12), 124113 (2012)
Liu, X., Tan, X.: Giant strains in non-textured (Bi1/2Na1/2)TiO3-based lead-free ceramics. Adv. Mater. 28(3), 574–578 (2016)
Malik, R.A., Hussain, A., Zaman, A., Maqbool, A., Rahman, J.U., Song, T.K., et al.: Structure-property relationship in lead-free A-and B-site co-doped Bi0.5(Na0.84K0.16)0.5TiO3-SrTiO3 incipient piezoceramics. RSC Adv. 5(117), 96953–96964 (2015)
Ullah, A., Malik, R.A., Ullah, A., Lee, D.S., Jeong, S.J., Lee, J.S., et al.: Electric-field-induced phase transition and large strain in lead-free Nb-doped BNKT-BST ceramics. J. Eur. Ceram. Soc. 34(1), 29–35 (2014)
Pham, K.-N., Hussain, A., Ahn, C.W., Ill, W.K., Jeong, S.J., Lee, J.-S.: Giant strain in Nb-doped Bi0.5(Na0.82K0.18)0.5TiO3 lead-free electromechanical ceramics. Mater. Lett. 64(20), 2219–2222 (2010)
Zhang, J., Dong, X., Cao, F., Guo, S., Wang, G.: Enhanced pyroelectric properties of Cax(Sr0.5Ba0.5)1-xNb2O6 lead-free ceramics. Appl. Phys. Lett. 102(10), 102908 (2013)
Hiruma, Y., Nagata, H., Takenaka, T.: Phase diagrams and electrical properties of (Bi1/2Na1/2)TiO3-based solid solutions. J. Appl. Phys. 104(12), 124106 (2008)
Yu, P., Ji, Y., Neumann, N., Lee, S.-G., Luo, H., Es-Souni, M.: Application of single-crystalline PMN-PT and PIN-PMN-PT in high-performance pyroelectric detectors. IEEE Trans. Ultrason. Ferroelectr. Freq. Control. 59(9), 1983–1989 (2012)
Tang, Y., Luo, H.: Investigation of the electrical properties of (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 single crystals with special reference to pyroelectric detection. J. Phys. D. Appl. Phys. 42(7), 075406 (2009)
Liu, X., Chen, Z., Wu, D., Fang, B., Ding, J., Zhao, X., et al.: Enhancing pyroelectric properties of Li-doped (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 lead-free ceramics by optimizing calcination temperature. Jpn. J. Appl. Phys. 54(7), 071501 (2015)
Sun, R., Wang, J., Wang, F., Feng, T., Li, Y., Chi, Z., et al.: Pyroelectric properties of Mn-doped 94.6Na0.5Bi0.5TiO3-5.4BaTiO3 lead-free single crystals. J. Appl. Phys. 115(7), 074101 (2014)
Bowen, C.R., Taylor, J., LeBoulbar, E., Zabek, D., Chauhan, A., Vaish, R.: Pyroelectric materials and devices for energy harvesting applications. Energy Environ. Sci. 7(12), 3836–3856 (2014)
Lau, S.T., Cheng, C., Choy, S., Lin, D., Kwok, K., Chan, H.L.: Lead-free ceramics for pyroelectric applications. J. Appl. Phys. 103(10), 104105 (2008)
Lang, S.B., Das-Gupta, D.K.: Pyroelectricity: fundamentals and applications. In: Handbook of Advanced Electronic and Photonic Materials and Devices, pp. 1–55. Elsevier (2001)
Acknowledgements
Rahul Vaish acknowledges the support from the Indian National Science Academy (INSA), New Delhi, India, through a grant by the Department of Science and Technology (DST), New Delhi, India under the INSA Young Scientists Award. Satyanarayan Patel would like to acknowledge sponsorship provided by the Alexander-von-Humboldt Foundation.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Srikanth, K.S., Singh, V.P., Patel, S. et al. Pyroelectric performance of [Bi0.48Na0.4032K0.0768]Sr0.04(Ti0.975Nb0.025)O3 ceramics. J Aust Ceram Soc 56, 395–402 (2020). https://doi.org/10.1007/s41779-019-00343-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s41779-019-00343-5